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101.
石油烃污染会对人类生存的环境造成严重危害,地下水系统中石油烃污染物的研究已受到国内外的高度重视。本文针对某石油烃污染场地的污染状况及水文地质条件,利用模拟柱实验研究石油烃中常见组分苯和菲在典型含水层中的迁移转化,实验结果表明,苯和菲在4种含水层介质中(粉砂、中砂、粗砂、砾砂)受到的迁移阻滞作用都是随着粒径的减小而增大。菲在4种介质中的迁移速率要小于苯,说明4种介质对菲的阻滞作用要大于苯。通过检测各模拟柱出水中Fe2+、Fe3+、NH4+-N和NO3--N浓度的变化可知,在苯和菲的砾砂模拟柱中,由于水流速度快,试验周期短,模拟柱内各项指标变化较小,生物作用较弱;而在苯和菲的粗砂、中砂和粉砂模拟柱中,NO3--N浓度减少,NH4+-N和Fe3+含量增加,说明微生物开始利用NO3--N和Fe3+降解苯和菲,微生物对苯和菲在粗砂、中砂和粉砂中的迁移转化过程有显著的作用。 相似文献
102.
Friha Hadj Ammar Najiba Chkir Kamel Zouari Zohra Azzouz-Berriche 《Journal of environmental radioactivity》2010,101(9):681-691
The distributions of 238U and 234U in groundwater from the “Jeffara aquifer” were studied by using alpha spectrometric methods. The concentration ranges of 238U and 234U/238U activity ratios were 1.34 ± 0.17 to 3.43 ± 0.38 ppb, and 1.43 ± 0.23 to 1.82 ± 0.27 respectively. Variations in concentrations can be related not only to lithostratigraphic formations but also to different origins of groundwater. U content of Jeffara are found very similar to those of Continental Intercalaire aquifer in both El Hamma and Chenchou regions, indicating that the Continental Intercalaire is the dominant source of the groundwater. 相似文献
103.
An approach is developed to simulate leaching of a dissolved chemical constituent in the vadose zone of an aquifer. Specifically,
nitrate loading at the water table for different water table depths, for a range of aquifer permeability values, and for different
cases of heterogeneity of the aquifer, are considered. Models from the literature are first used to derive soil–water characteristic
curves (water retention and hydraulic conductivity) from a grain size distribution curve for unsaturated conditions. Given
infiltration from the surface, the initial conditions for the chemical concentration, and the water content profile, leaching
of the chemical in the vadose zone is simulated as a function of both time and depth. The methodology is illustrated for a
permeable aquifer. Simulations are undertaken using a finite element code for saturated and unsaturated flow. Different scenarios
are simulated depending on the heterogeneity of the aquifer and the depth of the water table. Modeling results show that in
the example case studied, nitrate concentration loading at the water table does not depend strongly on the position of the
water table, but rather on the material properties of the aquifer. The contribution of this endeavor resides in the methodology
which allows a prediction of nitrate leaching using only the grain size property of the aquifer. It allows practitioners to
obtain a first assessment of leaching with limited data. 相似文献
104.
Hilke Würdemann Fabian Mller Michael Kühn Wolfgang Heidug Niels Peter Christensen Günter Borm Frank R. Schilling the COSINK Group 《International Journal of Greenhouse Gas Control》2010,4(6):938-951
The CO2SINK pilot project at Ketzin is aimed at a better understanding of geological CO2 storage operation in a saline aquifer. The reservoir consists of fluvial deposits with average permeability ranging between 50 and 100 mDarcy. The main focus of CO2SINK is developing and testing of monitoring and verification technologies. All wells, one for injection and two for observation, are equipped with smart casings (sensors behind casing, facing the rocks) containing a Distributed Temperature Sensing (DTS) and electrodes for Electrical Resistivity Tomography (ERT). The in-hole Gas Membrane Sensors (GMS) observed the arrival of tracers and CO2 with high temporal resolution. Geophysical monitoring includes Moving Source Profiling (MSP), Vertical Seismic Profiling (VSP), crosshole, star and 4-D seismic experiments. Numerical models are benchmarked via the monitoring results indicating a sufficient match between observation and prediction, at least for the arrival of CO2 at the first observation well. Downhole samples of brine showed changes in the fluid composition and biocenosis. First monitoring results indicate anisotropic flow of CO2 coinciding with the “on-time” arrival of CO2 at observation well one (Ktzi 200) and the later arrival at observation well two (Ktzi 202). A risk assessment was performed prior to the start of injection. After one year of operations about 18,000 t of CO2 were injected safely. 相似文献
105.
