实验性糖尿病新西兰兔主要器官组织的病理学观察

将雄性新西兰兔随机分为:基础饲料组(即对照组:n=15)和高糖高脂饲料组(即实验组:n=15,喂食10％猪油,37％白蔗糖混合53％的基础饲料).共观察12周.于12周实验结束时,全部处死动物,取动物心脏、肝脏、胰腺、肾脏,用1O％福尔马林液固定,常规石蜡包埋切片,H、E染色,光学显微镜下观察并照相.结果表明:动物心肌细胞肥大,并出现灶性坏死,淋巴细胞浸润,心肌细胞间成纤维细胞增生和毛细血管增生,胶原纤维增加;肝细胞有明显脂肪变性,细胞肿胀;肾脏表现有肾小球球囊增大,细胞增多,毛细血管壁增厚,肾小管上皮细胞胞体增大;胰腺组织表现为胰岛分布稀疏,数量减少,胰岛萎缩,胰岛细胞数量减少,成纤维细胞增生.     

Pomegranate husk as an adsorbent in the removal of toxic chromium from wastewater

The use of a new sorbent developed from the husk of pomegranate, a famous fruit in Egypt, for the removal of toxic chromium from aqueous solution has been investigated. The batch experiment was conducted to determine the adsorption capacity of the pomegranate husk. The effects of initial metal concentration (25 and 50 mg l^-1), pH, contact time, and sorbent concentration (2-6 g l^-1) have been studied at room temperature. A strong dependence of the adsorption capacity on pH was observed, the capacity increased as the pH decreased, and the optimum pH value was pH 1.0. Adsorption equilibrium and kinetics were studied with different sorbent and metal concentrations. The adsorption process was fast, and equilibrium was reached within 3 h. The maximum removal was 100% for 25 mg l^-1 of Cr⁶⁺ concentration on 5 g l^-1 pomegranate husk concentration, and the maximum adsorption capacity was 10.59 mg g^-1. The kinetic data were analysed using various kinetic models—pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion equations—and the equilibrium data were tested using several isotherm models, Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich, and Generalized isotherm equations. The Elovich and pseudo-second-order equations provided the greatest accuracy for the kinetic data, while Langmuir and Generalized isotherm models were the closest fit for the equilibrium data. The activation energy of sorption has also been evaluated as 0.236 and 0.707 kJ mol^-1 for 25 and 50 mg l^-1 chromium concentration, respectively.     

我国城市化过程中水土资源利用问题的认识

改革开放以来，我国城市化过程出现快速发展时期，特别是长江下游地区（长江三角洲及其周边地区），由于人口与产业不断集聚，重大基础设施项目投资加大，道路网密度增加，开发区扩大，使得城市空间迭加扩展，造成了严重的水土资源利用失衡，生态环境日趋恶化，使本地区城市发展出现了许多新问题。以长江下游地区为例，对本区城市化过程中有关水土资源环境恶化、水污染增加、土地资源流失，以及城镇化速度过快的情况，作了深入分析论证，同时对长江下游地区水土资源合理开发利用与保护提出了新的思维、新的方法措施，特别是对如何加强长三角地区水质环境的整治提出了4点切实可行的办法与措施，为本地区的经济发展与生态安全提供科学依据.     

典型铬渣简易掩埋场铬渣及土壤铬污染特征和处置分析

通过钻孔采样分析,研究了典型铬渣简易掩埋场地下铬渣及土壤铬中Cr6 、总Cr的分布特征和污染状况,结果表明,铬渣简易掩埋场铬污染程度严重,引起了周边和地下深部较大面积的土壤污染,深度达到了地下的基岩.铬含量在土壤层剖面中分布呈现规律性变化,即随土壤深度增加,Cr6 、总Cr含量逐渐下降,但绝大多数超过了危险废物毒性鉴别标准.从铬污染程度上看,总体上存在铬渣>土壤>人工填土.在此基础上,提出了铬渣及污染土壤的处置方式,为铬渣污染治理和资源化利用提供科学依据.     

