Solid waste characteristics and their relationship to gas production in tropical landfill

Solid waste characteristics and landfill gas emission rate in tropical landfill was investigated in this study. The experiment was conducted at a pilot landfill cell in Thailand where fresh and two-year-old wastes in the cell were characterized at various depths of 1.5, 3, 4.5 and 6 m. Incoming solid wastes to the landfill were mainly composed of plastic and foam (24.05%). Other major components were food wastes (16.8%) and paper (13.3%). The determination of material components in disposed wastes has shown that the major identifiable components in the wastes were plastic and foam which are resistant to biodegradation. The density of solid waste increased along the depth of the landfill from 240 kg m⁻³ at the top to 1,260 kg m⁻³ at the bottom. Reduction of volatile solids content in waste samples along the depth of landfill suggests that biodegradation of solid waste has taken place to a greater extent at the bottom of the landfill. Gas production rates obtained from anaerobic batch experiment were in agreement with field measurements showing that the rates increased along the depth of the landfill cell. They were found in range between 0.05 and 0.89 l kg⁻¹ volatile solids day⁻¹. Average emission rate of methane through the final cover soil layer was estimated as 23.95 g⁻²day⁻¹ and 1.17 g⁻²day⁻¹ during the dry and rainy seasons, respectively.     

Influence of laneway support spacing on methane/air explosion shock wave

A laneway support system provides an available way to solve problems related to ground movements in underground coal mines, but also poses another potential hazard. Once a methane/air explosion occurs in a laneway, inappropriate design parameters of the support system, especially the support spacing, likely have a negative influence on explosion disaster effects. The commercial software package AutoReaGas, a computational fluid dynamics code suitable for gas explosions, was used to carry out the numerical investigation for the methane/air explosion and blast process in a straight laneway with different support spacing. The validity of the numerical method was verified by the methane/air explosion experiment in a steel tube. Laneway supports can promote the development of turbulence and explosion, and also inhibit the propagation of flame and shock wave. For the design parameters in actual laneway projects, the fluid dynamic drag due to the laneway support plays a predominant role in a methane/air explosion. There is an uneven distribution of the peak overpressure on the same cross section in the laneway, and the largest overpressure is near the laneway walls. Different support spacing can cause obvious differences for the distributions of the shock wave overpressure and impulse. Under comparable conditions, the greater destructive effects of explosion shock wave are seen for the laneway support system with larger spacing. The results presented in this work provide a theoretical basis for the optimized design of the support system in coal laneways and the related safety assessments.     

欧盟甲烷减排战略对我国碳中和的启示

欧盟于2020年10月出台了《欧盟甲烷减排战略》,以支撑其中长期温室气体减排目标。该战略共提出了五个领域的24个行动方案。欧盟将油气行业作为重点,设置了两个强制性的政策来完善能源部门的温室气体监测、报告和核查制度,并禁止天然气放空和燃烧。农业领域以加强全生命周期甲烷排放核算、减排技术等方面研究,编制最佳减排实践和技术清单为主要措施。在废弃物管理领域,欧盟将主要修订废弃物管理方面的立法和废水处理标准并加强监管。全球层面,欧盟提出希望联合包括中国在内的主要油气进口国家,推动建立全球性的监测、报告和核查标准,分享其甲烷超级排放源探测的卫星数据等措施。我国提出2060碳中和愿景后,下一阶段温室气体减排将会从能源相关二氧化碳减排为主扩展到全部温室气体减排。建议我国和欧盟在甲烷减排方面开展广泛合作,借鉴欧盟的经验,尽快制定我国甲烷减排近期、中期、远期目标和行动计划,推广甲烷减排技术,加强科学研究和技术研发,探索在国家碳市场交易体系中纳入甲烷等非二氧化碳气体的时机和方案,鼓励大型能源企业加入国际甲烷减排倡议以提高能力,逐步完善我国甲烷减排相关政策和制度环境,打造我国在低碳领域的经济和技术竞争力。     

Enhanced methane recovery and exoelectrogen-methanogen evolution from low-strength wastewater in an up-flow biofilm reactor with conductive granular graphite fillers

