The structure of the fire fighting foam surfactant Forafac®1157 and its biological and photolytic transformation products

For several decades, perfluorooctane sulfonate (PFOS) has widely been used as a fluorinated surfactant in aqueous film forming foams used as hydrocarbon fuel fire extinguishers. Due to concerns regarding its environmental persistence and toxicological effects, PFOS has recently been replaced by novel fluorinated surfactants such as Forafac®1157, developed by the DuPont company. The major component of Forafac®1157 is a 6:2 fluorotelomer sulfonamide alkylbetaine (6:2 FTAB), and a link between the trade name and the exact chemical structure is presented here to the scientific community for the first time. In the present work, the structure of the 6:2 FTAB was elucidated by ¹H, ¹³C and ¹⁹F nuclear magnetic resonance spectroscopy and high-resolution mass spectrometry. Moreover, its major metabolites from blue mussel (Mytilus edulis) and turbot (Scophthalmus maximus) and its photolytic transformation products were identified. Contrary to what has earlier been observed for PFOS, the 6:2 FTAB was extensively metabolized by blue mussel and turbot exposed to Forafac®1157. The major metabolite was a deacetylated betaine species, from which mono- and di-demethylated metabolites also were formed. Another abundant metabolite was the 6:2 fluorotelomer sulfonamide. In another experiment, Forafac®1157 was subjected to UV-light induced photolysis. The experimental conditions aimed to simulate Arctic conditions and the deacetylated species was again the primary transformation product of 6:2 FTAB. A 6:2 fluorotelomer sulfonamide was also formed along with a non-identified transformation product. The environmental presence of most of the metabolites and transformation products was qualitatively demonstrated by analysis of soil samples taken in close proximity to an airport fire training facility.     

Radionuclide transfer to animal products: revised recommended transfer coefficient values

A compilation has been undertaken of data which can be used to derive animal product transfer coefficients for radionuclides, including an extensive review of Russian language information. The resultant database has been used to provide recommended transfer coefficient values for a range of radionuclides to (i) cow, sheep and goat milk, (ii) meat (muscle) of cattle, sheep, goats, pigs and poultry and (iii) eggs. The values are used in a new IAEA handbook on transfer parameters which replaces that referred to as ‘TRS 364’. The paper outlines the approaches and procedures used to identify and collate data, and assumptions used. There are notable differences between the TRS 364 ‘expected’ values and the recommended values in the revised Handbook from the new database. Of the recommended values, three milk values are at least an order of magnitude higher than the TRS 364 values (Cr, Pu (cow) Pu (sheep)) and one milk value is lower (Ni (cow)). For meat, four values (Am, Cd, Sb (beef) I (pork)) are at least an order of magnitude higher than the TRS 364 values and eight values are at least an order of magnitude lower (Ru, Pu (beef), Ru, Sr, Zn (sheep), Ru, Sr (pork), Mn (poultry)). Many data gaps remain.     

养生小镇旅游产品开发研究——以昆明市永定镇为例

养生旅游作为一种旅游新业态,是旅游业发展到一定阶段的一种新型旅游模式。昆明市永定镇具有优越的环境条件、资源条件和市场条件,适合打造成为发展养生旅游的养生小镇。永定镇养生旅游产品开发主要以"医疗昆明市养生"和"休闲养生"为核心产品,其产品价值表现为构筑核心竞争力;以"运动养生"、"农事养生"和"佛教养生"为重点产品,其产品价值表现为丰富养生旅游产品;以观光农业、康体运动和健康科普为配套产品,其产品价值表现为搭建养生旅游的基础平台。     

Facilitating substance phase‐out through material information systems and improving environmental impacts in the recycling stage of a product

The amount of electrical and electronic products is increasing rapidly, and this inevitably leads to the generation of large quantities of waste from these goods. Some of the generated e‐waste ends up in regions with sub‐standard recycling systems and may be processed under poor conditions. During uncontrolled incineration, halogenated dioxins and furans can be generated from brominated and chlorinated compounds in the products. In order to reduce the health and environmental risks involved in the recycling stage of the life cycle of electronics, an effective design‐for‐environment process must be established during the product development phase. Knowledge of the chemical substances in the product is crucial to being able to make informed decisions. Through full knowledge of the material content of procured components, phase‐outs of unwanted substances, such as halogenated substances, can be performed in an effective manner. Therefore, information is the key to success in phasing‐out substances; facilitating compliance of legal provisions for manufacturers of electrical and electronic devices; and improving the environmental footprint of products as they reach the end of the life cycle. After an introduction to the challenges of electronics waste management, this paper describes supply chain information systems and how they are used to facilitate substance phase‐outs in the electronics industry. Sony Ericsson has been working with phase‐outs of unwanted substances since it was founded in 2001. Through the introduction of a material declaration system that keeps track of all substances in the components used in the company's products, Sony Ericsson has been able to replace unwanted substances to improve environmental impacts at the recycling stage of a product.     

