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通过对中国石化仪征化纤股份有限公司(以下简称仪化公司)排放废水中乙醛污染的调查,表明仪化公司排放的含乙醛废水主要产生于聚酯生产过程中的工艺废水,喷淋废水,冲洗地面和其他跑、冒、滴、漏的废水(“清下水”)。1996年-2000年污水处理场日排放含乙醛废水约5.66万t,日排放含乙醛的“清下水”约3万t。排放的乙醛在长江仪征段未检出,在沿山河和胥浦河水中有不同程度的检出和超标,超标率分别为50%和9.1%,最大超标倍数分别为8.88倍和0.14倍。对长江仪征段乙醛污染的影响预测结果为:污水处理场在非正常处理情况下(即直排),其排放的废水将在排污口周围形成长1250m,宽200m的污染带,污染面积为25万m^2。 相似文献
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青藏高原纳木错流域水体总汞的时空分布特征 总被引:6,自引:4,他引:2
为研究青藏高原纳木错流域水体中总汞的时空分布特征,于2007~2010年对纳木错湖表层水及入湖河水进行了采样,检测了其总汞浓度,并分析了总汞浓度与降水量、河水径流量等的关系.结果表明,纳木错表层湖水和河水中的总汞质量浓度均值分别为(1.09±0.73)ng.L-1和(2.87±2.59)ng.L-1,显著低于受到汞污染的水体.近岸带湖水的总汞浓度在季风期远大于非季风期,而其浓度水平和空间变化明显大于湖心区.河水的总汞浓度季节变化明显,表现为季风盛期最高且波动最大,而季风期后最低,这与降水量变化趋势基本一致.对你亚曲的定点观测表明,河水总汞浓度的时间变化与径流量一致.入湖河流总汞浓度的空间分布特征在不同的时间表现不同,这可能是由河流的流域面积、流域内土壤汞本底值及补给方式的差异引起的. 相似文献
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Mikael Hult María Jos Martínez Canet Peter N. Johnston Kazuhisa Komura 《Journal of environmental radioactivity》2002,60(3)
During the JCO-accident in Tokai-mura in 1999, the surrounding village was irradiated by an uncontrolled neutron flux. At some locations in that village, the thermal neutron flux was determined retrospectively by measurement of the very low activity of 51Cr and 60Co in stainless-steel spoons using γ-ray spectrometry in underground laboratories. Activities determined in the HADES underground facility are presented here, together with calibrations performed using a well-defined thermal neutron flux to directly estimate the fluence of thermal neutrons independent of most assumptions. The results show measurable 51Cr in three samples and 60Co in four samples taken from locations at distances of up to 430 m from the accident location despite the elapse of 4 half-lives of 51Cr before measurement. Effects of air transport of the samples were considered and shown to be negligible. 相似文献
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选择某拟建填埋场土壤为研究对象,研究Co在土壤中的静态分配试验和动态迁移,以评价场址的安全性。结果表明:初始质量浓度为5 mg/L时,Co的Kd值为753 mL/g,土壤对Co的吸附模式符合Freundlich模式;核素初始质量浓度的升高导致静态试验Kd值增大;静态试验与动态试验的相互印证说明,可以通过动态试验较好地预测核素在极低放填埋场中的迁移速度;Co在该土壤中的迁移速度小于0.24 m/a,Co在进入地表水前已经衰变至非常低的水平,不会对生物圈造成污染。 相似文献
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NH3-SCR performances were explored to the relationship between structure morphology and physio-chemical properties over low-dimensional ternary Mn-based catalysts prepared by one-step synthesis method.Due to its strong oxidation performance,Sn-MnOx was prone to side reactions between NO,NH3 and O2,resulting in the generation of more NO2 and N2 O,here most of N2 O was driven from the non-selective oxidation of NH3,while ... 相似文献
29.
Jingya SHEN Yuliang SUN Liping HUANG Jinhui YANG 《Frontiers of Environmental Science & Engineering》2015,9(6):1084-1095
Cobalt and copper recovery from aqueous Co(II) and Cu(II) is one critical step for cobalt and copper wastewaters treatment. Previous tests have primarily examined Cu(II) and Co(II) removal in microbial electrolysis cells (MECs) with abiotic cathodes and driven by microbial fuel cell (MFCs). However, Cu(II) and Co(II) removal rates were still slow. Here we report MECs with biocathodes and driven by MFCs where enhanced removal rates of 6.0±0.2 mg?L−1?h−1 for Cu(II) at an initial concentration of 50 mg?L−1 and 5.3±0.4 mg?L−1 h−1 for Co(II) at an initial 40 mg?L−1 were achieved, 1.7 times and 3.3 times as high as those in MECs with abiotic cathodes and driven by MFCs. Species of Cu(II) was reduced to pure copper on the cathodes of MFCs whereas Co(II) was removed associated with microorganisms on the cathodes of the connected MECs. Higher Cu(II) concentrations and smaller working volumes in the cathode chambers of MFCs further improved removal rates of Cu(II) (115.7 mg?L−1?h−1) and Co(II) (6.4 mg?L−1?h−1) with concomitantly achieving hydrogen generation (0.05±0.00 mol?mol−1 COD). Phylogenetic analysis on the biocathodes indicates Proteobacteria dominantly accounted for 67.9% of the total reads, followed by Firmicutes (14.0%), Bacteroidetes (6.1%), Tenericutes (2.5%), Lentisphaerae (1.4%), and Synergistetes (1.0%). This study provides a beneficial attempt to achieve simultaneous enhanced Cu(II) and Co(II) removal, and efficient Cu(II) and Co(II) wastewaters treatment without any external energy consumption. 相似文献
30.
Francesca Quinto Carlo Sabbarese Lidianna Visciano Filippo Terrasi Antonio D'Onofrio 《Journal of environmental radioactivity》2009
137Cs and 60Co, two of the radionuclides more representative of discharges from nuclear facilities, are of interest for radiological protections because of their great mobility in biosphere and affinity with biological systems. The aim of the present work is the investigation of the possible influence of the vertical distribution of 137Cs and 60Co in soil upon their uptake by lettuce as function of plant's growth. An experiment ad hoc has been carried out in field conditions. The results show that (i) the transfer of 137Cs and 60Co from soil to lettuce is independent by their distribution in soil, (ii) the soil–plant transfer factors of 137Cs and 60Co show a similar trend vs. growth stage, (iii) the 40K transfer factor trend is different from those of anthropogenic radionuclides, and (iv) 137Cs and 60Co specific activities are about 1 Bq/kg, in the mature vegetable with soil activity from 9 to 21 kBq/m2. 相似文献