催化铁内电解法+CAST法处理制革综合废水的研究

采用以催化铁内电解法联合CAST法处理制革综合废水,当进水ρ(SS),ρ(BOD5),ρ(CODCr),ρ(TCr),ρ(S2-),色度分别为2120mg·L-1,648mg·L-1,1240mg·L-1,96.2mg·L-1,113.8mg·L-1,840倍时,出水82mg·L-1,32mg·L-1,78mg·L-1,0.6mg·L-1,0.3mg·L-1,8倍,出水水质稳定能够达到二级排放标准。此工艺操作简便,造价低廉,适用中小型制革企业的废水处理。     

黄土高原降水的季节性指标及其与作物水分亏缺的关系

黄土高原位于我国东部季风区与西部非季风区之过渡地区,属弱季风区,降水相对较集中。为分析本区降水的时空分布,文中采用矢量合成方法计算了黄土高原296个站的降水季节性指标值及降水季节,前者变化于0.44—0.64 之间,后者集中于7月中、下旬至8月上旬,自东南向西北推迟。降水的季节性指标与降水季节直接影响到作物水分的亏缺量,全区小麦严重缺水100—200mm 不等,玉米缺水30—50mm,而谷子生育期中水分需求基本可以得到满足。最后,讨论了本区降水与土壤水分含量的关系,指出本区水分不足,认为有的作者提出的该区尚有80％的水分潜力没有得到发挥的见解是错误的。     

中国PM2.5污染状况和污染特征的研究

近１０ 余年来在中国的城市地区和清洁地区进行了ＰＭ２－５ 的采集和分析，其中包括ＰＭ２－５ 的质量浓度、离子和元素成分、酸度和酸化缓冲能力以及来源解析，研究结果表明，中国大部分地区ＰＭ２－５ 的污染较重，不论是质量浓度，还是各种主要成分浓度，在ＴＳＰ 和ＰＭ１０ 中都占有很高的比重，而ＰＭ２－５ 的酸度也远远高于ＴＳＰ 和ＰＭ１０ ，特别是近年来ＰＭ２－５ 污染还有相对加剧的趋势     

碳酸盐对铜离子在黄土中吸持及形态影响的实验研究

选用黄土和重金属Cu为研究对象，通过等温吸持实验和Tessier形态提取实验，研究了碳酸盐对铜离子在黄土中吸持及形态的影响。结果表明：黄土去除碳酸盐后，其吸持铜离子的量大幅度降低；碳酸盐结合态、铁锰氧化物结合态和有机质结合态铜含量明显降低，而可交换态铜含量显著增加。     

化学沉淀法去除垃圾渗滤液中氨氮的试验研究

采用MgCl2·6H2O和Na2HPO4·12H2O或MgSO4和Na2HPO4·12H2O使NH3-N生成磷酸铵镁的化学沉淀法,考察了pH值,反应时间,药剂选用,药剂配比以及分步沉淀工艺等对垃圾渗滤液中氨氮去除率的影响.结果表明:在pH值为9.0,反应时间为25min,采用分步沉淀工艺,当药剂配比为:n(N):n(Mg):n(P)=1.5:1:1.5时,垃圾渗滤液中NH3-N, 沉淀降低到28.54 mg·l-1,去除率达98.10%.     

DETECTABILITY OF STEP TRENDS IN THE RATE OF ATMOSPHERIC DEPOSITION OF SULFATE1

A method is presented to assist policy makers in determining the combination of number of sampling stations and number of years of sampling necessary to state with a given probability that a step reduction in atmospheric deposition rates of a given magnitude has occurred at a pre-specified time. This pre-specified time would typically be the time at which a sulfate emission control program took effect, and the given magnitude of reduction is some percentage change in deposition rate one might expect to occur as a result of the emission control. In order to determine this probability of detection, a stochastic model of sulfate deposition rates is developed, based on New York State bulk collection network data. The model considers the effect of variation in precipitation, seasonal variations, serial correlation, and site-to-site (cross) correlation. A nonparametric statistical test which is well suited to detection of step changes in such multi-site data sets is developed. It is related to the Mann-Whitney Rank-Sum test. The test is used in Monte Carlo simulations along with the stochastic model to derive statistical power functions. These power functions describe the probability of detecting (α=0.05) a step trend in deposition rate as a function of the size of the step-trend, record length before and after the step-trend, and the number of stations sampled. The results show that, for an area the size of New York State, very little power is gained by increasing the number of stations beyond about eight. The results allow policy makers to determine the tradeoff between the cost of monitoring and time required to detect a step-trend of a given magnitude with a given probability.     

