空气湿度对低浓度有机蒸气在活性炭上吸附平衡的影响

采用吸附柱穿透曲线法测定了30℃不同相对湿度（RH）下4种低浓度有机蒸气（VOC）在活性炭上的等温吸附量，结果表明，水蒸汽对VOC吸附平衡的抑制作用。随着RH的增大，VOC浓度的降低而增大，且随着VOC分子极性的增强则有所增大；VOC水蒸汽吸了平衡的抑制作用，随着VOC分子极性的增强是有所减弱，提出一个基于竞争吸附机理的olanyi-Dubi-min方程，解释空气湿度对低浓度VOC在活性炭吸附平衡的影响。     

“城郊型农副业综合经营生态区”探讨

介绍了上海闽行区近年来大中型禽畜场污染治理的典型技术。根据该区的实践及其发展趋势来看,建立“城郊型农副业综合经营生态区“模式势在必行。文章还探讨了“城郊型农副业综合经营生态区”的特征、必要条件以及功能区划方案等。     

土壤溶液中镉的化学形态及化学平衡研究

据土壤溶液的实际情况建立简便的平衡模式,研究了红壤、黄棕壤、黄潮土三种典型土壤溶液中Cd的化学形态和化学平衡.结果表明,溶液中Cd的主要形态为Cd~(2+)、CdCl~+和CdSO_4~6.黄潮土还有一定量的CdHCO_3~+,其它形态Cd很少,其中游离Cd~(2+)占绝大部分.红壤最高,黄棕壤次之.红壤施石灰后游离Cd~(2+)下降,CdSO_4~6增加;添加氯化物后,溶液pH下降,大量Cd进入溶液中,CdCl~+比例明显升高.溶液中Cd的形态分布与土壤Cd的生物有效性有一定关系.此外,溶解度图证明,供试土壤中不可能有Cd的矿物生成.Cd在固液相间的平衡受吸附解吸反应控制.     

对Janbu普遍条分法计算方法的改进

Janbu普遍条分法(或称严格Janbu法)是第一个基于任意形状滑面且考虑滑体所有平衡条件的边坡稳定性计算方法。该方法存在的严重不收敛问题一直困扰着边坡理论和工程界近半个世纪。本文基于Janbu普遍条分法的基本原理和假设,重新推导出数学上更为简洁的安全系数积分表达式,指出传统计算格式不易收敛性是推力二阶导数的不合理数值误差所致,应用数值平滑技术可减少这个误差,使计算过程稳定收敛。研究表明,改进后的Janbu普遍条分法不失为理论相对严格、工程较为实用的边坡稳定性计算方法。     

略阳电厂后部山体边坡的稳定性评价与初步治理设计

在对略阳电厂后部山体地质条件分析的基础上,采用定性分析与定量数值计算相结合的方法评价了电厂后部山体在开挖前后的稳定性问题,并对开挖后的坡体提出了相应的工程治理措施.     

顶空气相色谱法测定食品中甜蜜素含量

采用顶空气相色谱法测定食品中甜蜜素含量,探讨了气液相平衡条件及色谱条件的选择,实验结果表明甜蜜素的标准溶液在0.1-0.4μg/l范围内具有良好的线性关系,回收率为87.5%-101.8%,相对标准偏差为2.6%.     

Vertical fiscal externalities and the environment

We show that imposition of a state-level environmental tax in a federation crowds out pre-existing federal taxes. We explain how this vertical fiscal externality can lead unilateral state-level environmental policy to generate a welfare gain in the implementing state, at the expense of other states, even absent any environmental benefits. Using a computable general equilibrium model of the Canadian federation, we show that vertical fiscal externalities can be the major determinant of the welfare change following environmental policy implementation by a state government. Our numerical simulations indicate that – as a consequence of vertical fiscal externalities – state governments can reduce greenhouse gas emissions by over 20 percent without any net cost to themselves.     

The effects of breath alcohol concentration on postural control

Background: Two of the 3 standardized field sobriety tests that U.S. law enforcement uses at roadside checks have a postural equilibrium component to them. Those tests have been validated to detect impairment caused by blood alcohol concentrations (BACs) of 0.08 g/dL or above. Many medical and traffic safety associations support a lower limit, and one state, Utah, has passed a law to lower the limit to 0.05 g/dL. Many studies have examined the effects of alcohol on postural control (of which postural equilibrium is a component), with a consensus emerging that impairment is usually found at BACs greater than 0.06 g/dL. Most of these studies, however, had a relatively small number of subjects, usually between 10 and 30. The current study collected data from a much larger sample.

