Low-temperature oxidation of coal at elevated pressures

A mathematical model is presented to describe steady-state mass transfer and oxidation processes in coal at low temperatures in a fixed-bed flow reactor. The model incorporates the effects of partial pressure of oxygen, temperature and coal particle size, and accounts for the rate of coal oxidation and the composition of oxygenated products at high pressures. This is an important development since previous models did not include the effect of pressure in their formulation. It is found that, when the partial pressure of oxygen increases the rate of oxygen consumption increases accordingly. However, the influence of partial pressure of oxygen on the rate of oxidation is less pronounced when the pressure surpasses 1 MPa. In addition the model predicts that, for a constant partial pressure of oxygen, higher rates of oxygen consumption occur at lower total pressures. The same trends are also found for the concentration of oxygenated products at the reactor outlet. It is suggested that, the variation of partial pressure of oxygen leads to different concentration levels of oxygen at the surface and within the pores of coal particles, substantially affecting the rate of oxidation.     

论注册安全主任制度

为适应市场经济条件下安全生产工作的需要,以广州市建立注册安全主任执业资格制度为背景,概述了作为职业资格制度之一的“执业资格制度”、分析了安全主任执业资格制度产生的社会条件,论述了安全主任知识结构、作用机理等。用以上内容,试图论证：注册安全主任执业资格制度的产生是社会市场经济发展的必然要求     

促进人机环境系统本质安全化建设安全生产良性循环

结合金川公司龙首矿安全生产的实际,论述了建设人机环境系统并实现其本质安全化的意义,对该矿员工的本质安全化建设、机具与环境的本质安全化建设的经验作了介绍,其中,特别强调“四合一”的管理模式是人机环境系统实现本质安全化的重要保证。     

论职业卫生安全管理体系标准化与我国职业卫生安全管理及其改革的一致性

职业卫生安全管理体系（ＯＨＳＭＳ）标准倡导好的管理的共同原理,将ＯＨＳＭＳ融入组织总的管理体系,与我国组织职业卫生安全（ＯＨＳ）管理的经验相容,对我国组织在市场经济体制下建立自主安全管理机制有极重要的意义。实施ＯＨＳＭＳ标准不存在经济实力的前提,且ＯＨＳ投入与组织的经济效益是一致的。这种标准化适应了我国经济体制转变时期政府安全管理职能和管理方式的变化,还与我国ＯＨＳ管理体制的改革方向相吻合。我国基本具备实施ＯＨＳＭＳ标准的法律基础。为有效实施ＯＨＳＭＳ标准化,应加强ＯＨＳ法规建设,在监察体系上实行第三方机构的认证／注册制度     

冲天炉烟气除尘

采用湿法除尘,在烟气管道内设置喷嘴,使烟气充分加湿和降温后再进入立式文丘里,旋流析除尘器,消除了ＣＯ爆炸危险,在冲天炉上部烟囟顶端设安全２盖板,以保证生产的正常进行;烟气经湿式除尘后达到排放标准。     

丙烯腈装置火灾爆炸危险指数评价

运用美国道化学公司的火灾、爆炸危险指数评价方法(第七版)，对丙烯腈装置的火灾爆炸危险性进行定量计算和评价，为装置的安全管理提供依据。     

Influence of hydrogeochemical processes on zero-valent iron reactive barrier performance: a field investigation

Geochemical and mineralogical changes were evaluated at a field Fe0-PRB at the Oak Ridge Y-12 site concerning operation performance during the treatment of U in high NO3- groundwater. In the 5-year study period, the Fe0 remained reactive as shown in pore-water monitoring data, where increases in pH and the removal of certain ionic species persisted. However, coring revealed varying degrees of cementation. After 3.8-year treatment, porosity reduction of up to 41.7% was obtained from mineralogical analysis on core samples collected at the upgradient gravel-Fe0 interface. Elsewhere, Fe0 filings were loose with some cementation. Fe0 corrosion and pore volume reduction at this site are more severe due to the presence of NO3- at a high level. Tracer tests indicate that hydraulic performance deteriorated: the flow distribution was heterogeneous and under the influence of interfacial cementation a large portion of water was diverted around the Fe0 and transported outside the PRB. Based on the equilibrium reductions of NO3- and SO4(2-) by Fe0 and mineral precipitation, geochemical modeling predicted a maximum of 49% porosity loss for 5 years of operation. Additionally, modeling showed a spatial distribution of mineral precipitate volumes, with the maximum advancing from the interface toward downgradient with time. This study suggests that water quality monitoring, coupled with hydraulic monitoring and geochemical modeling, can provide a low-cost method for assessing PRB performance.     

水污染治理工程的环境绩效审计

环境绩效审计的作用之一就是检查投入到环境治理上的资金到底发挥了多大的效益.本研究以五里湖综合整治工程效益审计案例为基础,提出环境效益评估的程序,将条件评估法应用于水污染治理工程项目审计案例中,分析了无锡市居民为改善水环境质量和对周边房产的支付意愿,并计算出五里湖水环境改善的效益和周边房产的增值效益.结果表明,综合整治工程实施后会带来可观的经济效益.最后,对条件评估法在政府环境绩效审计中应用存在的问题进行了讨论,以期为政府环境审计提供技术支持.     

粉末活性炭对膜过滤性能的影响

向一体式膜生物反应器中投加粉末活性炭(PAC),可以显著提高膜的过滤性能,有效缓解膜的污染.研究结果表明:投加PAC的吸附作用减少了由于胞外聚合物(EPS)而引起的膜污染;膜表面PAC颗粒的存在减小了浓差极化层的厚度和水力边界层的厚度,提高了过滤物质的传递速率;膜表面形成的PAC层还可过滤微生物和胶体颗粒,减少了它们到达膜表面的数量.     

有机物对SAD的影响及其数学模拟

通过血清瓶批式实验,研究了不同C/N下葡萄糖和乙酸钠对厌氧氨氧化耦合反硝化系统（SAD）污泥活性及脱氮性能的影响.耦合系统颗粒污泥为在亚硝态氮充足的UASB连续流反应器中培养得到,具有较高的厌氧氨氧化活性和反硝化活性.以葡萄糖为碳源,C/N分别为1,2,4时,厌氧氨氧化活性差异不大,反硝化活性逐渐增加,亚硝态氮最大降解速率分别为0.265,0.345,0.453kgN/（kgVSS·d）;以乙酸钠为碳源,C/N分别为1、2、4时,厌氧氨氧化活性和反硝化活性都无明显差别.相同C/N下,耦合系统以葡萄糖为碳源时的厌氧氨氧化活性较高,以乙酸钠为碳源时的反硝化活性较高.C/N分别为1,2,4时,以葡萄糖为有机物的氨氮最大降解速率分别为乙酸钠的1.15,1.19,1.58倍,以乙酸钠为有机物时反应的亚硝态氮最大降解速率分别为葡萄糖的1.89,1.48,1.15倍.实验的数学模拟结果表明,通过模型的模拟,能较为准确地预测实验过程中氮素的变化趋势,在C/N为1~4时耦合系统中颗粒污泥的厌氧氨氧化活性无较大变化.