盐穴地下储气库事故统计及风险分析

借鉴输气管道和二氧化碳地下封存设施的风险评价方法,结合盐穴地下储气库的事故统计分析,对储气库系统中的潜在风险因素进行12大类、35小类的初步分类,并归纳总结了盐穴地下储气库的3种主要事故类型。采用事故树分析的风险评价方法,对13种主要风险因素进行风险识别。在此基础上,提出定量风险评价的重要工程模型,其包括气体水合物模型、盐穴稳定性评价模型以及气体泄漏模型。该风险分析方法和工程模型有助于定量评价盐穴地下储气库的主要风险因素,为储库的安全稳定运行提供了科学依据。     

浅论石油化工企业二氧化硫总量减排

为满足石油化工企业总量控制的要求,采取相应的治理措施,降低污染物排放总量,避免采取大量投资和占地的末端治理措施,在工艺过程中采取措施降低主要污染物排放总量是行之有效的途径,采用催化工艺中添加硫转移脱氮剂的办法、热电厂锅炉采用改善炉体燃烧状态、配合石灰石脱硫等工艺过程措施,探讨进一步减少二氧化硫排放总量的可行性。     

纳米级聚合氯化铝处理石化废水絮凝效果研究

采用自制的纳米级聚合氯化铝絮凝荆处理石大科技股份公司胜华炼油厂隔油池出水，以处理后水样的透光率作为混凝沉降效果的评价指标，并对絮凝剂投加量、搅拌速度、搅拌时间等影响混凝效果的因素进行了研究。试验表明，聚合氯化铝对石化废水的处理达到较为理想的效果，聚合氯化铝混凝处理石化废水的最佳条件为：纳米级聚合氯化铝投加量为15mg／L左右，慢速搅拌的搅拌速度为50～60rpm，快速搅拌的搅拌速度为190—225rpm，快速搅拌时间90s。慢速搅时间10min时效果最佳。使用Al-Ferron逐时络合比色法及XRD对絮凝荆进行了表征，结果证实样品中Alb含量可达到85％左右。     

中国碳捕集、利用与封存技术研发与示范

碳捕集、利用与封存(CCUS)是一项新兴的、具有大规模减排潜力的技术,有望实现化石能源使用的CO2近零排放,被认为是进行温室气体深度减排最重要的技术路径之一.开展CCUS技术的研发和储备,将为中国未来温室气体减排提供一种重要的战略性技术选择,受到政府、企业和学术界的广泛关注.本文从CCUS技术产生和发展的背景出发,概括了该技术的特点及存在的主要同题,总结了当前中国CCUS技术政策,介绍了中国CCUS技术研发、试点示范、国际合作等的开展情况,并通过与欧美等发达国家CCUS技术发展与示范活动现状的对比,初步分析了中国CCUS技术发展方面存在的主要不足.为进一步推动我国CCUS技术的研发与示范,文章提出应加强国家层面的技术政策指导和宏观协调、引导资源有效配置；推动建设行业间的CCUS技术合作平台；重视CCUS来来技术应用软环境建设等有针对性的建议.     

A COMPARISON OF STREAMFLOW GENERATION MODELS FOR RESERVOIR CAPACITY-YIELD ANALYSIS1

ABSTRACT: An analysis of four streamflow generation schemes for the use in the estimation of the required conservation storage for a single reservoir is presented. The comparison of the generating schemes should aid in the selection of an appropriate model type for the reservoir sizing problem. The streamflow generation models are compared using two criteria. The first comparison is between the statistics of the generated streamflow sequences and the corresponding statistics from the historical record. The second evaluation compares the median reservoir size determined by each model with the required storage based on the historical flow sequence. The results of a comparative analysis for monthly streamflow data for the Rzav River in Yugoslavia are presented and discussed. The results indicate that both evaluation criteria are required to discriminate between the various options.     

