煤中掺比伴生硫化物的自燃特性分析

为了深入探究矿井下伴生硫化物对煤自燃及着火燃烧特性的影响，向原煤中添加不同量的含硫物配制4种不同含硫量的煤样，通过TG实验、DSC测试和XRD分析，研究伴生硫化物对煤自燃及着火燃烧特性的影响规律；基于Coats-Redfern法计算煤中掺加不同伴生硫化物时煤燃烧阶段的活化能。研究结果表明:随着煤中掺比伴生硫化物的增多，煤的特征温度相应减小，而吸氧量、可燃和稳燃指数相应增大，原煤中混入伴生硫化物后更易自燃；随着煤中掺比伴生硫化物的增多，煤燃烧阶段的活化能降低，煤更易着火燃烧；伴生硫化物的主要成分为水绿矾、叶绿矾，这些物质在常温下遇水和氧气能够发生化学循环反应，反应放热促使了煤更易自燃；伴生硫化物在温度高于200℃以后整体表现为放热，在温度为565℃时达到放热峰值，这使得煤燃烧阶段的活化能降低，煤更易燃烧。     

Determination of biogas generation potential as a renewable energy source from supermarket wastes

Fruit, vegetable, flower waste (FVFW), dairy products waste (DPW), meat waste (MW) and sugar waste (SW) obtained from a supermarket chain were anaerobically digested, in order to recover methane as a source of renewable energy. Batch mesophilic anaerobic reactors were run at total solids (TS) ratios of 5%, 8% and 10%. The highest methane yield of 0.44 L CH₄/g VS_added was obtained from anaerobic digestion of wastes (FVFW + DPW + MW + SW) at 10% TS, with 66.4% of methane (CH₄) composition in biogas. Anaerobic digestion of mixed wastes at 5% and 8% TS provided slightly lower methane yields of 0.41 and 0.40 L CH₄/g VS_added, respectively. When the wastes were digested alone without co-substrate addition, the highest methane yield of 0.40 L CH₄/g VS_added was obtained from FVFW at 5% TS. Generally, although the volatile solids (VS) conversion percentages seemed low during the experiments, higher methane yields could be obtained from anaerobic digestion of supermarket wastes. A suitable carbon/nitrogen (C/N) ratio, proper adjustment of the buffering capacity and the addition of essential trace nutrients (such as Ni) could improve VS conversion and biogas production yields significantly.     

加快废钢产业发展 促进钢铁资源循环利用

分析了废钢的应用现状及应用不足的原因，为加快废钢产业发展提出建议。提出为适应当今钢铁工业节能、降耗、环保等方面的发展要求，应大力发展废钢产业，加快废钢资源利用，促进钢铁资源循环利用，实现我国钢铁工业的可持续发展．     

Fuelwood assessment at micro-watershed level in Northeast Himalaya:a case study in Manipur,India

Fuelwood is one of the major sources of energy in the domestic sector across the rural areas,especially in the developing regions across the world.The Northeastern Himalayan state of Manipur is dominated by the tribal population that largely depends on fuelwood from the nearby forest area.The entire dependence on forests for energy resources is affecting the sustainability of the forest ecosystem in the region,thus indicating the livelihood conditions.Since land-use land-cover change is the key driver to the change in resource availability of a region,the present study has tried to analyze the landcover changes over a period 28 years.The second major component affecting resource availability is the increasing population pressure that leads to changes in the land dynamics,which directly affect the resource production.Based on the existing consumption pattern,the total consumption of fuelwood in the watershed ranges fiom a minimum of 289.992 tons/year to a maximum of 3545.719 tons/year with an average of 1561.956 tons/year in the year 2009 and simulated fuelwood consumption for the year 2021 is around 1469.260 tons/year.Nine different probable scenarios of resource are proposed to calculate the stress value that can be used by the policy-makers and planners for suitable policy implementation at the micro level with a complex social system.     

Application of integrated micro sensor in internal measurement of high temperature fuel cell

This study developed an integrated (flow, voltage, and temperature) micro sensor using the micro-electro-mechanical systems (MEMS) technology. It was inserted into the high temperature proton exchange membrane fuel cell (HT-PEMFC) for local real-time measurement. The integrated micro sensor is made of 40 µm thick stainless steel base material, and its protective layer is formed by polyimide (PI) that has better temperature resistance. The integrated micro sensor has three functions, and is favorably characterized by small size, good acid resistance and temperature resistance, quick response, real-time measurement, and being able to be put in any place for measurement. After calibration, and its reliability confirmed, the integrated micro sensor is inserted into the HT-PEMFC for local microcosmic measurement.     

能源革命背景下中国能源系统转型的挑战与对策研究

目前全球能源系统转型正处于化石能源阶段通向第三次能源系统转型的入口。基于第三次能源革命的特点和我国目前以煤炭为主、油气为辅的化石能源系统未来发展趋势,中国第三次能源系统转型是一次"新能源革命"。本文通过分析全球能源系统转型的观点、特点来探索中国能源系统转型的方向与目标,并提出中国能源系统转型在产业技术、电力系统弹性、管理体制和社会公众参与方面面临的挑战。为此,近期中国要实现"十三五"(2016—2020年)新能源目标和2030年减碳目标,需要做好五方面的工作;①做好需求响应分析,加大新能源产业技术政策支持力度;②整合新能源产业管理职能,以提高能源系统的弹性;③拓宽新能源企业的融资渠道,参与全球碳排放限额交易市场;④推进新能源相关立法并提高规划的时效性和协调性;⑤提高政策决策透明度,增强能源革命公众参与度。     