CHEMICAL COMPOSITION OF SOFTWATER FLORIDA LAKES AND THEIR SENSITIVITY TO ACID PRECIPITATION1

ABSTRACT: Based on alkalinity data for 596 lakes, 31 percent of Florida's 7300 lakes have < 100 μeq/l alkalinity and are sensitive to acid depostion. More than two-thirds of the lakes in 12 northern Florida counties fit this criterion. Increasing aluminum and decreasing nutrient and chlorophyll a concentrations were observed with decressing pH in a survery of 20 softwater lakes. Maximum measured aluminum values (100-150 μg/L) are below levels asociated with fish toxicity. Factor analysis showed that lake chemistry was related to three principal factors, representing three major processes: watershed weathering, acidification, and nutrient inputs. An acidification index defined as the difference between excess SO₄^2- and excess (Ca²⁺+Mg²⁺) accounted for 74 percent of the variance in lake pH. Comparison of historical (late 1950a) and present data for pH, alkalinity, and excess SO₄^2- indicated loss of alkalinity (>25 μeq/L) and increase in excess SO₄^2- (16-34 μeq/L) in several softwater lakes.     

ATMOSPHERIC CONTRIBUTIONS TO FOREST NUTRIENT CYCLING1

The atmosphere is a significant source of plant nutrients that partially replenishes losses due to timber harvesting. The relative importance of wet and dry deposition depends upon the specific nutrient and site. Nitrogen in bulk precipitation (wetfall and dryfall) is equivalent to at least 70 percent of the nitrogen incorporated annually in above-ground woody tissues of some temperate hardwood forests. Atmospheric sources of calcium and potassium supply between 20 and 40 percent of the nutrients sequestered in woody increments. Annual nutrient inputs in bulk precipitation can exceed removals associated with sawiog harvest over a rotation period. Atmospheric inputs of nitrogen are only slightly less than hydrologic losses immediately after timber harvesting. The deposition of nutrients is highly variable in both time and space; interpretations of nutrient inputs and forest management impacts require quantification of inputs for a variety of ecosystems over long periods of time.     

FLOOD INUNDATION IN THE SOUTHEASTERN UNITED STATES FROM AIRCRAFT AND SATELLITE IMAGERY1

ABSTRACT: Panchromatic black and white, color, and color infrared photographs and thermal infrared imagery are compared for a capability to show flood boundaries. In open agricultural and urban areas, these boundaries are easily delineated on all types of am. Boundaries are more difficult to see in wooded areas. In March, hardwood trees are dormant, but black and white photographs and color photographs show only the tops of these trees. Color infrared photographs in January and March have a distinctive color or tone in inundated woods; the limit of this tone is the flood boundary. Daytime thermal infrared imagery in March shows that inundated woods are cooler than dry land but warmer than open water. After about April 1, both color infrared photography and thermal infrared imagery show only the top of the tree canopy and do not reflect underlying flood water. Inundated areas can be delineated easily on ERTS satellite imagery from December through March. On imagery from May 4–5, 1973, however, most inundation boundaries had to be drawn as dashed lines; the tree canopy obscures flood waters in wooded areas. Despite this problem, the results of mapping flood boundaries on May imagery are believed to be reasonable for the scale of the imagery.     

UNCERTAINTIES IN ESTIMATING THE WATER BALANCE OF LAKES1

ABSTRACT: Evaluation of hydrologic methodology used in a number of water balance studies of lakes in the United States shows that most of these studies calculate one or more terms of the budget as the residual. A literature review was made of studies in which the primary purpose was error analysis of hydrologic measurement and interpretation. Estimates of precipitation can have a wide range of error, depending on the gage placement, gage spacing, and areal averaging technique. Errors in measurement of individual storms can be as high as 75 percent. Errors in short term averages are commonly in the 15-30 percent range, but decrease to about 5 percent or less for annual estimates. Errors in estimates of evaporation can also vary widely depending on instrumentation and methodology. The energy budget is the most accurate method of calculating evaporation; errors are in the 10–15 percent range. If pans are used that are located a distance from the lake of interest, errors can be considerable. Annual pan-to-lake coefficients should not be used for monthly estimates of evaporation because they differ from the commonly used coefficient of 0.7 by more than 100 percent. Errors in estimates of stream discharge are often considered to be within 5 percent. If the measuring section, type of flow profile, and other considerations, such as stage discharge relationship, are less than ideal errors in estimates of stream discharge can be considerably greater than 5 percent. Errors in estimating overland (nonchannelized) flow have not been evaluated, and in most lake studies this component is not mentioned. Comparison of several lake water balances in which the risdual consists solely of errors in measurement, shows that such a residual, if interpreted as ground water, can differ from an independent estimate of ground water by more than 100 percent.