纳米铝粉对烟火药剂热安全性影响研究

为研究铝粉纳米化后对烟火药剂性能的影响，本文将普通铝粉和纳米铝粉分别与氯酸钾、硫粉按照零氧平衡的同一配比（17％AL＋63％KClO3＋20％S）配成的烟火药剂进行ARC热分析对比试验发现，含纳米铝粉的烟火药剂热分解的初始反应温度降低，反应到达最大温升速率所需的时间延长，反应所能达到的最高压力降低。这说明纳米铝粉的加入在加速其反应进程的同时，可有效地降低其反应的激烈程度和危险性，即铝粉纳米化后可以有效的改善烟火药剂的性能，提高其安全性。     

Developmental toxicity of two common corn pesticides to the endangered southern bell frog (Litoria raniformis)

To examine the link between corn agriculture and the observed decline of the endangered southern bell frog (SBF), the effects of two corn crop pesticides on larval growth and development were investigated. Tadpoles were exposed to terbufos sulfone (10 μg/L), a major breakdown product of the insecticide terbufos, and the herbicide atrazine (25 μg/L) individually and as a mixture until the completion of metamorphosis. Atrazine did not interact synergistically with terbufos sulfone or result in significant effects on growth and development alone, although there was some indication of accelerated metamorphosis in the pilot study. Terbufos sulfone alone and as a mixture (terbufos/atrazine) significantly slowed larval development and ultimately delayed metamorphosis. The observed developmental effects from an environmentally relevant concentration of terbufos sulfone indicates a risk posed by this persistent degradation product to the endangered SBF, which breeds and develops in the rice bays adjacent to corn fields treated with pesticides.     

微波再生载苯酚活性炭过程中再生产物分析

研究了载氮气和无载气2种条件下,微波再生载苯酚活性炭过程中再生产物的成分和苯酚随再生过程的去向分布。结果表明,无载气时,微波功率越高,再生反应器内温度越高,吸附质的高温裂解反应越彻底,再生产物以挥发性气体为主,有机质种类很少;而当微波功率较低或载氮气再生时,反应器内温度相对较低,苯酚难以被彻底分解,再生产物中含多种复杂的链状或环状有机物。此外,载氮气时,经气提、挥发而去除的苯酚量约占总吸附量的一半,再生炭上无苯酚残留,活性炭吸附性能可完全恢复乃至优化;无载气时,经挥发而去除的苯酚量只有19.9%,其余大量苯酚则在微波作用下裂解或缩合为其他物质随尾气而去除,且再生炭上仍有少量苯酚未被解吸出来。因此,前者活性炭再生的效果优于后者。     

我国城市间客运交通能源消耗趋势的分解

随着我国城镇化水平不断提高,城市作为重要的交通网络节点,其衔接交通运输线路、产生和承担客货流转换的功能日益显著。定量地探讨城市间客运交通能源消费变化的影响因素对于我国未来城市间客运交通能源需求的研究及温室气体减排具有重要意义。本文采用终端能源需求MAED模型,对我国城市间客运交通能耗的历史基期数据进行处理,同时对未来能耗进行预测,在形成ASIF结构的数据基础上,利用对数平均迪氏指数法(Logarithmic Mean Index,LMDI)对城市间客运交通能耗的活动效应、结构效应和强度效应进行分解分析。结果表明,从历史数据来看,我国"十五"期间城市间客运交通能耗的快速增加同时取决于客运周转量的增加、客运交通模式和能耗强度的转变,若延续这一发展趋势,我国中长期城市间客运交通模式将快速增长。未来城市间轨道交通网络的发展和高效利用及交通节能减排政策的落实将是促进能源消耗增速降低的可能选择。     

Value of information in product recovery decisions: a Bayesian approach

There is a widespread recognition of the need for better information sharing and provision to improve the viability of end-of-life (EOL) product recovery operations. The emergence of automated data capture and sharing technologies such as RFID, sensors and networked databases has enhanced the ability to make product information; available to recoverers, which will help them make better decisions regarding the choice of recovery option for EOL products. However, these technologies come with a cost attached to it, and hence the question ‘what is its value?’ is critical. This paper presents a probabilistic approach to model product recovery decisions and extends the concept of Bayes' factor for quantifying the impact of product information on the effectiveness of these decisions. Further, we provide a quantitative examination of the factors that influence the value of product information, this value depends on three factors: (i) penalties for Type I and Type II errors of judgement regarding product quality; (ii) prevalent uncertainty regarding product quality and (iii) the strength of the information to support/contradict the belief. Furthermore, we show that information is not valuable under all circumstances and derive conditions for achieving a positive value of information.     

基于行业增长的省级可再生能源规划目标分解

为了有效的把国家可再生能源规划分阶段的落实到各个省市,做好二者之间衔接工作,研究考虑了我国在从发展中国家过渡到中等发达国家时所需要考虑的如何平衡公平与效率之阀关系的问题,结合中国可再生能源发展实际特征,提出一种基于行业增长曲线的可再生能源阶段目标分解模型.模型首先求解出中国不同的可再生能源行业的增长曲线.然后给出可再生能源发展阶段目标函数.结合区域发展规划,给出了各省的阶段目标,为了验证该模型的正确性,以风电、水电和太阳发电为代表能源,结合国家可再生能源整体规划和资源需求分布状况,分阶段提出了各省域的可再生能源发展目标.目标分解参照两个原则(1)可分解原则.国家总量目标可以根据一定的标准在不同地区、部门和行业进行分解,由全社会共同完成发展目标.(2)公平性和区域差异的原则.考虑资源禀赋和社会经济发展水平差距,各地总量目标有所区别.研究对于可再生能源规划的整体实施和监管具有一定的借鉴意义.