全文获取类型
收费全文 | 614篇 |
免费 | 60篇 |
国内免费 | 91篇 |
专业分类
安全科学 | 78篇 |
废物处理 | 11篇 |
环保管理 | 56篇 |
综合类 | 272篇 |
基础理论 | 63篇 |
污染及防治 | 121篇 |
评价与监测 | 140篇 |
社会与环境 | 17篇 |
灾害及防治 | 7篇 |
出版年
2024年 | 2篇 |
2023年 | 20篇 |
2022年 | 21篇 |
2021年 | 10篇 |
2020年 | 25篇 |
2019年 | 22篇 |
2018年 | 17篇 |
2017年 | 14篇 |
2016年 | 31篇 |
2015年 | 28篇 |
2014年 | 26篇 |
2013年 | 36篇 |
2012年 | 43篇 |
2011年 | 50篇 |
2010年 | 28篇 |
2009年 | 48篇 |
2008年 | 37篇 |
2007年 | 44篇 |
2006年 | 35篇 |
2005年 | 26篇 |
2004年 | 20篇 |
2003年 | 17篇 |
2002年 | 20篇 |
2001年 | 27篇 |
2000年 | 19篇 |
1999年 | 15篇 |
1998年 | 20篇 |
1997年 | 17篇 |
1996年 | 4篇 |
1995年 | 6篇 |
1994年 | 12篇 |
1993年 | 7篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
排序方式: 共有765条查询结果,搜索用时 296 毫秒
101.
Vinzenz Brendler Annett Vahle Thuro Arnold Gert Bernhard Thomas Fanghnel 《Journal of contaminant hydrology》2003,61(1-4):281
This paper presents a digitized version of a thermodynamic sorption database, implemented as a relational database with MS Access. It is mineral-specific and can therefore be used for additive models of complex solid phases such as rocks or soils. An integrated user interface helps users to access selected mineral and sorption data, to extract internally consistent data sets for sorption modeling, and to export them in formats suitable for other modeling software. Data records comprise mineral properties, specific surface area values, surface binding sites' characteristics, sorption ligand information, and surface complexation reactions. An extensive bibliography is included, providing links not only to the above listed data, but also to background information concerning surface complexation model theories, evidence for surface species, and sorption experimental techniques. 相似文献
102.
Shen YH 《Chemosphere》2002,48(10):1075-1079
This study investigates the feasibility of using ethylene oxide chain adsorption to determine the surface area of an expandable clay, montmorillonite. Experimental results indicate that high molecular weight poly(ethylene oxide) or nonionic surfactant with long ethylene oxide chain should be used to provide reasonable estimations for monolayer capacity. The method has advantages over Brunauer, Emmett, and Teller method in that it is readily applicable to a wide range of areas, particularly to 2:1 layer silicates under aqueous conditions. 相似文献
103.
104.
105.
Sorption and desorption of Yb(III) were studied on hematite and on alumina using a surface complexation model. The experimental methodology was conceived to allow an analysis of the data using a constant capacitance model. The FITEQL code was used for the calculations.The experimental results tend to show reversibility of sorption when the surface loading is small, and irreversibility when the surface loading is high. Surface complexation modeling gives a good interpretation of these two phenomena, taking into account hydroxylation of the surface complexes. In these two cases, it is possible to describe sorption and desorption curves with the same surface stoichiometries and the same surface complexation constants. The existence of these surface complexes depends on the pH of the solution, surface loading, and reaction direction. 相似文献
106.
The current approach for modelling ion adsorption onto binary (hydr)oxides using homogeneous surface complexation models involves the assumption of either an ideal mixture of the two surfaces (i.e. two surface sites on one surface) or a patchwise surface (i.e. two surfaces with one surface site on each surface). As the physical truth should be between these two limiting cases, a model which assumes a patchwise surface constituted of three patches is proposed. Two patches represent the distinct (hydr)oxides, and the third one a mixture of these distinct (hydr)oxides. Using the diffuse layer model, the three approaches are applied to literature data for Cd adsorption onto binary mixtures of alumina-coated silica at total constant Cd concentration and varying amounts of alumina coatings. For Cd adsorption onto these binary (hydr)oxide systems, the new approach explains the observed potential effects. The proposed model, which contains two additional adjustable parameters in terms of site concentrations or one adjustable parameter in terms of specific surface area, is more successful than the two limiting cases. The new model is then validated by predicting Ca and Zn behaviour on the same binary (hydr)oxide system. 相似文献
107.
