临海航天发射场设施设备腐蚀控制策略研究

针对临海航天发射场设施设备金属结构腐蚀严重的问题,基于金属腐蚀机理,对发射场设施设备的差异性腐蚀损伤进行了统计和梳理,得出腐蚀成因,并提出腐蚀控制策略和研究方向的建议,为进一步提升我国航天发射场维修保障能力提供理论和技术支撑.     

Experimental study on the space charge properties in haze events

In recent years, haze has posed a serious threat to the global climate change, ecological balance and human health. In this study, the laboratory experiments and field observations were performed and a possible charging mechanism was proposed to investigate the space charge properties in haze events. The laboratory experiments showed that the charge polarity of primary aerosol is determined by species of combustion fuels while the magnitude is dependent on the combustion completeness. The field observations revealed that the space charge of atmosphere aerosol in haze events differs from that of fair weather and is closely related to PM_2.5 concentration when Relative Humidity (RH)?<?60%, with 1 to 2 orders of magnitude less than the case when RH?≥?60%. The analysis of equivalent charge-to-mass ratio (ECTM) suggested that in haze events the space charge is governed by primary aerosol emitted by combustion of fossil fuel in a low relative humidity, whereas it is manipulated by the secondary chemical reaction of atmosphere aerosol in a high relative humidity. And we can identify the main pollutants in haze events according to the polarity of atmosphere aerosol and quickly take measures when RH?<?60%. Accordingly, the dust-haze of RH?<?80% can be divided into dry-dust-haze when RH?<?60% and wet-dust-haze when 60%?≤?RH?<?80%. Our study firstly elucidated the space charge properties of atmosphere aerosol in haze events and can provide a new perspective for the prevention and control of air pollution.     

NASA的RIDM风险管理策略及其启示

依据美国国家航空和宇航局(NASA)于2010年4月发布的《基于风险响应的决策方法技术手册》,介绍了NASA采用的基于风险响应的决策方法(RIDM),分析了RIDM风险管理策略的产生背景、运作情况、适用范围、主要特点和成功做法,并对国内开展航天工程项目的风险量化评估以及进行相应领域的风险管理研究提出了若干启示。     

基于三维荧光光谱特征研究土壤腐殖质氧化还原特性

以国际腐殖质协会腐殖酸和实验室提纯腐殖酸为研究对象,发现被H2还原前后腐殖酸的三维荧光光谱明显不同,但有共同的变化趋势:还原态腐殖酸的三维荧光光谱图的波峰荧光强度均明显低于还原前,说明腐殖酸还原过程有类似π-π*化学键断开的结构变化.对苯醌是腐殖酸氧化还原醌基官能团的代表化合物,将其还原前后与腐殖酸还原前后的荧光光谱对比,发现两组变化趋势一致,这一发现是利用荧光特性量化腐殖质氧化还原官能团的基础.利用铁氰化钾测定腐殖酸的得失电子能力,发现不同土壤提纯的腐殖酸得失电子能力有一定差别:鹰潭土壤腐殖酸和桃源土壤腐殖酸在原态下对三价铁的还原能力都较弱,分别为0.998和0.465 meq.g-1C(原态转移电子数);但还原后得电子数(还原态转移电子数减原态转移电子数)分别为3.384 meq.g-1C(鹰潭土壤腐殖酸)和1.187 meq.g-1C(桃源土壤腐殖酸).鹰潭土壤腐殖酸具有较高的得电子数,与其具有较高荧光峰值这一结果互相支持.结合得失电子能力测定,利用光学分析方法,量化官能团,预测氧化还原反应进程,使三维荧光光谱法测定土壤有机质的氧化还原性在实际应用中具有广阔的前景.     

Electrostatic ignition of sensitive flammable mixtures: Is charge generation due to bubble bursting in aqueous solutions a credible hazard?