A method for quick assessment of CO2 storage capacity in closed and semi-closed saline formations 总被引:1,自引:0,他引:1
Quanlin Zhou Jens T. Birkholzer Chin-Fu Tsang Jonny Rutqvist 《International Journal of Greenhouse Gas Control》2008,2(4):626
Saline aquifers of high permeability bounded by overlying/underlying seals may be surrounded laterally by low-permeability zones, possibly caused by natural heterogeneity and/or faulting. Carbon dioxide (CO2) injection into and storage in such “closed” systems with impervious seals, or “semi-closed” systems with non-ideal (low permeability) seals, is different from that in “open” systems, from which the displaced brine can easily escape laterally. In closed or semi-closed systems, the pressure buildup caused by continuous industrial-scale CO2 injection may have a limiting effect on CO2 storage capacity, because geomechanical damage caused by overpressure needs to be avoided. In this research, a simple analytical method was developed for the quick assessment of the CO2 storage capacity in such closed and semi-closed systems. This quick-assessment method is based on the fact that native brine (of an equivalent volume) displaced by the cumulative injected CO2 occupies additional pore volume within the storage formation and the seals, provided by pore and brine compressibility in response to pressure buildup. With non-ideal seals, brine may also leak through the seals into overlying/underlying formations. The quick-assessment method calculates these brine displacement contributions in response to an estimated average pressure buildup in the storage reservoir. The CO2 storage capacity and the transient domain-averaged pressure buildup estimated through the quick-assessment method were compared with the “true” values obtained using detailed numerical simulations of CO2 and brine transport in a two-dimensional radial system. The good agreement indicates that the proposed method can produce reasonable approximations for storage–formation–seal systems of various geometric and hydrogeological properties. 相似文献
106.
The Seymour aquifer region of Texas has been identified as containing elevated levels of nitrate in ground water. Various state and federal agencies are currently studying policy options for the region by gathering more site-specific information. However, because of lack of sufficient information, cause and effect relationships between water quality and agricultural practices have not been well established for the region. Some recently available biophysical simulation models have impressive capabilities in generating large amounts of data on environmental pollution resulting from agricultural production practices. In this study, the data generated by a biophysical simulation model were used to estimate the nitrate percolation response functions for the Seymour aquifer region. Interestingly, nitrate percolation values obtained from simulation models often comprise acensoredsample because the non-zero percolation values are only observed under certain climatic events and input levels. It has been shown in the econometric literature that the use of Ordinary Least Squares (OLS) on censored sample data produces biased and inconsistent parameter estimates. Thus, a sample selection model was used in this study to estimate the response functions for nitrate percolation. The study provides some insight into the relationship between nitrate percolation and agricultural production practices. In particular, the study demonstrates the potential of selected design standards in minimizing agricultural nonpoint-source (NPS) pollution for the study area. 相似文献
107.
108.
109.
R. Stuart Haszeldine 《Mitigation and Adaptation Strategies for Global Change》2006,11(2):369-393
The principles of hydrocarbon exploration and production provide well-established and tested principles and technologies to
investigate storage of fluids in the subsurface. CO2 can be stored in the subsurface using settings of: (A) thick permeable coal seams; (B) depleted oil and gas fields; (C) saline
aquifers of regional extent, with an overlying seal. The North Sea Sleipner project shows that CO2 can be injected into the pore space of deep geological aquifers deeper than 800 m at 1 Mt/yr, using established technology.
Suitable sediment sequences of saline aquifers exist in all hydrocarbon-producing areas, are volumetrically much larger than
exploited oil and gas fields, and hold the potential to easily store all worldwide CO2 emissions until 2050. Geological principles are established to assess entire continents for candidate sites of CO2 storage. This shows that opportunity may be widespread, but needs more specific local investigations. Onshore sub-Saharan
Africa is considered the most problematic region – but even here there are potentially viable sediment sequences. No demonstration
projects currently exist for CO2 capture and storage using small-scale onshore facilities. A simple estimate, assuming CO2 value of $20 per ton, suggests that single boreholes onshore may be viable over 20 years with supply rates of 100,000 ton
CO2 per year. In principle, atmospheric CO2 could be captured by cultivated biomass, and co-fired in existing power stations. Or energy crops could be grown, CO2 to be used, and stored deep below ground, in a country distant from an original fossil-fuel CO2 emission site. 相似文献
110.