Storage stability of injection-molded starch-zein plastics under dry and humid conditions

Corn starch and zein mixtures (4 : 1 dry weight) were extruded and injection-molded in the presence of plasticizers (glycerol and water). Tensile strength and percentage elongation of the molded plastics were measured before and after 1 week of storage under a dry or humid condition (11 or 93% RH). With 10–12% glycerol and 6–8% water, injection-molded plastics had relatively good tensile properties (20- to 25-MPa tensile strength and 3.5–4.7% elongation). But while exposed to dry conditions (11% RH), the molded plastics lost weight (0.5–1.5% in 7 days) and became very brittle, with significant decreases in tensile strength and elongation. Partial replacement (5–10%) of starch with a maltodextrin (average DE 5) reduced the glass transition and melting temperatures of the starch-zein mixture as well as the dry storage stability. Using potato starch instead of corn starch significantly improved the dry storage stability of the injection-molded starch-zein plastics (18- vs 11-MPa tensile strength). Anionic corn starches with a maleate or succinate group (DS<0.01) produced injection-molded plastics with improved tensile properties and storage stability. Plastics prepared from the starch maleate and zein mixture retained the strength during 1 week of dry storage without a significant change (26-MPa tensile strength and 3.7% elongation after 1 week of storage).Paper presented at the Bio/Environmentally Degradable Polymer Society—Second National Meeting, August 19–21, 1993, Chicago, Illinois.Journal paper No. J-15561 of the Iowa Agriculture and Home Economics Experiment Station, Ames, Iowa, Project No. 2863.     

SUSPENDED SEDIMENT AND METALS REMOVAL FROM URBAN RUNOFF BY A SMALL LAKE1

ABSTRACT: A small lake in the Chicago Metropolitan Area was from 91 to 95 percent efficient in removing suspended sediment and from 76 to 94 percent efficient in removing copper, iron, lead, and zinc from urban runoff. Sediments accumulated in the lake in the form of an organic-rich mud at an average rate of 20 millimeters per year; this reduced lake storage and covered potential habitat for aquatic organisms. Copper, lead, and zinc concentrations were closely associated with suspended-sediment concentrations and with silt- and clay-sized fractions of lake sediment. Although concentrations of mercury and cadmium were near detection limits in runoff, measurable concentrations of these metals accumulated in the lake sediments.     

Effects of increased wood energy consumption on carbon storage in forests of the United States

Large but feasible increases that have been projected for the production of wood energy in the United States can be expected to significantly alter the current carbon storage patterns in US forest vegetation. The 1976 net wood increment left after forest cutting equals about 136 × 10⁶ tons of carbon/year, with about 60% of the increment found in merchantable trees, and the remainder in nonmerchantable components.Achieving 5–10 quads of wood energy beyond 1976 levels by the year 2010 can significantly change current carbon storage patterns with the magnitude of change dependent on the extent of residue harvest to meet energy goals, and the rate of future forest growth. Complete loss of the apparent net wood increment is a possible outcome.Although the future growth and harvest situation cannot be known now, a range of possible scenarios suggests that US forests in the year 2010 will store much less carbon than today, thus significantly changing their role in the global carbon cycle.     

ASSESSING FLOOD MITIGATION ALTERNATIVES IN SHIJR AREA IN METROPOLITAN TAIPEI1

The Keelung River Basin in northern Taiwan lies immediately upstream of the Taipei metropolitan area. The Shijr area is in the lower basin and is subject to frequent flooding. This work applies micromanagement and source control, including widely distributed infiltration and detention/ retention runoff retarding measures, in the Wudu watershed above Shijr. A method is also developed that combines a genetic algorithm and a rainfall runoff model to optimize the spatial distribution of runoff retarding facilities. Downstream of Wudu in the Shijr area, five dredging schemes are considered. If 10‐year flood flows cannot be confined in the channel, then a levee embankment that corresponds to the respective runoff retarding scheme will be required. The minimum total cost is considered in the rule to select from the regional flood mitigation alternatives. The results of this study reveal that runoff retarding facilities installed in the upper and middle parts of the watershed are most effective in reducing the flood peak. Moreover, as the cost of acquiring land for the levee embankment increases, installing runoff retarding measures in the upper portion of the watershed becomes more economical.     

石化废水脱氮技术现状分析

针对石化废水脱氮的现有技术进行归纳,并对各种方法的优缺点进行了对比分析,探讨了目前石化废水的脱氮技术现状和发展趋势。结论是:目前还没有一种通用的方法能处理所有氨氮废水,必须针对不同废水选择不同的技术及工艺。为了更有效地处理废水,应联合使用多种方法和工艺,这已是目前废水处理的一种趋势。