全文获取类型
收费全文 | 666篇 |
免费 | 73篇 |
国内免费 | 561篇 |
专业分类
安全科学 | 30篇 |
废物处理 | 130篇 |
环保管理 | 42篇 |
综合类 | 722篇 |
基础理论 | 171篇 |
污染及防治 | 196篇 |
评价与监测 | 5篇 |
社会与环境 | 3篇 |
灾害及防治 | 1篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 10篇 |
2021年 | 18篇 |
2020年 | 11篇 |
2019年 | 16篇 |
2018年 | 22篇 |
2017年 | 22篇 |
2016年 | 38篇 |
2015年 | 29篇 |
2014年 | 41篇 |
2013年 | 105篇 |
2012年 | 76篇 |
2011年 | 68篇 |
2010年 | 59篇 |
2009年 | 70篇 |
2008年 | 64篇 |
2007年 | 80篇 |
2006年 | 120篇 |
2005年 | 68篇 |
2004年 | 56篇 |
2003年 | 61篇 |
2002年 | 41篇 |
2001年 | 37篇 |
2000年 | 32篇 |
1999年 | 34篇 |
1998年 | 29篇 |
1997年 | 19篇 |
1996年 | 21篇 |
1995年 | 18篇 |
1994年 | 10篇 |
1993年 | 11篇 |
1992年 | 1篇 |
1991年 | 5篇 |
1989年 | 2篇 |
1986年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有1300条查询结果,搜索用时 15 毫秒
71.
Daniel O. Onunga Anastasiah N. Ngigi Aggrey Osogo Francis Orata Zachary M. Getenga 《Journal of environmental science and health. Part. B》2013,48(6):387-397
Carbofuran (2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate) has been used within the Nzoia River Basin (NRB), especially in Bunyala Rice Irrigation Schemes, in Kenya for the control of pests. In this study, the capacity of native bacteria to degrade carbofuran in soils from NRB was investigated. A gram positive, rod-shaped bacteria capable of degrading carbofuran was isolated through liquid cultures with carbofuran as the only carbon and nitrogen source. The isolate degraded 98% of 100-μg mL?1 carbofuran within 10 days with the formation of carbofuran phenol as the only detectable metabolite. The degradation of carbofuran was followed by measuring its residues in liquid cultures using high performance liquid chromatography (HPLC). Physical and morphological characteristics as well as molecular characterization confirmed the bacterial isolate to be a member of Bacillus species. The results indicate that this strain of Bacillus sp. could be considered as Bacillus cereus or Bacillus thuringiensis with a bootstrap value of 100% similar to the 16S rRNA gene sequences. The biodegradation capability of the native strains in this study indicates that they have great potential for application in bioremediation of carbofuran-contaminated soil sites. 相似文献
72.
Mark Radosevich Samuel J. Traina Olli H. Tuovinen 《Journal of environmental science and health. Part. B》2013,48(4):457-494
Abstract An atrazine‐degrading bacterial isolate (M91–3) was able to utilize simazine and cyanazine as N sources for glucose‐dependent growth. The degradation of these three 5‐triazine herbicides was also investigated in binary and ternary mixtures. The organism used atrazine and simazine indiscriminately, whereas cyanazine degradation was slow and delayed until the depletion of the two other herbicides. There was no apparent effect of other commonly used herbicides on the rate of atrazine degradation by M91–3. 相似文献
73.
Yun Ma Liansheng Chen Jiguo Qiu 《Journal of environmental science and health. Part. B》2013,48(10):851-859
A novel strain HZ5 was isolated from the activated sludge of a pesticide manufacturer in Hangzhou, which was capable of degrading beta-cypermethrin (beta-CP). Based on its physiological characteristics and analysis of 16S rDNA gene, strain HZ5 was identified as Azoarcus indigens, which was a new genus that can degrade beta-CP effectively. Strain HZ5 could degrade beta-CP over a wide range of temperature (20 to 40°C) and pH (5.5 to 9.0), and the optimal temperature and pH were 30°C and 7.0. The highest degradation rate was approximately 70% of 50 mg/L beta-CP within 144 h at pH 7.0 and 30°C in MSM. An additional carbon source could enhance the biodegradation of beta-CP. Studies on biodegradation of the beta-CP showed no significant enantioselectivity. During the process, two main intermediate metabolites were produced by strain HZ5 and determined as 3-phenoxybenzaldehyde and 3-phenoxybenzoic acid by gas chromatography-mass spectrometry (GC-MS) analysis. The results indicated that strain HZ5 may have potential application in bioremediation of beta-CP polluted environment. 相似文献
74.
75.
76.
Rajiv K. Sinha Sunil Herat Sunita Agarwal Ravi Asadi Emilio Carretero 《The Environmentalist》2002,22(3):261-268
The practice of vermiculture is at least a century old but it is now being revived worldwide with diverse ecological objectives such as waste management, soil detoxification and regeneration and sustainable agriculture. Earthworms act in the soil as aerators, grinders, crushers, chemical degraders and biological stimulators. They secrete enzymes, proteases, lipases, amylases, cellulases and chitinases which bring about rapid biochemical conversion of the cellulosic and the proteinaceous materials in the variety of organic wastes which originate from homes, gardens, dairies and farms. The process is odour free because earthworms release coelomic fluids in the decaying waste biomass which has anti-bacterial properties which kills pathogens. The species used in India were Indian blue (Perionyx excavatus), African night crawler (Eudrilus euginae) and the Tiger worm (Elsinia foetida). E. foetida was used in Australia. E. euginae was found to have higher feeding, growth and biodegradation capacity compared to other two species.Earthworm action was shown to enhance natural biodegradation and decomposition of wastes (60–80 percent under optimum conditions), thus significantly reducing the composting time by several weeks. Within 5 to 6 weeks, 95–100 percent degradation of all cellulosic materials was achieved. Even hard fruit and egg shells and bones can be degraded, although these may take longer. 相似文献
77.
