• K+ hinder the structural degradation of Cu/SAPO-34 under humid condition<100°C.• K+ on Cu/SAPO-34 brings lower acidity and inferior SCR activity at high temperature.• Fe/Beta was used to compensate the low activity of Cu/SAPO-34 at high temperature.• The hybrid catalysts with KCu/SAPO-34 and Fe/Beta show a great potential for using. K ions were introduced onto Cu/SAPO-34 catalysts via the ion-exchange process in order to improve their stability under low-temperature hydrothermal aging. The changes in structure and copper-species contents of these catalysts upon hydrothermal aging were probed in order to investigate their effects on selective catalytic reduction (SCR) activity. For the fresh Cu/SAPO-34 catalysts, K ions had little influence on the chabazite framework but effected their acidities by exchanging with acid sites. After hydrothermal aging, the structural integrity and amount of active sites decreased on pure Cu/SAPO-34. While the K-loaded catalysts showed improved chabazite structure, acidity, and active site conservation with increasing K loading. However, although the 0.7 wt% K catalyst maintained the same crystallinity, active site abundance, and low-temperature SCR activity as the fresh catalyst upon aging, an apparent decrease in SCR activity at high temperature was observed because of the inevitable decrease in the number of Brönsted acid sites. To compensate for the activity disadvantage of K-loaded Cu/SAPO-34 at high temperature, Fe/Beta catalysts were co-employed with K-loaded Cu/SAPO-34, and a wide active temperature window of SCR activity was obtained. Thus, our study reveals that a combined system comprising Fe/Beta and K-loaded Cu/SAPO-34 catalysts shows promise for the elimination of NOx in real-world applications. 相似文献
Biofilm is an effective simultaneous denitrification and in situ sludge reduction system, and the characteristics of different biofilm carrier have important implications for biofilm growth and in situ sludge reduction. In this study, the performance and mechanism of in situ sludge reduction were compared between FSC-SBBR and SC-SBBR with constructed by composite floating spherical carriers (FSC) and multi-faceted polyethylene suspension carriers (SC), respectively. The variation of EPS concentration indicated that the biofilm formation of FSC was faster than SC. Compared with SCSBBR, the FSC-SBBR yielded 0.16 g MLSS/g COD, almost 27.27% less sludge. The average removal rates of COD and NH4+-N were 93.39% and 96.66%, respectively, which were 5.21% and 1.43% higher than the average removal rate of SC-SBBR. Investigation of the mechanisms of sludge reduction revealed that, energy uncoupling metabolism and sludge decay were the main factors for sludge reduction inducing 43.13% and 49.65% less sludge, respectively, in FSC-SBBR. EEM fluorescence spectroscopy and SUVA analysis showed that the hydrolytic capacity of biofilm attached in FSC was stronger than those of SC, and the hydrolysis of EPS released more DOM contributed to lysis-cryptic growth metabolism. In additional, Bacteroidetes and Mizugakiibacter associated with sludge reduction were the dominant phylum and genus in FCS-SBBR. Thus, the effect of simultaneous in situ sludge reduction and pollutant removal in FSC-SBBR was better.
A bioretention unit (BRU) or cell is a green infrastructure practice that is widely used as a low impact development (LID) technique for urban stormwater management. Bioretention is considered a good fit for use in China’s sponge city construction projects. However, studies on bioretention design, which incorporates site-specific environmental and social-economic conditions in China are still very much needed. In this study, an experimental BRU, consisted of two cells planted with Turf grass and Buxus sinica,was tested with eighteen synthesized storm events. Three levels (high, median, low) of flows and concentrations of pollutants (TN, TP and COD) were fed to the BRU and the performance of which was examined. The results showed that the BRU not only delayed and lowered the peak flows but also removed TN, TP and COD in various ways and to different extents. Under the high, medium and low inflow rate conditions, the outflow peaks were delayed for at least 13 minutes and lowered at least 52%. The two cells stored a maximum of 231 mm and 265 mm for turf grass and Buxus sinica, respectively. For both cells the total depth available for storage was 1,220 mm, including a maximum 110 mm deep ponding area. The largest infiltrate rate was 206 mm/h for both cells with different plants. For the eighteen events, TP and COD were removed at least 60% and 42% by mean concentration, and 65% and 49% by total load, respectively. In the reservoir layer, the efficiency ratio of removal of TN, TP and COD were 52%, 8% and 38%, respectively, within 5 days after runoff events stopped. Furthermore, the engineering implication of the hydrological and water quality performances in sponge city construction projects is discussed.
