Substance flow analysis of coplanar PCBs released from waste incineration processes

Previous reports have focused on the emission of coplanar polychlorinated biphenyls (Co-PCBs) which have a toxic mechanism similar to that of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDDs/DFs) released from municipal solid waste (MSW) incineration. Such emissions accounted for a small percentage of all the dioxins (PCDDs/DFs and Co-PCBs) recorded at the toxicity equivalent (TEQ) level. There is, however, very little information about Co-PCBs, such as the quantities being released and their effect on overall environmental pollution. The aim of this research has been to clarify the substance flow of Co-PCBs from MSW incineration processes. The results reveal that whereas the input of Co-PCBs into the MSW incineration facilities in Kyoto City was 0.13–0.29 μg-TEQ per ton waste, the total output of Co-PCBs (the sum of Co-PCBs released from emission gas, fly ash, and bottom ash) was 4.9 μg-TEQ per ton waste. The total output was therefore found to be higher than the total input. Over 90% of the total PCBs were decomposed in the incineration process. In comparing the profiles of congeners and homologues, those in the MSW were found to be similar to those detected in the atmosphere and products containing PCBs, but different from those in the MSW incineration gas. Received: August 26, 1998 / Accepted: March 2, 1999     

废线路板处理工艺中持久性有毒物质环境释放特征

以江苏省某示范企业为例,对废线路板退锡和粉碎2个处理阶段的有组织、无组织废气以及废线路板处理余物中的持久性有毒物质(PTS)进行检测,并对其环境释放特征进行分析。结果表明,退锡阶段无组织废气中氯代二噁英类物质的浓度显著高于有组织废气,粉碎阶段有机和无机PTS浓度均高于退锡阶段,无机PTS的环境释放主要为悬浮颗粒物中的Pb、Cd、Cr及其化合物。通过PTS物质流分析可知,无机PTS释放质量分数(0. 0%～22. 0%)高于有机PTS释放质量分数(0. 0%～1. 0%),在金属和非金属粉末中含有大量的有机PTS。提出,采用自动化设施,减少工人的车间工作时间,降低其职业暴露风险,并关注废线路板处理余物的后续使用与处理。     

首都经济圈水资源循环经济模式的探讨

以资源环境经济学、循环经济学作为理论基础,采用实证与规范经济分析法,从理论和实践两个层面系统研究首都经济圈水资源环境,提出水资源循环经济发展模式,用以解决首都经济圈水资源与经济发展的矛盾.重点分析了该区水资源问题及其对国民经济的影响,阐述了以经济手段为主的具体对策,旨在从根本上解决水资源问题,促进区域和谐发展.     

我国应急产业发展动力机制模型研究

调研分析了应急产业有关定义,明确了应急产业的范围;从产业内容、产业发展阶段等角度,分析了应急产业的特点;基于自组织理论和新古典经济理论,结合应急产业特点,建立了应急产业发展动力机制“内切圆”模型。模型中,应急产业的发展动力机制系统包括产业成长的外部动力因素和内部动力因素,其中,外部动力因素包括有市场需求、技术创新、产业政策、产业投资等,内部动力因素包括应急产业内相关企业间的竞争与协作、针对市场失效的产业政策。内部动力因素和外部动力因素之间存在着相互作用,在一定的条件下,外部动力可以与内部动力相互转化。内部和外部动力因素的综合作用,推动应急产业不断发展。     

铀尾矿库WSN安全监控镜像约束域定位算法

铀尾矿库的WSN安全监控监测技术是一门新型领域技术,是实现铀尾矿库安全综合治理的重要前提,定位技术因其能够快速定位事件发生区域的地理位置而成为WSN的关键技术之一。RSSI测距定位技术因其易于实现、成本低等特点而被广泛应用,然而其在铀尾矿库中会受到多径、非视距等因素的影响,远距离得到的RSSI值测距误差较大。为此,提出一种镜像最小通信圆约束域定位算法,未知节点利用多个近距离RSSI测距值生成最小通信圆,以锚节点坐标镜像最小通信圆生成镜像圆,多条件约束形成定位区域进行区域定位。仿真结果表明:多最小通信圆定位效果优于单最小通信圆,且比传统RSSI和RSSI质心算法具有更高的定位精度和较小的误差均方差。     