Methane production from low-strength wastewater (LSWW) is generally difficult because of the low metabolism rate of methanogens. Here, an up-flow biofilm reactor equipped with conductive granular graphite (GG) as fillers was developed to enhance direct interspecies electron transfer (DIET) between syntrophic electroactive bacteria and methanogens to stimulate methanogenesis process. Compared to quartz sand fillers, using conductive fillers significantly enhanced methane production and accelerated the start-up stage of biofilm reactor. At HRT of 6 h, the average methane production rate and methane yield of reactor with GG were 0.106 m³/(m³·d) and 74.5 L/kg COD, which increased by 34.3 times and 22.4 times respectively compared with the reactor with common quartz sand fillers. The microbial community analysis revealed that methanogens structure was significantly altered and the archaea that are involved in DIET (such as Methanobacterium) were enriched in GG filler. The beneficial effects of conductive fillers on methane production implied a practical strategy for efficient methane recovery from LSWW.

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Feasibility assessment of up-flow anaerobic sludge blanket treatment of sulfamethoxazole pharmaceutical wastewater

The UASB system successfully treated sulfamethoxazole pharmaceutical wastewater. High concentration sulfate of this wastewater was the main refractory factor. UASB recovery performance after a few days of inflow arrest was studied. The optimal UASB operating conditions for practical application were determined. Treatment of sulfamethoxazole pharmaceutical wastewater is a big challenge. In this study, a series of anaerobic evaluation tests on pharmaceutical wastewater from different operating units was conducted to evaluate the feasibility of using anaerobic digestion, and the results indicated that the key refractory factor for anaerobic treatment of this wastewater was the high sulfate concentration. A laboratory-scale up-flow anaerobic sludge blanket (UASB) reactor was operated for 195 days to investigate the effects of the influent chemical oxygen demand (COD), organic loading rate (OLR), and COD/SO₄^2? ratio on the biodegradation of sulfamethoxazole in pharmaceutical wastewater and the process performance. The electron flow indicated that methanogenesis was still the dominant reaction although sulfidogenesis was enhanced with a stepwise decrease in the influent COD/SO₄^2? ratio. For the treated sulfamethoxazole pharmaceutical wastewater, a COD of 4983 mg/L (diluted by 50%), OLR of 2.5 kg COD/(m³·d), and COD/SO₄^2? ratio of more than 5 were suitable for practical applications. The recovery performance indicated that the system could resume operation quickly even if production was halted for a few days.     

Monitoring of Gin Drinkers' Bay landfill,Hong Kong: I. Landfill gas on top of the landfill

The present study centered on the composition of landfill gas and its effects on soil and plants at the Gin Drinkers' Bay (GDB) landfill in Hong Kong This first part of the study was a whole-year monitoring of landfill gas composition in the gas ventilation system installed on top of the landfill Methane, carbon dioxide, oxygen, and ethylene were measured It was shown that gas generation was positively correlated with the amount of precipitation and air temperature and negatively correlated with atmospheric pressure     

Effects of ignition energy on fire and explosion characteristics of dilute hybrid fuel in ventilation air methane

Deflagration explosions of coal dust clouds and flammable gases are a major safety concern in coal mining industry. Accidental fire and explosion caused by coal dust cloud can impose substantial losses and damages to people and properties in underground coal mines. Hybrid mixtures of methane and coal dust have the potential to reduce the minimum activation energy of a combustion reaction. In this study the Minimum Explosion Concentration (MEC), Over Pressure Rise (OPR), deflagration index for gas and dust hybrid mixtures (K_st) and explosive region of hybrid fuel mixtures present in Ventilation Air Methane (VAM) were investigated. Experiments were carried out according to the ASTM E1226-12 guideline utilising a 20 L spherical shape apparatus specifically designed for this purpose.Resultsobtained from this study have shown that the presence of methane significantly affects explosion characteristics of coal dust clouds. Dilute concentrations of methane, 0.75–1.25%, resulted in coal dust clouds OPR increasing from 0.3 bar to 2.2 bar and boosting the K_st value from 10 bar m s⁻¹ to 25 bar m s⁻¹. The explosion characteristics were also affected by the ignitors’ energy; for instance, for a coal dust cloud concentration of 50 g m⁻³ the OPR recorded was 0.09 bar when a 1 kJ chemical ignitor was used, while, 0.75 bar (OPR) was recorded when a 10 kJ chemical ignitor was used.For the first time, new explosion regions were identified for diluted methane-coal dust cloud mixtures when using 1, 5 and 10 kJ ignitors. Finally, the Le-Chatelier mixing rule was modified to predict the lower explosion limit of methane-coal dust cloud hybrid mixtures considering the energy of the ignitors.     

