Extractive Spectrofluorometric Determination of Quinalphos Using Fluorescein in Environmental Samples

A simple, sensitive, convenient and low cost spectrofluorometric technique for determination of quinalphos is described. Quinalphos is decomposed with sodium ethoxide. Resultant sodium diethyl thiophosphate (Na-DETP) is extracted with a cationic fluorescein as ion pair complex into 1-chloro-2-nitrobenzene. The fluorescence of the ion pair, fluorescein-DETP is measured at 530 nm after excitation at 490 nm. This technique is applicable for the determination of quinalphos in water, food grains and vegetable samples up to ng level with Amberlite XAD-4.     

Linking Land Cover and Water Quality in New York City’S Water Supply Watersheds

The Catskill/Delaware reservoirs supply 90% of New York City’s drinking water. The City has implemented a series of watershed protection measures, including land acquisition, aimed at preserving water quality in the Catskill/Delaware watersheds. The objective of this study was to examine how relationships between landscape and surface water measurements change between years. Thirty-two drainage areas delineated from surface water sample points (total nitrogen, total phosphorus, and fecal coliform bacteria concentrations) were used in step-wise regression analyses to test landscape and surface-water quality relationships. Two measurements of land use, percent agriculture and percent urban development, were positively related to water quality and consistently present in all regression models. Together these two land uses explained 25 to 75% of the regression model variation. However, the contribution of agriculture to water quality condition showed a decreasing trend with time as overall agricultural land cover decreased. Results from this study demonstrate that relationships between land cover and surface water concentrations of total nitrogen, total phosphorus, and fecal coliform bacteria counts over a large area can be evaluated using a relatively simple geographic information system method. Land managers may find this method useful for targeting resources in relation to a particular water quality concern, focusing best management efforts, and maximizing benefits to water quality with minimal costs.The United States Environmental Protection Agency through its Office of Research and Development funded and managed the research described here. It has been subjected to Agency’s administrative review and approved for publication as an EPA document.     

Higher Plants As Bioindicators Of Sulphur Dioxide Emissions In Urban Environments

The evaluation of certain vascular plants that grow in the city of Madrid as biomonitors of SO₂ air pollution in urban environments has been carried out. Total concentration of sulphur in leaves of the chosen higher plants as well as other parameters in close relation to this contaminant (visible injury symptoms, chlorophyll a- and b-content and peroxidase activity) have been determined in order to study the spatial distribution and temporal changes in SO₂ deposition. Results obtained show that coniferous species such as Pinus pinea, were more sensitive to SO₂ atmospheric concentration than leafy species as Quercux ilex subspecies ballota and, in the same way, bush species, such asPyracantha coccinea and Nerium oleander, were more sensitive than wooded species, such as Cedrus deodaraandPinus pinea, respectively. There is a higher accumulation of sulphur in vegetable species located near highways and dense traffic incidence roads and near areas with high density of population. The minimum values for accumulation of SO₂ were registered in winter and spring seasons (from January to April) due to the vegetative stop; while maximum values are obtained during the summer season (from June to September), due to the stoma opening. The highest increments in sulphur concentration, calculated as the difference between two consecutive months, are obtained in May and June for all considered species except forCedrus deodara and Pyracantha coccinea, both species have few seasonal changes during the whole year. Some species are more sensitive to natural washing than others, showing a decrease in sulphur concentration after rainfall periods.     

Source Apportionment Of Groundwater Pollution Around Landfill Site In Nagpur, India

The present work attempts statistical analysis of groundwater quality near a Landfill site in Nagpur, India. The objective of the present work is to figure out the impact of different factors on the quality of groundwater in the study area. Statistical analysis of the data has been attempted by applying Factor Analysis concept. The analysis brings out the effect of five different factors governing the groundwater quality in the study area. Based on the contribution of the different parameters present in the extracted factors, the latter are linked to the geological setting, the leaching from the host rock, leachate of heavy metals from the landfill as well as the bacterial contamination from landfill site and other anthropogenic activities. The analysis brings out the vulnerability of the unconfined aquifer to contamination.     

Evaluation of Water Quality in the Chillán River (Central Chile) Using Physicochemical Parameters and a Modified Water Quality Index

The Chillán River in Central Chile plays a fundamental role in local society, as a source of irrigation and drinking water, and as a sink for urban wastewater. In order to characterize the spatial and temporal variability of surface water quality in the watershed, a Water Quality Index (WQI) was calculated from nine physicochemical parameters, periodically measured at 18 sampling sites (January–November 2000). The results indicated a good water quality in the upper and middle parts of the watershed. Downstream of the City of Chillán, water quality conditions were critical during the dry season, mainly due to the effects of the urban wastewater discharge. On the basis of the results from a Principal Component Analysis (PCA), modifications were introduced into the original WQI to reduce the costs associated with its implementation. WQI_DIR2 and WQI_DIR, which are both based on a laboratory analysis (Chemical Oxygen Demand) and three (pH, temperature and conductivity), respectively, four field measurements (pH, temperature, conductivity and Dissolved Oxygen), adequately reproduce the most important spatial and temporal variations observed with the original index. They are proposed as useful tools for monitoring global water quality trends in this and other, similar agricultural watersheds in the Chilean Central Valley. Possibilities and limitations for the application of the used methodology to watersheds in other parts of the world are discussed.     

Air Pollution and Heat Exposure Study in the Workplace in a Glass Manufacturing Unit in India

Air pollution in the workplace environment due to industrial operation have been found to cause serious occupational health hazard. Similarly, heat stress is still most neglected occupational hazard in the tropical and subtropical countries like India. The hot climate augments the heat exposure close to sources like furnaces. In this study an attempt is made to assess air pollution and heat exposure levels to workers in the workplace environment in glass manufacturing unit located in the State of Gujarat, India. Samples for workplace air quality were collected for SPM, SO₂, NO₂ and CO₂ at eight locations. Results of workplace air quality showed 8-hourly average concentrations of SPM: 165–9118 μg/m³, SO₂: 6–9 μg/m³ and NO₂: 5–42 μg/m³, which were below the threshold limit values of workplace environment. The level of CO₂ in workplace air of the plant was found to be in the range 827–2886 μg/m³, which was below TLV but much higher than the normal concentration for CO₂ in the air (585 mg/m³). Indoor heat exposure was studied near the furnace and at various locations in an industrial complex for glass manufacturing. The heat exposure parameters including the air temperature, the wet bulb temperature, and the globe parameters were measured. The Wet Bulb Globe Temperature (WBGT), an indicator of heat, exceeded ACGIH TLVs limits most of the time at all the locations in workplace areas. The recommended duration of work and rest have also been estimated.     

汉江水质评价的化学计量学研究

运用因子分析法对汉江各主要水质断面进行水质因子分析及综合评价,通过各主因子的方差贡献及因子得分得出各水质因子的赋权值,从而对所取断面进行水质污染程度的综合评价、分析与排序。同时运用聚类分析法对汉江17个断面的水质污染相似性进行分析,给出分类处理结果。     

南水北调东平湖水质变化趋势分析研究

采用了季节性肯达尔法水质趋势分析方法,分析了1984～2000年东平湖水质的变化情况,目前东平湖水质一般为Ⅴ类、Ⅵ类,个别年份为超Ⅴ类,氨氮平均值历年变化不大,一般均符合Ⅰ Ⅲ类水质,挥发酚和砷含量甚小,各年均符合Ⅰ类水。     

焦作市区大气污染状况与防治措施

根据“九五”期间焦作市区的大气污染监测资料，对市区大气污染状况进行了分析和评价，并对其成因进行了分析，提出了一些具体的防治措施。