全文获取类型
收费全文 | 468篇 |
免费 | 107篇 |
国内免费 | 159篇 |
专业分类
安全科学 | 37篇 |
废物处理 | 29篇 |
环保管理 | 34篇 |
综合类 | 369篇 |
基础理论 | 130篇 |
污染及防治 | 69篇 |
评价与监测 | 50篇 |
社会与环境 | 9篇 |
灾害及防治 | 7篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2022年 | 11篇 |
2021年 | 15篇 |
2020年 | 14篇 |
2019年 | 19篇 |
2018年 | 62篇 |
2017年 | 26篇 |
2016年 | 26篇 |
2015年 | 25篇 |
2014年 | 37篇 |
2013年 | 53篇 |
2012年 | 33篇 |
2011年 | 38篇 |
2010年 | 31篇 |
2009年 | 32篇 |
2008年 | 26篇 |
2007年 | 30篇 |
2006年 | 41篇 |
2005年 | 27篇 |
2004年 | 24篇 |
2003年 | 20篇 |
2002年 | 23篇 |
2001年 | 19篇 |
2000年 | 23篇 |
1999年 | 8篇 |
1998年 | 7篇 |
1997年 | 12篇 |
1996年 | 13篇 |
1995年 | 7篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1988年 | 2篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1983年 | 4篇 |
1981年 | 1篇 |
排序方式: 共有734条查询结果,搜索用时 15 毫秒
101.
针对电镀生产过程产生的难降解、高浓度的有机废水,采用Fe~(2+)活化过硫酸钠产生硫酸根自由基的高级氧化技术对其进行预处理。重点探讨了S_2O_8~(2-)投加量、n(Fe~(2+))∶n(S_2O_8~(2-))、废水pH等因素对有机物去除及废水可生化性的影响。实验结果表明,常温下,在S_2O_8~(2-)投加量为4.0 g/L、n(Fe~(2+))∶n(S_2O_8~(2-))为1.00、废水pH为7.0的条件下,废水的处理效果最佳,反应20 min后COD去除率可达70%,BOD_5/COD从原水的0.21升至0.40,废水的可生化性大幅提高,能够满足深度生化处理的要求。 相似文献
102.
V2O5/TiO2催化剂中毒机理的试验研究 总被引:1,自引:0,他引:1
选择性催化还原(SCR)催化剂是SCR烟气脱硝技术的核心,是整个SCR系统脱硝效率和经济性的决定因素.本文工作的主要研究思路是以钒钛SCR催化剂为研究对象,研究了H2O和SO2,以及相同含量下K、Na、Ca、Pb的氧化物对钒钛催化剂NO转化率的影响.H2O的存在会抑制V2O5/TiO2催化剂脱硝活性,而SO2在一定程度上促进(V2O5/TiO2)催化剂的SCR脱硝反应,提高NO转化率;碱金属K对钒钛催化剂的钝化作用都是最强,K2O和Na2O的掺入会抑制钒钛催化剂上V2O5的还原能力,而CaO和PbO的掺入对钒钛催化剂上V2O5的还原能力影响较小. 相似文献
103.
PBXN-5传爆药安全可靠性试验方法研究 总被引:1,自引:0,他引:1
为满足引信传爆序列对高可靠性、高安全性火工药剂的需求,通过小隔板试验及升降法试验对PBXN-5传爆药的输出能力和冲击波感度作了分析和研究,小样本试验发现:当施主药柱装药相同,随施主与受主间隔板厚度增加,可靠起爆概率明显降低;但随受主药柱的装药尺寸的减小,传爆概率却增大。总之,受主药柱直径越小,隔板越薄,使用可靠性越高,结合安全使用性,计算得到合适的可靠度数据,为微型火工品装药提供参数依据。 相似文献
104.
105.
Lijie Zhou Hongwu Wang Zhiqiang Zhang Jian Zhang Hongbin Chen Xuejun Bi Xiaohu Dai Siqing Xia Lisa Alvarez-Cohen Bruce E. Rittmann 《Frontiers of Environmental Science & Engineering》2021,15(1):16
106.