Polycyclic aromatic hydrocarbons in the bulk precipitation and surface waters of Northern Greece 总被引:15,自引:0,他引:15
Bulk (wet and dry) precipitation and surface water sampling was undertaken in the main plain of central Macedonia in Northern Greece. Fourteen polycyclic aromatic hydrocarbons (PAHs) included in the US EPA's priority pollutant list were analysed. The concentrations determined in bulk precipitation were in general within the range of values worldwide reported. Concentrations were highest in the cold months. Deposition fluxes of PAHs were of the same order of magnitude as reported data. The greatest values were found when high concentrations of PAHs in precipitation coincided with large precipitation amounts. The concentrations of PAHs in surface waters (main rivers, tributaries, ditches, etc) were in general lower than those in bulk precipitation, and among the lowest reported for European rivers, excepting Np and Ph. Bulk deposition and domestic effluents are suggested as being the main PAH sources into surface waters. 相似文献
108.
The estrogenic pollutants 4-tert-octylphenol (OP), 4-nonylphenol (NP) and bisphenol A (BPA) were determined in surface water samples from the Haihe River, Tianjin, China. The analytes were extracted and concentrated from 300 ml acidified water samples by liquid–liquid extractions using dichloromethane, derivatized with trifluoroacetic anhydride, and quantified by gas chromatography–mass spectrometry (GC–MS) with selected ion monitoring (SIM). Among the samples collected from 14 sampling sites, only one sample was found to have a relatively high concentration of BPA (8.30 μg l−1) and NP (0.55 μg l−1). The concentrations of OP, NP and BPA in the other samples were in the range of 18.0–20.2, 106–296 and 19.1–106 ng l−1, respectively. Recoveries for OP, NP and BPA in the spiked water samples were all over 80%. 相似文献
109.
Screening 31 endocrine-disrupting pesticides in water and surface sediment samples from Beijing Guanting reservoir 总被引:13,自引:0,他引:13
For screening 31 potential or suspected endocrine-disrupting pesticides in water and surface sediments, a multiresidue analysis method based on gas chromatography with electron capture detection (GC/ECD) was developed. Solid phase extraction (SPE) technology with Oasis® HLB cartridge was also applied in sample extraction. The relevant mean recoveries were 70–103% and 71–103% for water and sediment, respectively. Relative standard deviations (RSD) are 2.0–7.0%, 4.0–8.0% for water and sediment, respectively. Thirty one pesticides (-HCH, β-HCH, γ-HCH, δ-HCH, hexachlorobenzene (HCB), aldrin, heptachlor, endosulfan I & II, p,p′-DDD, o,p′-DDT, p,p′-DDT, p,p′-DDE, endrin aldehyde, endosulfan sulphate, methoxychlor, hepachlor epoxide, -chlordane, γ-chlordane, dieldrin, endrin, dicofol, acetochlor, alachlor, metolachlor, chlorpyriphos, nitrofen, trifluralin, cypermethrin, fenvalerate, deltamethrin) in water and surface sediment samples from Beijing Guanting reservoir were analyzed. Concentrations of pesticides ranged from 7.59 to 36.0 ng g−1 on a dry wt. basis for sediment samples, from 279.3 to 2740 ng l−1 for pore waters and from 48.8 to 890 ng l−1 for water samples, respectively, with a mean concentration of 10.7 ng g−1 in sediment, 735 ng l−1 in pore water and 295 ng l−1 in water, respectively. The data obtained provides information on the levels and sources of endocrine-disrupting pesticides in Guanting reservoir. These results underscore the need to improved environmental protection measures in order to reduce the exposure of the population and aquatic biota to these endocrine-disrupting compounds. 相似文献
110.
几种海藻表面附着细菌的分离及其gyrB基因序列分析 总被引:1,自引:0,他引:1
利用TCBS培养基从三种海藻:孔石莼(Ulva pertusa)、海带苗(Laminaria japonica)和多管藻(Polysiphonia urceolata)表面共分离得到10株细菌.生理生化试验和gyrB基因序列分析结果表明10株细菌都属于弧菌(Vibrio).基于gyrB基因序列构建的系统发生树显示,菌株L5、L6、P7、P8、P10、P11、P12与Vibrio splendidus属于同一分支,序列间相似性为97.5-100%.菌株L4、P9与Vibrio cyclitrophicus属于同一分支,序列间完全一致.菌株U3在系统发生树上独立构成一个分支.本文结果表明不同海藻表面的附着细菌组成也不相同,具有一定的海藻特异性. 相似文献