TiO_2纳米管阵列光电极的制备及光催化性能研究

采用阳极氧化法在不同的条件下制备了TiO2纳米管阵列（TNT）光电极,利用SEM、XRD等手段对电极的表面形貌、晶体结构进行了分析和表征。以Rh.B为目标污染物,研究了不同电极的光催化和光电催化性能。结果表明：当氧化电压为20 V时,可获得形貌规则的有序排列的TiO2纳米管光电极,纳米管管径为80～120 nm;经50...     

Photoelectrocatalytic degradation of recalcitrant organic pollutants using TiO2 film electrodes: an overview

Photoelectrocatalytic (PEC) technology involved applying an electrical bias to a TiO₂ film electrode, has been widely applied to the degradation of refractory organic pollutants, owing to its high degradation efficiency. This paper reviews recent developments in the PEC degradation of recalcitrant organic contaminants using a TiO₂ film electrode. The preparation and application of various TiO₂ film electrodes have been investigated, as well as the parameters that influence PEC activity such as the crystal structure, the film thickness and substrate material, the applied electrical bias, the solution pH and conductivity. The improvement of PEC activity by doping the TiO₂ film electrode with metal and non-metal ions has been discussed. The mechanism and kinetics for the PEC degradation of organic pollutants have also been highlighted.     

微波辐照碳酸钾化学活化法制备菌渣活性炭

以食用菌渣为原料,以K2CO3为活化剂,利用微波辐照加热法制备活性炭。采用正交实验设计,研究了活化功率、活化时间、K2CO3与菌渣质量比、浸渍时间对活性炭碘值及得率的影响。实验结果表明,活化时间、活化功率、K2CO3与菌渣质量比对活性炭碘值影响显著,浸渍时间对活性炭碘值影响不显著;对活性炭得率,各因素影响均不显著。综合考虑碘值和得率2个指标,实验得出的最佳活性炭制备工艺条件为:活化功率560 W,活化时间20 min,K2CO3与菌渣质量比0.8,浸渍时间20 h。     

微振动台阵记录中空间自相关法的时间延迟校正

本文给出了微振动台阵的波长与台站对间距离的半理论-半经验关系;根据前人的理论和实验,指出微振动波场存在优势方向,即在有效波长范围内,微振动的各道记录存在相位差;提出了投影到某方位的相位校正公式和校正方法,由此实现空间自相关法的相关函数和相速度曲线的时间延迟校正,通过实例验证了该方法的有效性.     

雷电电磁脉冲对便携计算机终端的损伤分析

目的使用电磁仿真软件XFDTD,研究雷电磁脉冲(LEMP)对便携计算机的电磁危害。方法给出腔体内部采样点处的电场时域波形图和截面的电场分布图,计算腔体内不同位置处的屏蔽效能和瞬时坡印廷矢量的大小,分析雷电电磁脉冲与腔体正面孔阵和侧面孔洞的耦合以及孔洞的互耦合。结果雷电电磁脉冲会与入射正面和侧面上的小孔发生不同程度的耦合。雷电电磁脉冲对腔体内部的电磁危害很小,电磁能量主要被限制在开孔附近,腔体中心处受到的影响最小。开孔面积越大,耦合进的电磁能量越多。相邻孔洞之间的互耦合效应使得腔体的屏蔽性变差。结论雷电电磁脉冲对便携计算机的危害一般很小。     

TiO_2纳米棒阵列薄膜的制备及其光催化还原Cr(Ⅵ)

采用水热法在导电玻璃(FTO)上合成具有一维结构的TiO2纳米棒阵列薄膜.用扫描电子显微镜,广角X-射线粉末衍射,紫外可见分光光谱等手段对薄膜进行了表征,研究了不同浓度钛酸四丁酯和水热反应时间对FTO-TiO2纳米棒阵列薄膜形貌的影响及FTO-TiO2纳米棒阵列薄膜光催化还原Cr(Ⅵ)的反应性能.结果表明,当钛酸四丁酯浓度为0.05 mol·L-1和水热反应时间为20 h时制备的FTO-TiO2纳米棒阵列薄膜形貌最优,一维FTO-TiO2纳米棒阵列薄膜光催化还原Cr(Ⅵ)的性能优于商业化二氧化钛P25制备的薄膜.     

High-resolution array genomic hybridization in prenatal diagnosis

Array genomic hybridization (AGH) can detect chromosomal gains or losses that are 100 times smaller than those identifiable by conventional cytogenetic methods. Genome-wide AGH can identify genomic imbalance that causes birth defects and mental retardation at least twice as frequently as conventional cytogenetic analysis. Using AGH as a prenatal test for fetal genomic imbalance offers the promise of detecting pathogenic gain or loss of genomic material more quickly and much more frequently than current methods. However, the chance of finding a result of uncertain clinical significance is much greater than with conventional cytogenetic analysis, and the benefit–cost ratio of doing AGH in addition to conventional cytogenetic analysis in pregnancies at high risk for Down syndrome is likely to be poor. Very little is known about the natural history and range of clinical variability associated with most pathogenic submicroscopic copy number variants (CNVs). It seems doubtful that patients can be adequately counseled for prenatal AGH testing in most cases because the risks and benefits are unknown. At present, AGH should be offered for prenatal diagnosis only if the pregnancy is at especially high risk of having a pathogenic CNV or if AGH is being done as part of a clinical trial. Copyright © 2008 John Wiley & Sons, Ltd.     

HNS多点阵列装药慢速烤燃试验研究

研究多点阵列冲击片雷管装药的热安全性。方法针对φ3 mm×3 mm、φ4 mm×4 mm、φ5 mm×5 mm、φ4mm×8mm共四种不同尺寸的HNS多点阵列装药开展慢速烤燃试验研究,得到HNS多点阵列装药在3.3℃/h、5、10℃/min三种不同升温速率下的响应特性。结果同规格装药情况下,随着升温速率的提高,其热烤响应剧烈程度有加剧趋势;同升温速率条件下,试样药量越大,反应剧烈程度有加剧趋势。结论阵列装药有利于分散HNS装药在热烤条件下的热积累,降低热烤试验的响应强度,提升装药的热安全性。     

多点激励中的控制载荷存在性

目的 给出多点激励振动试验中控制载荷的存在性判据,建立控制载荷分析的数值模拟方法.方法 从控制载荷数量与目标响应数量关系出发,通过传递函数矩阵及其增广矩阵的秩的大小关系比较,对多点激励振动环境试验中控制载荷的存在性进行研究,并针对当前多点激励试验中只控制多个点的幅值而不控制相互之间相位差的现状,对存在性结论进行修正,同时通过理论推导和数值优化算法,建立不同工况下控制载荷的分析方法.结果 对于同时控制响应幅值和相位的情况,当传递函数矩阵的秩Rc与其增广矩阵的秩Rz相同且为满秩时,控制载荷存在唯一解;当Rc=Rz但非满秩时,控制载荷不唯一;当Rc相似文献