Anne Calmon Serge Guillaume Véronique Bellon-Maurel Pierre Feuilloley Françoise Silvestre 《Journal of Polymers and the Environment》1999,7(3):157-166
This work validated a burial protocol for in situ testing and presents a robust, repeatable and time-saving technique to measure degraded areas in the sample, i.e. an image analysis method. 1440 specimens of degraded samples have been compiled in a data base. To this end, twenty samples presenting different levels of biodegradability (i.e. PHBV/HV, PLA, PCL, PCL-Starch, paper, PE, PE-Starch) were buried at 4 different locations and then disinterred at 4, 6, 9, 12, 18, and 24-month intervals. The biodegradation levels of these samples were determined by computing weight and area loss. Weight loss was measured after careful cleaning, whereas area loss was quantified using image analysis. Image analysis gives reliable information on visual pollution while only requiring a rudimentary and thus quicker cleaning of the samples. 相似文献
78.
选择性吸附-高效生物降解法处理含硝基苯与苯酚混合废水 总被引:1,自引:0,他引:1
结合NDA-150型树脂(简称树脂)选择性吸附和生物降解的优点,对含硝基苯和苯酚的模拟混合废水(简称混合废水)进行处理。通过树脂的选择性吸附,使混合废水中的硝基苯和苯酚分离,随后用高效菌对树脂所吸附的硝基苯进行生物降解,同时实现树脂的再生。实验结果表明:通过调节混合废水的pH,树脂可有效地将混合废水中的硝基苯和苯酚进行选择性吸附分离;树脂对硝基苯的吸附是可逆的;树脂的再生程度受微生物对可利用硝基苯质量浓度的下限(1.2mg/L)限制;吸附-生物再生循环实验结果表明,该树脂可有效抵抗微生物的生物降解与破坏。 相似文献
79.
采用两段SBR工艺处理石化废水 总被引:1,自引:0,他引:1
采用两段序批式活性污泥反应器(SBR)工艺处理高浓度石化废水,考察了DO、MLSS、反应温度对废水处理效果的影响。实验结果表明,两段SBR系统中有机物降解存在着不同的作用机理,第一段主要以去除易降解有机物为主,第二段主要以去除难降解有机物为主。在进水COD为4000mg/L、SBR1中DO为4~5mg/L、MLSS为5000mg/L,SBR2中DO为2~4mg/L、MLSS为3000mg/L、反应温度约为20℃的条件下,废水COD去除率达90%以上。 相似文献
80.
Jasmin Jaquet Pascal Weitzel Thorsten Junge Burkhard Schmidt 《Journal of environmental science and health. Part. B》2013,48(4):245-254
The metabolic fate of 14C-phenyl-labeled herbicide clodinafop-propargyl (CfP) was studied for 28 days in lab assays using a soil from Germany (Ap horizon, silt loam, and cambisol). Mineralization amounted to 12.40% of applied 14C after 28 days showing a distinct lag phase until day 7 of incubation. Portions of radioactivity extractable by means of 0.01 M CaCl2 solution (bioavailable fraction) decreased rapidly and were 4.41% after 28 days. Even immediately after application, only 57.31% were extracted with the aqueous solvent. Subsequent extraction using accelerated solvent extraction (ASE; acetonitrile/water 4:1, v/v) released 39.91% of applied 14C with day 0 and 26.16% with day 28 of incubation from the samples. Non-extractable portions of radioactivity thus, increased with time amounting to 11.99% (day 0) and 65.00% (day 28). A remarkable increase was observed between 14 and 28 days correlating with the distinct increase of mineralization. No correlation was found throughout incubation with general microbial activity as determined by DMSO reduction. Analysis of the CaCl2 and ASE extracts by radio-TLC, radio-HPLC and GC/MS revealed that CfP was rapidly cleaved to free acid clodinafop (Cf), which was further (bio-) transformed; DT50 values (based on radio-TLC detection of the parent compound) were far below 1 day (CfP) and about 7 days (Cf). TLC analysis pointed to 2-(4-hydroxyphenoxy)-propionic acid as further metabolite. Due to fractionation of non-extractable residues, most of the 14C was associated with fulvic and humic acids, portions in humin fractions and non-humics were moderate and low, respectively. Using a special strategy, which included pre-incubation of the soil with CfP and then mineralization of 14C-CfP as criterion, a microorganism was isolated from the soil examined. The microorganism grew using CfP as sole carbon source with concomitant evolution of 14CO2. The bacterium was characterized by growth on commonly used carbon sources and by 16S rDNA sequence analysis. The sequence exhibited high similarity with that of Rhodococcus wratislaviensis (99.56%; DSM 44107, NCIMB 13082). 相似文献