山西省能源圈辐射的环境效应

根据历年<山西统计年鉴>提供的能源输出数据,分析了1985-2007年间山西省煤炭的输出情况,并借助于GIS软件,分析了2006年山西省煤炭的流向及流量.山西省是一个大的能源辐射基地,每年产出煤炭的三分之二左右供应外省市,在外省市的经济水平、人民生活质量不断得到提升的同时,对于为周边地区的发展做出巨大贡献的能源输出地--山西来说,人均地区生产总值却低于全国平均水平,更低于其能源辐射到的其它省市区.山西省在不断向外省市输出能源的同时,也产生了巨大的环境辐射效应,但这种效应对于山西这个能源输出地来说却是负向的.主要表现在:山西省由于煤炭开采导致空气污染、地下水位下降、地面塌陷等地质灾害,而这些环境压力有三分之二是替煤炭输入地所承担的.输送电力,山西省不仅要承担煤炭开采造成的环境破坏,还要承担火力发电所造成的巨大环境二次污染,仅2007年,山西省生产外调电量就产生381.75×10~4 tSO_2,139.98×10~4 tNO_2,2799.51×10~4 t灰粉.     

Fate of metals contained in waste electrical and electronic equipment in a municipal waste treatment process

In Japan, waste electrical and electronic equipment (WEEE) that is not covered by the recycling laws are treated as municipal solid waste. A part of common metals are recovered during the treatment; however, other metals are rarely recovered and their destinations are not clear. This study investigated the distribution ratios and substance flows of 55 metals contained in WEEE during municipal waste treatment using shredding and separation techniques at a Japanese municipal waste treatment plant. The results revealed that more than half of Cu and most of Al contained in WEEE end up in landfills or dissipate under the current municipal waste treatment system. Among the other metals contained in WEEE, at least 70% of the mass was distributed to the small-grain fraction through the shredding and separation and is to be landfilled. Most kinds of metals were concentrated several fold in the small-grain fraction through the process and therefore the small-grain fraction may be a next target for recovery of metals in terms of both metal content and amount. Separate collection and pre-sorting of small digital products can work as effective way for reducing precious metals and less common metals to be landfilled to some extent; however, much of the total masses of those metals would still end up in landfills and it is also important to consider how to recover and utilize metals contained in other WEEE such as audio/video equipment.     

京津冀都市圈休闲旅游开发研究

随着我国经济发展和旅游需求的增长，休闲旅游消费日益成为我国居民的重要消费构成。京津冀都市圈休闲旅游的发展将有助于提升生活质量，带动相关产业发展，吸引内部休闲客源，提升都市圈及内部城市旅游竞争力，改善区域生态环境。分析了京津冀都市圈经济和旅游发展状况、休闲旅游发展条件、休闲旅游需求变化及开发潜力。在此基础上，论述了休闲地开发布局及相应的策略。     

西藏东南部森林可燃物特点及气候变化对森林火灾的影响

根据西藏林芝地区的DEM数据和植被分布数据分析了该地区可燃物的水平分布和垂直分布规律,并根据火发生纪录分别计算了火发生周期和发生概率,根据火灾高发期的降水和气温数据分析降水和气温的变化趋势,本地区易发生火灾的可燃物主要有高山松云南松林,草甸灌丛,云冷杉林等.该地区的火灾轮回期为17178 a,火发生概率为0.00006,远远低于东北林区,但由于该地区处于高海拔地区,生态系统脆弱,林木蓄积量大,积累能量高,潜在的火强度高.林芝地区夏季降水减少,火灾高发期(2～5月)降水有所增加,但增温明显,气温升高对高海拔地区的影响比低海拔地区更大,对于森林可燃物而言,气温增高使高海拔地区的森林火险增大,森林防火面临的形势更加严峻.     

荒漠能源植物气化发电的环境影响评价

对荒漠生物质气化发电进行LCA评价,建立评价模型,在评价过程中选用了燃煤发电系统为参照。研究结果表明,生物质利用过程没有CO2的排放,整个发电周期中仅原料的生产、运输以及预处理过程消耗能量导致CO2排放,因此生物质气化发电方案的排放量远远小于燃煤方案,减排量达到了87％-94％。生物质发电与燃煤发电相比,对环境污染降低程度的总指数为3．68。生物质能源的开发大大削减了化石能源利用带来的环境污染问题,同时也能够缓解能源危机。