Experiments have been conducted to gain insight into the credibility of sparging aqueous solutions as an electrostatic ignition hazard for sensitive hydrogen/air or fuel/oxygen mixtures (Minimum Ignition Energies of ∼0.017 mJ and ∼0.002 mJ, respectively, compared to ∼0.25 mJ for hydrocarbon/air mixtures). Tests performed in a 0.5 m³ ullage produced electric field strengths between 125 and 560 V m⁻¹ for air flows of 5–60 l min⁻¹, respectively, comprised of 2–4 mm diameter bubbles. Field strength can be related to the space charge and fitting to an exponential accumulation curve enabled the charge generation rate from the air flows to be estimated. This was observed to be directly proportional to the air flow and its magnitude was consistent with literature data for bubble bursts. The charge accumulation observed at laboratory scale would not be a cause for concern. On the basis of a simple model, the charge accumulation in a 27 m³ ullage was predicted for a range of air flows. It is apparent from such calculations that ignition of hydrocarbon/air mixtures would not be expected. However, it would seem possible that field strengths might be sufficient to cause a risk of incendive spark or corona discharges in moderately sized vessels with sensitive flammable mixtures.     

载人航天空间环境模拟试验安全与措施

载人航天空间环境模拟试验极其危险 ,为了确保参试航天员的生命安全 ,必须对模拟试验设备进行系统配套与完善 ,同时必须事先进行人员培训、制定详细的试验流程 ,进行严密的组织管理。为此 ,重点介绍了为确保参试航天员的安全 ,对试验设备所提出的技术要求 ,以及试验所涉及的训练、演习、试验组织管理等方面的安全措施。     

钢结构暨空间结构的抗火设计综述

钢结构暨空间结构是目前建筑结构的重要发展方向之一。因钢材对高温的敏感性 ,其防火、抗火性能的研究应是设计时考虑的重要因素。笔者简述了抗火与防火的概念及其区别 ;评估了国内外关于抗火设计的基本方法及优缺点 ;重点对整体结构有限元非线性抗火反应全过程分析方法进行了讨论。通过选择科学的抗火设计方法 ,将为经济、适用的防火设计提供重要的依据     

应用地理信息系统进行垃圾填埋场选址的初步研究

在ArcGIS 8.3软件空间分析模块(spatial analysis)支持下,以江苏省长江以南市辖区为研究对象,进行了空间叠加和空间复合查询分析,以确定垃圾填埋场候选区域分布,并同已有的垃圾填埋场监测点进行比较,结果表明,利用地理信息系统技术进行垃圾填埋场辅助分析是可行的.     

Mercury (Hg) emissions from domestic biomass combustion for space heating

Three mercury (Hg) species (gaseous elemental mercury (GEM), gaseous oxidized mercury (GOM), and fine particulate-bound mercury (PBM_2.5)) were measured in the stack of a small scale wood combustion chamber at 400 °C, in the stack of an advanced wood boiler, and in two areas influenced by wood combustion. The low temperature process (lab-scale) emitted mostly GEM (∼99% when burning wood pellets and ∼95% when burning unprocessed wood). The high temperature wood boiler emitted a greater proportion of oxidized Hg (approximately 65%) than the low temperature system. In field measurements, mean PBM_2.5 concentrations at the rural and urban sites in winter were statistically significantly higher than in warmer seasons and were well correlated with Delta-C concentrations, a wood combustion indictor measured by an aethalometer (UV-absorbable carbon minus black carbon). Overall the results suggest that wood combustion may be an important source of oxidized mercury (mostly in the particulate phase) in northern climates in winter.     

基于RS的荒漠景观空间格局的研究

利用ＮＯＡＡ气象卫星五波段遥感数据作主要信息源,经图像增强处理和解译,获得区域景观类型图。在完成景观类型图的数字化输入手,采用景观生态学的方法,对研究区域进行景观空间格局指标的计算机测定,筛选、建立了一套度量景观生态空间格局变化的评价指标体系。