Explosion prevention and weighting analysis on the inerting effect of methane via grey entropy model

Explosion prevention is vital for process safety and daily life. In practice, inerting is viewed as an ideal method to reach basic explosion prevention as well as to diminish flammability risk in normal operation, storage, and transportation of materials. This study deals with the inerting effect on the explosion range for methane via grey entropy model, comparatively detected under the different inert gases of nitrogen (N₂), argon (Ar), and carbon dioxide (CO₂), which have various loading inerting concentrations: 10 (90 vol% air), 20 (80 vol% air) and 25 vol% (75 vol% air). The inert influences were determined via the experimental 20-L-apparatus investigations under 1 atm, 30 ^OC, combined with the grey entropy model, which is one of the most prevailingly used grey system theories for weighting analysis and decision-making of the fire and explosion assessment for practical operations. The results indicated that CO₂ had better inerting capacity than the others, as derived from our grey entropy theoretical soft computing calculations. Through the combination of the grey entropy weighting analysis model and the flammability investigations in this study, the concluded decision-making was feasible and useful for the practical applications of inert gases for preventing fire and explosion hazards in relevant processes.     

The effect of orifice plates with different shapes on explosion propagation of premixed methane–air in a semi-confined pipeline

The effect of internal shape of obstacles on the deflagration of premixed methane–air (concentration of 10%) was experimentally investigated in a semi-confined steel pipeline (with a square cross section size of 80 mm × 80 mm and 4 m long). The obstacles used in this study were circular, square, triangular and gear-shaped (4-teeth, 6-teeth and 8-teeth) orifice plates with a blockage ratio of 75%, and the perimeter of the orifice was regarded as a criterion for determining the sharpness of the orifice plate. The overpressure history, flame intensity histories, flame front propagation speed, maximum flame intensity and peak explosion overpressure were analyzed. The explosion in the pipeline can be divided into two stages: initial explosion and secondary explosion. The secondary explosion is caused by recoiled flame. The perimeter is positively related to the intensity of the recoiled flame and the ability of orifice plate to suppress the explosion propagation. In addition, the increase in the perimeter will cause the acceleration of the flame passing through the orifice plate, while after the perimeter of the orifice reaches a certain value, the effect of the increase in perimeter on explosion excitation becomes no obvious. The overpressure (static pressure) downstream of the orifice plate is the result of the combined effect of explosion intensity and turbulence. The increase in perimeter leads to the increase in turbulence downstream of the orifice plate which in turn causes more explosion pressure to be converted into dynamic pressure.     

Methane Emissions from Large Dams as Renewable Energy Resources: A Developing Nation Perspective

By means of a theoretical model, bootstrap resampling and data provided by the International Commission On Large Dams (ICOLD (2003) World register of dams. http://www.icold-cigb.org) we found that global large dams might annually release about 104 ± 7.2 Tg CH₄ to the atmosphere through reservoir surfaces, turbines and spillways. Engineering technologies can be implemented to avoid these emissions, and to recover the non-emitted CH₄ for power generation. The immediate benefit of recovering non-emitted CH₄ from large dams for renewable energy production is the mitigation of anthropogenic impacts like the construction of new large dams, the actual CH₄ emissions from large dams, and the use of unsustainable fossil fuels and natural gas reserves. Under the Clean Development Mechanism of the Kyoto Protocol, such technologies can be recognized as promising alternatives for human adaptations to climate change concerning sustainable power generation, particularly in developing nations owning a considerable number of large dams. In view of novel technologies to extract CH₄ from large dams, we estimate that roughly 23 ± 2.6, 2.6 ± 0.2 and 32 ± 5.1 Tg CH₄ could be used as an environmentally sound option for power generation in Brazil, China and India, respectively. For the whole world this number may increase to around 100 ± 6.9 Tg CH₄.