为从安全生产大数据中挖掘安全规律并最终提炼安全生产基础原理,首先在对安全生产大数据的定义及其内涵进一步阐释基础上,提出安全生产大数据采集的定义,并将其分解为3个过程;然后提出安全生产大数据的5W2H采集法,并对其内涵(采集原因,使用主体、采集者及采集对象,采集数据类型,采集边界,采集时间,采集数据量及其采集方法)进行详细分析;最后以思维路径为主、过程路径和技术路径为辅,建立安全生产大数据采集的一般模式。结果表明,安全生产大数据采集模式的研究可为安全生产大数据的存储、处理及其应用提供基础。 相似文献
107.
108.
Zhuoying WU Qing WANG Feng GUO Shenghua ZHANG Qipei JIANG Xin YU 《Frontiers of Environmental Science & Engineering》2014,8(2):205-214
Often as a result ofbiofilm formation, drinking water distribution systems (DWDS) are regularly faced with the problem of microbial contamination. Quorum sensing (QS) systems play a marked role in the regulation of microbial biofilm formation; thus, inhibition of QS systems may provide a promising approach to biofilm formation control in DWDS. In the present study, 22 bacterial strains were isolated from drinking water-related environments. The following properties of the strains were investigated: bacterial biofilm formation capacity, QS signal molecule N-acyl-L-homoserine lactones (AHLs) production ability, and responses to AHLs and AHL analogs, 3-chloro-4-(dichloromethyl)-5-hydroxy-2(5H)- furanone (MX) and 2(5H)-furanone. Four AHLs were added to developed biofilms at dosages ranging from 0.1 nmol.L J to 100nmol.L1. As a result, the biofilm growth of more than 1/4 of the isolates, which included AHL producers and non-producers, were significantly promoted. Further, the biofilm biomasses were closely associated with respective AHLs concentrations. These results provided evidence to support the idea that AHLs play a definitive role in biofilm formation in many of the studied bacteria. Meanwhile, two AHLs analogs demon- strated unexpectedly minimal negative effects on biofilm formation. This suggested that, in order to find an applicable QS inhibition approach for biofilm control in DWDS, the testing and analysis of more analogs is needed. 相似文献
109.
Many substances react with water in such a way that flammable gases are formed. For transport issues this reaction may possess a considerable hazard especially if the cargo is wetted by rain or by water from other sources. In the UN Recommendations on the Transport of Dangerous Goods these kinds of problems are addressed. The UN test N.5 “Test method for substances which in contact with water emit flammable gases” corresponds to this hazard. Classification according to the test method is done by measurement of the gas evolution rate of the flammable gas by any suitable procedure. At BAM a gravimetric approach is used to measure the gas evolution rate. In this paper we present the evaluation of the apparatus by means of an absolute calibration routine utilizing a reaction where a known amount of gas is produced as well as the evaluation of important parameters influencing the gas evolution rate using different substances. It can be shown that the apparatus is capable of measuring absolute gas volumes as low as 6 mL with an acceptable error of about 17% as determined from the reaction of Mg with demineralized water. 相似文献
110.
In this work, a new procedure for the enrichment of the trace amount of Cu2+, Ni2+, Co2+, Pb2+, Fe2+, and Zn2+ ions based on the utilization of multiwalled carbon nanotubes (MWCNT) modified with 2-(2-hydroxy-5-nitrophenyl)-4,5-diphenyl imidazole as chelating agent prior to their determination by flame atomic absorption spectrometry has been described. The influence of effective parameters including pH, amount of ligand and MWCNT, composition of eluent, and coexisting ions on recoveries of understudy metal ions was examined. At the optimum pH of 5.0, all metal ions were quantitatively sorbed onto the proposed solid phase and completely desorbed with 8?mL of 5.0?mol?L?1 HNO3. The detection limit of Cu2+, Co2+, Ni2+, Pb2+, Fe2+, and Zn2+ ions was 1.7, 2.4, 2.3, 2.9, 2.8, and 1.4?µg?L?1, while the preconcentration factor was 63 for Cu2+ and 94 for the other metal ions and relative standard deviations between 1.8 less than 3.0%. The proposed procedure was applied for the analysis of various samples. 相似文献