As an environmental friendly measure for surface runoff reduction, low impact development (LID) has been applied successfully in urban areas. However, due to high price of land and additional expense for LID construction in highly urbanized areas, the developers of real estate would not like to proceed LID exploitation. Floor area ratio (FAR) refers to “the ratio of a building’s total floor area to the size of the piece of land upon which it is built.” Increasing FAR indicates that the developers can construct higher buildings and earn more money. By means of awarding FAR, the developers may be willing to practice LID construction. In this study, a new residential district is selected as a case study to analyze the tradeoff between the runoff reduction goal achieving by LID practices and the incentive of awarding FAR to promote LID construction. The System for Urban Stormwater Treatment and Analysis IntegratioN (SUSTAIN) model is applied to simulate the runoff reduction under various LID designs and then derive the Pareto-optimal solutions to achieve urban runoff reduction goals based on cost efficiency. The results indicates that the maximum surface runoff reduction is 20.5%. Under the extremity scenarios, the government has options to award FAR of 0.028, 0.038 and 0.047 and the net benefits developers gain are 0 CNY, one million CNYand two million CNY, respectively. The results provide a LID construction guideline related to awarding FAR, which supports incentive policy making for promoting LID practices in the highly urbanized areas.
It is generally recognised by the disaster risk management and development communities that disasters have a negative impact on development, and indeed can set back development by years. This realisation led to a new paradigm for the management of hazards and their impacts, namely an integrated approach which emphasises disaster risk reduction being incorporated into national development planning. Awareness, however, does not necessarily translate into implementation. ‘Reduce the underlying risk factors’, Priority for Action 4 of The Hyogo Framework for Action 2005–2015, reported the lowest average score for progress of the five priority areas. Challenges to progress, as reported by Governments included inappropriate development practices, high levels of poverty and other factors which increase vulnerability. Various authors have recognised the difficulty of consistently and successfully integrating disaster risk reduction into development planning. This integration is particularly challenging for Small Island Developing States (SIDS) which face high exposure to hazards, vulnerable populations and limited resources, often both human and financial. The efforts of Jamaica, a Caribbean SIDS, at integrating disaster risk reduction into national development, and some factors which proved to be important in making progress are presented here. This retrospective paper is written from the perspective of a participant observer and traces developments in disaster risk management over three decades, 1980–2010. Integration and inclusiveness, use of quantitative methods and application of risk assessments are identified as being important in gaining acceptance for disaster risk reduction. 相似文献
In the past 10 years, both the Wenchuan earthquake (2008, Magnitude?=?8.0) and the Lushan earthquake (2013, Magnitude?=?7.0) struck in the Longmen Shan Fault area, causing extraordinary human and economic losses. After the Wenchuan earthquake, the Chinese government began promoting the Community for Disaster Prevention and Mitigation (CDPM) project nationwide to enhance community-level disaster-resistance capacities. Due to post-earthquake demand, CDPM construction in the Longmen Shan Fault area involved many diverse organisations, each of which had different organisational leadership models, which greatly influenced the CDPM characteristics and mechanisms. From long-term field research in 23 CDPM organisations in Longmen Shan Fault area, four types of CDPM organisations were found, including eight Government-oriented CDPM, six Resident-oriented CDPM, seven NGO-oriented CDPM and two Enterprise-oriented CDPM, forming a multiple organisation-oriented CDPM (M-CDPM) model. As there was only 85?km between the Wenchuan earthquake and the Lushan earthquake epicentres, many of the hardest-hit regions were the same; therefore, most CDPM organisations examined in this study were established after the Wenchuan earthquake and their effectiveness was tested in the Lushan earthquake. Therefore, research on the M-CDPM gives valuable information and provides a practical perspective for community-level disaster risk reduction. 相似文献
