事故树在油库静电火灾爆炸分析中的应用

主要分析了引起油库静电火灾爆炸的各种原因和环节,并建立了油库静电火灾爆炸事故树。通过对事故树的定性分析,提出了预防油库静电火灾爆炸事故的对策,给出了具体的防静电措施。     

反应性液体紧急泄放面积设计进展

为防止反应失控造成爆炸事故,减少事故损失,在介绍模拟反应失控的实验装置ARC、VSP以及RSST等的基础上,针对不同的紧急泄放类型,如气相系统、蒸气系统和混合系统的紧急泄放研究进展,进行了分析论述,旨在发现解决反应失控紧急泄放问题的更好方法,从而为进一步研究反应失控的紧急泄放问题打下基础.     

Effects of ferric oxide on decompositions of methyl ethyl ketone peroxide

Methyl ethyl ketone peroxide (MEKPO) is a widely used initiator for polymerization reaction and hardener in glass-reinforced plastic. However, MEKPO is an unstable reactive chemical and has caused several serious accidents all over the world. This work studied the thermal stability of MEKPO in the presence of ferric oxide as the contaminant through calorimetric and kinetic studies. The calorimetry was performed using Automatic Pressure Tracking Adiabatic Calorimeter (APTAC) to identify the effects of ferric oxide (different concentration) on important reactive hazards such as onset temperature and pressure hazard. Kinetic modeling was then performed to study the kinetics of the runaway reaction and estimate important kinetic parameters. The results indicate that in the low concentration range (<0.3%), ferric oxide has no significant effect on the thermal stability of MEKPO. However, in the high and intermediate concentration range of ferric oxide (i.e., 10%), the negative effect on the thermal stability of MEKPO was observed. This result is in agreement with the kinetic study result that the activation energy and frequency factor decrease dramatically in the high ferric oxide concentration range. The results provide necessary process safety information for the handling of MEKPO and also technical basis for the further study in this area.     

Thermal risk analysis of cumene hydroperoxide in the presence of alkaline catalysts

Many studies have been performed to clarify the basic thermal runaway hazards and kinetics of cumene hydroperoxide (CHP) decomposition. However, materials that are incompatible with CHP have not been clearly identified. Alkaline solutions have been used as a catalyst to form dimethylphenyl carbinol (DMPC) and dicumyl peroxide (DCPO); however, these solutions also affect the reaction and storage temperature of CHP. In this study, thermal calorimeters, differential scanning calorimetry (DSC) and vent sizing package 2 (VSP2), were used to compare the effects of various bases on the decomposition of CHP in cumene. Specifically, the exothermic onset temperature, change in pressure over time, self-heating rate and heat of decomposition were evaluated. Moreover, to appraise the degree of hazard associated with the use of CHP, the compatibility of CHP with various substances was analyzed, and a risk matrix for thermal runaway reactions was obtained. The results of the present study could be used to design safety procedures for the production of CHP and its derivatives.     

加油站埋地汽油储罐爆炸定量分析

针对加油站的埋地汽油储罐爆炸进行了定量分析。简要叙述了加油站埋地储罐的埋地方式以及埋地深度等基本情况,运用岩土中的爆炸理论描述分析了埋地储罐爆炸的过程。在计算爆炸冲击波超压时,提出一个计算埋地汽油储罐爆炸冲击波超压的准则:对于埋地汽油储罐爆炸,应当结合汽油储罐的埋地深度以及储罐周围覆土的性质等因素来确定冲击波超压的计算方法。     

泄爆容器中粉尘爆炸的试验研究与数值模拟

为了解泄爆容器中粉尘爆炸的发展过程,采用试验和数值模拟相结合的方法对玉米淀粉在圆柱形容器内的泄爆过程进行研究。数值模型采用欧拉–拉格朗日方法模拟粉尘爆炸的两相流问题,通过求解非稳态的湍流两相反应流守恒方程对试验进行二维仿真。试验和模拟结果表明,点火位置对爆炸发展过程有明显影响,点火位置离泄爆口越远,容器中的最大泄爆压力Pred,max越高。在粉尘爆炸的安全防护设计中,应把点火位置作为重要影响因素之一加以考虑。     

含DOPO磷酸酯阻燃改性环氧丙烯酸树脂的制备及热性能研究

将工业上广泛应用的光固化树脂EA作为基体,通过分子设计,利用甲苯二异氰酸酯TDI的双异氰酸酯结构将合成的磷酸酯阻燃剂ODOPM链接到其分子主链上,制备出一组改性的光固化丙烯酸酯预聚物。利用FT-IR,1 H-NMR,31P-NMR对分子结构进行表征;极限氧指数（LOI）和微型量热仪（MCC）的结果表明材料的阻燃性能明显提高,改性后树脂的热释放速率峰值PHRR相对于EA降低了近66%,总热释放量也明显降低;扫描电镜结果显示改性后的树脂固化膜形成的炭层变得更平滑和致密,并且完整无破裂现象;同时对固化膜的热稳定性和热降解过程进行了探讨。分析论证了ODOPM改性修饰后的EA有更高的阻燃性,成炭能力明显增强,形成的致密炭层有效地阻止了热交换,使材料在高温下更稳定。     

城市危险源爆炸灾害应急损失评估研究

采用冲击波伤害-破坏超压准则,首先确定了不同当量TNT炸药爆炸引起的人员伤害区域和建筑物破坏区域;再通过确定危险物爆炸所产生热量值的大小,将各种危险物料转化为相应当量的TNT炸药,可用于评估各种不同危险物料爆炸所造成的损失。同时,结合GIS软件平台,编制了爆炸灾害评估模拟程序。在软件平台中以图形的形式给出了设定条件下人员伤害区域及建筑物破坏区域的范围,根据区域内的人员分布和建筑物造价、财产多少,给出了定量的人员伤亡和经济损失应急评估。     

天然气管道泄漏火球事故后果模拟评价

天然气管道发生泄漏时,大约90%的气体产生燃烧并形成火球,遇火源即发生危害性非常大的火球爆炸事故。本文针对城市天然气管道泄漏事故,综合考虑天然气泄漏后可能发生的火球燃烧和爆炸,利用爆炸冲击波和火球热辐射模型对天然气管道(完全破裂)在发生泄漏时发生火球爆炸进行计算,结果表明:2分钟内泄漏天然气云团超压爆炸的死亡半径和热辐射的火球半径分别高达39.44m和92.93m。因此,通过计算天然气泄漏火球事故爆炸和热辐射范围,对天然气火球爆炸事故预防与应急救援具有一定的意义。     

粉尘爆炸特征和预防措施探讨

随着现代工业的发展,粉末技术得到了广泛应用,使得粉末产物日益增多.许多粉体加工企业对粉体的相关危害知识没有深刻的认识,这些物质在安全生产、储存、运输和应用过程中,安全管理比较混乱,没有做到很好的防护,缺乏必要的防火防爆设施,再加上操作人员思想上的麻痹大意.粉尘爆炸的危险性大大增加,粉尘爆炸的事故也频繁发生.粉尘爆炸具有很强的破坏力,往往造成重大人员伤亡和严重损失,已经越发成为工业安全不可忽视的重要问题.本文从粉尘爆炸的基本特征出发,论述了粉尘爆炸的机理、条件、特点.根据粉尘爆炸需要的条件,从可燃物、助燃物和点火源三个方面,提出了在实际生产中,预防粉尘爆炸的一些具体措施,以期指导安全生产.