中国经济增长与能源消耗的脱钩——东部地区的时空分异研究

工业时代的经济增长是以大量消耗能源为代价的,直接导致环境污染和资源枯竭。将经济增速与环境压力脱钩的同时,实现将人类福祉与资源消耗的脱钩,是实现绿色可持续发展的焦点问题。采用Tapio基本模型构建中国能源消耗与经济增长的脱钩模型,将1979-2014年的脱钩指数划分为8种脱钩类型。结果说明,绝对而稳态的脱钩是不存在的。虽然大部分年份的中国处于弱脱钩状态,但长时间尺度上,经济增长与能源消耗存在"连接-脱钩-复钩-再脱钩"的动态反复过程。以中国东部地区10省份为例,研究脱钩指数变化的趋势和时间分异情况。结果显示,进入21世纪后该地区复钩的可能性不断增加,特别在经济增速趋缓的背景下,需要警惕以能源消耗驱动经济发展的模式重现。计算并比较脱钩指数的5年均值,研究中国东部地区脱钩的空间分异情况。结果表明,经济增长与能源消耗是否脱钩与宏观政策的调整密切相关。不断提高利用效率以减少能源消耗总量,保持弱脱钩是中国经济发展与能源消耗关系的常态。     

Simulation Study of a PEM Fuel Cell System with Steam Reforming

Abstract

This article summarizes the results of a study for a 100 kWe DC electrical power PEM fuel cell system. The system consists of a pre-steam reformer, a steam reformer, high and low temperature shift reactors, a preferential oxidation reactor, a PEM fuel cell, a combustor, and an expander. Acceptable net electrical efficiency levels can be achieved via intensive heat integration within the PEM fuel cell system. The calculations take into account the auxiliary equipment such as pumps, com pressors, heaters, coolers, heat exchangers and pipes. The process simulation package “Aspen-HYSYS 3.1’’ has been used. The operation parameters of the reactors have been determined considering all the technical limitations involved. A gasoline type hydrocarbon fuel has been studied as hydrogen rich gas source. Thermal efficiencies have been calculated for all of the major system components for selected operation conditions. The fuel cell stack efficiency has been calculated as a function of cell numbers (500, 750, 1000, and 1250 cells). Efficiencies of all of the major system components along with auxiliary unit efficiencies determine the net electrical efficiency of the PEM fuel cell system. The obtained net electrical efficiency levels are between 34 (500 cells) to 41% (1250 cells).     

双赢目标约束下中国能源结构调整测算

中国碳排放的主要来源是能源消费,能源消费又是经济增长的重要驱动因素,因而如何进行能源结构调整成为我国能否如期实现经济增长和碳减排双赢目标的关键。考虑技术进步的动态条件,基于1991-2013年中国的数据,采用超越对数生产函数对我国GDP增长中不同能源要素的贡献率进行了分解,并在2020年实现双赢目标的约束下,对不同能源2014-2020年期间的增长率在技术进步动态条件下进行了估算,分析了实现双赢目标的路径条件。研究结果显示:1综合要素、煤炭、石油、天然气、非化石能源等驱动因素1991-2013年期间对GDP的年均贡献率分别为:36.38%、13.03%、16.99%、12.00%、21.60%,中国经济增长对能源投入的依赖较强;2煤炭、石油、天然气对非化石能源的替代弹性较小,可替代性较差,但非化石能源对煤炭的替代弹性从2007年开始逐步增大,同时,煤炭、石油利用的技术进步慢于非化石能源,这有利于我国双赢目标的实现;3为实现2020年的双赢目标,煤炭、石油、天然气和非化石能源2020年的投入量需要比2013年分别增长26.43%、26.92%、57.53%、64.27%,2020年的能源消费结构比例为:0.63∶0.18∶0.07∶0.12,各种能源增长幅度不同,保持平稳调整;4在双赢目标约束条件下,从非化石能源、煤炭、石油、天然气四种能源角度分析了实现该目标的路径条件。从整体上看,在技术进步推动下,到2020年中国可以实现经济年均增长7%、碳排放强度下降44%的双赢目标。     

基于能值的中国农业绿色经济增长与空间收敛

构造合理的评价指标,对农业绿色经济增长现状及其演变进行客观评估与分析,是实现传统农业向绿色农业转变,促进农业经济可持续发展的迫切要求。本文基于能值理论,对2003—2014年中国及各省域单元农业绿色GDP进行了测算,在此基础上,利用空间分析方法研究我国农业绿色经济增长的空间格局与收敛特征。结果表明:1相较于传统农业GDP,中国人均农业绿色GDP增长相对缓慢,农业绿色GDP占农业传统GDP的比重在80%—85%之间,并呈下降趋势。2我国农业绿色经济增长存在显著的空间集聚,且集聚效应逐渐增强。3人均农业绿色GDP并未打破传统经济增长东部高、西部低的整体格局。东部经济发达地区更高的农业生产效率和西部相对粗放的生产方式是形成这种空间格局的主要原因。4农业人均绿色GDP的收敛分析适用于空间误差自回归模型,考虑了空间自相关因素后得出的收敛速度快于普通收敛分析的收敛速度。因此,准确评价农业经济增长水平需要充分考虑农业增长中的资源环境代价。在今后的发展过程中,我国应实施差别化的农业绿色发展政策,经济发达地区需要进一步减少农业经济增长中的资源环境成本,在继续扩大高增长优势下,促进农业发展的绿色转型。而欠发达地区则应在稳定粮食生产的同时更加注重生态环境保护,努力实现整体跨越式发展。各地区还应加快现代农业技术的转移与扩散,通过增强技术知识的空间溢出效应来提高农业绿色经济增长的收敛速度,尤其是农业发展落后地区应加强与先进地区的交流合作,大力引进先进的农业生产技术与管理经验,提升人力资本水平,以逐步缩小差距,促进农业绿色经济的协调发展。