中美新化学物质管理制度的比较

简要叙述了中美两国新化学物质管理的基本情况，分别从管理原则、管理范围、管理具体要求、申报种类、评审程序、监督管理等方面重点论述了中美新化学物质管理制度的特点。通过借鉴美国新化学物质管理的优点及经验，提出了强化和完善中国新化学物质管理制度的对策。     

铬渣中铬的浸出行为

采用BCR法连续浸提研究铬渣中铬的存在形态,结果表明:铬渣中总铬和六价铬主要以残渣态和可氧化态形式存在;通过铬渣动态连续浸提实验与静态浸提实验研究了浸提剂和活性炭对铬渣中铬浸出行为的影响,研究发现p H值为3.1的醋酸浸提剂浸出液中铬浓度最低,且添加活性炭后的静态浸出液中铬的浓度有不同程度降低。     

全面落实新《安全生产法》强化焦化企业安全管理

新《安全生产法》的颁布和实施,对焦化企业提出了更高的要求。焦化企业可以通过完善安全仪表系统、开展危险与可操作分析、建立企业安全生产预警体系、贯彻执行焦化行业安全生产标准和建立现代企业安全管理制度来更好地促进其安全生产。     

Simultaneous photocatalytic treatment of Cr(VI), Ni(II) and SDBS in aqueous solutions: Evaluation of removal efficiency and energy consumption

Simultaneous photocatalytic reduction of poisonous Cr(VI) and Ni(II) ions, coupled with photocatalytic oxidation of sodium dodecyl benzene sulfonate (SDBS) were studied with a trace amount of commercial titania nanoparticles and by means of a direct-photo-irradiation reactor. The co-presence of metal ions and SDBS causes metal ions reduction as well as SDBS oxidation to enhance and energy efficiency to improve. XRD, XPS and FTIR analysis were used to characterize TiO₂ particles before and after usage with the aim of evaluating the mechanism of reactions. The effect of major operating parameters, pH and temperature, was investigated. Under conditions of [Cr(VI)]₀ = [Ni(II)]₀ = 5 mg/L, [SDBS]₀ = 10 mg/L, [TiO₂] = 40 mg/L, pH 6 and T = 35 °C; the removal efficiencies of 55.4%, 71.2% and 57.2% were obtained, respectively, for Cr(VI) and Ni(II) reduction, as well as for SDBS oxidation, after 110 min operation. The relevant kinetic model jointed with the Arrhenius equation was introduced. Pseudo-first-order reactions are relevant. Energy consumption (electrical and thermal) evaluations revealed that operations at higher temperatures provide significant cost reduction. Meantime, a criterion was proposed for a consistent assessment of this kind of processes.     

运行参数对水蚯蚓生物吸持六价铬性能影响研究

水蚯蚓能通过摄食剩余污泥而使污泥减量,但剩余污泥中常含有各种重金属污染物.本文以颤蚓科蠕虫(Tubificidae)为研究对象,以六价铬为典型重金属污染物,考察运行工艺参数:初始铬浓度、p H、水蚯蚓投加量和温度对水蚯蚓吸持六价铬的影响.实验结果表明,在研究浓度范围内(0.1~8.0 mg·L-1),水蚯蚓对六价铬的吸持速率随铬浓度的增大而加快,单位质量吸持量从14.4 mg·kg-1(以干重计,下同)增加到312.7 mg·kg-1,但六价铬的吸持率却随Cr6+初始浓度的增加而降低;p H从6.0增加到8.0,水蚯蚓对六价铬的吸持速率随p H的上升而提高,吸持率和单位质量吸持量先明显增强,p H达到7.5后逐渐趋于平衡,即吸持最佳p H为7.5;水蚯蚓投加量从1.0 g(以湿重计,下同)增加到5.0 g时,吸持速率及吸持率均上升,但单位质量吸持量却随着水蚯蚓投加量的增加而减少;当温度在10~20℃范围内时,水蚯蚓对六价铬的吸持速率相对较慢,到25℃时,吸持速率明显加快,吸持率和单位质量水蚯蚓的吸持量的变化趋势与吸持速率的变化相一致,但当温度达到30℃,水蚯蚓会大量死亡,综合考虑,处理系统最佳温度宜控制在25℃.     

新常态下要科学认识环境管理六个量的关系

针对新常态下环境管理面临的机遇与挑战,本文提出了环境管理工作要树立新的思维,并在此基础上深入剖析了总量与质量、容量与流量、存量与增量的关系。现行的总量控制制度在实施过程中带来的污染减排潜力越来越小,因此,环境管理的目标应从以污染排放控制为主向以环境质量改善为主转变,通过采取具有针对性的差异化容量总量控制管理手段,实现污染排放流量管控,同时,应充分考虑现有环境本底负荷的问题,实现污染存量和可能增量的协同控制,这对于推进环境管理工作的战略转型具有借鉴意义。