Objective: The objective of this study was to provide additional evidence that posture control is negatively affected at BACs greater than 0.06 g/dL or breath alcohol concentrations (BrACs) of 0.06 g/210 L.

Method: This was a between-subjects study, with BrAC group as the independent variable (5 levels: 0.00, 0.04, 0.06, 0.08, and 0.10 g/210 L); 4 measures of postural control as the dependent variables; and age, height, and weight as the covariates. Posture control was measured with a force-sensing platform connected to a computer. The feet's center of pressure (CoP) on the platform was recorded and the corresponding movement of the body in the anterior–posterior and lateral planes was derived. Participants (N = 96) were randomly assigned to one of the BrAC groups. Positive BrAC groups were compared to the zero BrAC group. Data were examined with hierarchical multiple regression.

Results: Adjusted for age, height, and weight, the main effect of lateral CoP with eyes open was not statistically significant. There was a statistically significant main effect of alcohol on anterior–posterior CoP excursion with eyes open and with eyes closed and lateral CoP excursion with eyes closed. For all 3 of those variables, only BrACs of 0.08 and 0.10 g/210 L produced differences against zero BrAC. Although the main effect of alcohol on Lateral CoP Excursion with eyes open was not statistically significant, the contrasts between 0 and 0.08 and 0 and 0.10 g/210L BrAC were in the hypothesized direction.

Conclusion: The current study did not directly address the issue of whether the sobriety tests are sensitive to BrACs of 0.05 g/210 L or above; rather, it provides additional evidence that postural control, one of the components of those tests, is relatively unaffected by BrACs lower than 0.08 g/210 L. Additional research is needed on the diagnostic characteristics of the sobriety tests at BrACs lower than 0.08 g/210 L.     

企业环境寻求、污染密集型生产区际转移与环境监管

在当前强调产业结构调整的政策背景下,产业有序转移必须以有利于或者加强环境保护为基本目标。环境规制差异造成了不同经济地域之间污染密集型生产的比较优势调整,强化了高污染产业进行生产区位选择的动机,以规避来自政府的环境监管。环境治理成本的不同是高污染企业区际转移的重要驱动因素,企业环境寻求策略推动了污染密集型生产由环境规制强度高的地区向环境规制松弛地区的转移。企业污染密集型生产的区际转移受到环境要素产品生产比较优势的明显影响,这些环境要素产品与区际环境规制差异、企业市场内部化战略以及污染密集型产品的生命周期密切关联。借鉴一般均衡分析框架,可以明晰企业环境寻求策略下污染密集型生产转移的内在机制。一方面,环境成本差异决定了非环境友好产品生产转移的意愿,高强度的环境规制使得企业生产的边际环境治理成本和平均环境治理成本提高,污染密集型生产外迁的动力加强,生产效率高的企业对环境规制强度更加敏感。污染密集型生产承接地提高环境规制强度能形成对环境负面影响的有力对冲,遏制环境恶化趋势。另一方面,合理的区际环境政策差异能在产业有序转移中发挥重要作用。合理设定区际环境规制级差与碳信征信系统建设,加强分类监管与行业节能减排,建立拟承接生产项目的效率筛选机制,提高区域市场开放程度、降低产业优惠政策所形成隐性市场保护等环境监管手段是保证欠发达地区通过产业承接实现跨越式发展的关键所在。     

应用相平衡分配法建立湘江衡阳段沉积物重金属质量基准

采集湘江衡阳段29个站点的表层沉积物样品,测定沉积物中4种重金属(Cu、Pb、Zn和Cd)含量及赋存形态、以及孔隙水中重金属含量,根据相平衡分配法的基本理论,考虑参与沉积物-水相平衡分配的重金属组成,实测法计算重金属的沉积物-水相平衡分配系数(Kp),分别引用美国EPA制定保护水生生物不受重金属慢性毒性影响的基本连续浓度(CCC)和我国地表水环境质量标准(GB 3838-2002)Ⅰ类水质标准,建立两种湘江衡阳段沉积物重金属质量基准(SQC)进行对比分析,其中基于美国CCC建立的湘江衡阳段沉积物重金属质量基准与国内外研究成果相比可比性较好,4种重金属(Cu、Pb、Zn和Cd)的SQC值分别为64.62、55.57、1 360.40和2.34μg.g-1,此SQC具有保护长期生活于沉积物中的底栖生物不受重金属慢性毒性影响的意义.通过单因子评价法将湘江衡阳段沉积物中重金属总量与沉积物质量基准值(SQC)进行比较,结果表明,湘江衡阳段沉积物中Cd和Pb含量水平对底栖生物具有较大的慢性毒性影响,Cd污染不容忽视.