气相色谱法测定二硫化碳和甲硫醚

利用气相色谱(配火焰光度检测器,采用3mxφ2mm玻璃填充柱分离)对CS2和甲硫醚(DMS)两种含硫化合物进行了分离检测。该方法具有较高的灵敏度和良好的线性关系。结果表明:该分析对含硫气体的最小检测浓度在mg/m3级,在柱温为70℃,检测器温度为180℃,气化室温度为150℃,氮气流速为50mL/min时,CS2的回收率为98.66%,变异系数为2.12%;甲硫醚的回收率为98.66%,变异系数为1.56%。     

铁炭内电解法处理染料废水的试验

文章采用铁屑一活性炭内电解法作为光合细菌生化处理染料废水的预处理方法，考查了3个主要影响因素（铁炭比、停留时间、初始pH值）。结果表明，最佳的处理条件为：铁炭比为7：3，pH值为5，停留时间为60min。在上述最佳处理条件下，对初始COD为6790mg／L的染料废水处理效率可以达到66．1％，并且废水经预处理后可生化性得到大大提高，有利于后续生化处理的进行。     

Developing Canada's National Forest Carbon Monitoring, Accounting and Reporting System to Meet the Reporting Requirements of the Kyoto Protocol

The rate of carbon accumulation in the atmosphere can be reduced by decreasing emissions from the burning of fossil fuels and by increasing the net uptake (or reducing the net loss) of carbon in terrestrial (and aquatic) ecosystems. The Kyoto Protocol addresses both the release and uptake of carbon. Canada is developing a National Forest Carbon Monitoring, Accounting and Reporting System in support of its international obligations to report greenhouse gas sources and sinks. This system employs forest-inventory data, growth and yield information, and statistics on natural disturbances, management actions and land-use change to estimate forest carbon stocks, changes in carbon stocks, and emissions of non-CO₂ greenhouse gases. A key component of the system is the Carbon Budget Model of the Canadian Forest Sector (CBM-CFS). The model is undergoing extensive revisions to enable analyses at four spatial scales (national, provincial, forest management unit and stand) and in annual time steps. The model and the supporting databases can be used to assess carbon-stock changes between 1990 and the present, and to predict future carbon-stock changes based on scenarios of future disturbance rates and management actions.     

Carbon Dioxide Balance of Wood Substitution: Comparing Concrete- and Wood-Framed Buildings

In this study a method is suggested to compare the net carbon dioxide (CO₂) emission from the construction of concrete- and wood-framed buildings. The method is then applied to two buildings in Sweden and Finland constructed with wood frames, compared with functionally equivalent buildings constructed with concrete frames. Carbon accounting includes: emissions due to fossil fuel use in the production of building materials; the replacement of fossil fuels by biomass residues from logging, wood processing, construction and demolition; carbon stock changes in forests and buildings; and cement process reactions. The results show that wood-framed construction requires less energy, and emits less CO₂ to the atmosphere, than concrete-framed construction. The lifecycle emission difference between the wood- and concrete-framed buildings ranges from 30 to 130 kg C per m² of floor area. Hence, a net reduction of CO₂ emission can be obtained by increasing the proportion of wood-based building materials, relative to concrete materials. The benefits would be greatest if the biomass residues resulting from the production of the wood building materials were fully used in energy supply systems. The carbon mitigation efficiency, expressed in terms of biomass used per unit of reduced carbon emission, is considerably better if the wood is used to replace concrete building material than if the wood is used directly as biofuel.     

活性炭吸附与生物活性炭脱臭效果的比较研究

针对污水收集与处理系统中恶臭气体的组成与特性,比较分析不同情况下活性炭吸附与生物活性炭的脱臭效果。当干活性碳总处理气量达到1.3m~3/g时,出现穿透。将吸附饱和的活性炭填料塔转为生物滴滤反应器后,仍能较快的实现挂膜生长,达到满意的处理效果。直接运行的生物活性炭滴滤器对H_2S的处理效率在95％以上,并具有较强的恢复能力。H_2S平均出口浓度为0.052mg/m~3。循环液pH值与盐度在一定范围内对系统影响不大。     

活性污泥系统动力学模拟方法的综合分析

活性污泥法的应用现状和污水中氮磷排放标准的日益严格，使得传统数学模型已满足不了目前的要求，需要对活性污泥系统复杂的动力学规律进行有效模拟。文章在综合分析活性污泥动态模型国内外研究现状的基础上，介绍了3种占主流地位的模型：活性污泥数学模型、神经网络模型和混合模型。这3种模型在污水处理的设计、运行控制和工艺优化等方面各有其独到之处。     

Can Forest-protection carbon projects improve rural livelihoods? Analysis of the Noel Kempff Mercado climate action project,Bolivia

We studied the Noel KempffMercado Climate Action Project (NKMCAP),Bolivia, to assess whether forestprotection carbon (C) projects cansignificantly benefit local people. Wehypothesized that forest protection canonly securely deliver C if significantstakeholders are meaningfully andtransparently involved, traditional orcustomary rights are recognized and theirloss compensated for, and there are directlinkages between conservation anddevelopment objective. Our researchfocused on 53 members of the communities ofFlorida, Porvenir and Piso Firme and 36secondary stakeholders. In each of thevillages we held half-day meetings withcommunity leaders, complemented bysemi-structured one-hour interviews with 5,10, and 7 families, representing 20%, 10%and 8% of each community. The long-termimpact of the NKMCAP on the localcommunities may well be positive. However,in the short run, certain sections of thelocal communities are financially poorer. Forest protection projects clearly have thepotential to sequester C, protectbiodiversity and simultaneously contributeto sustainable rural development, but ifthey really are to improve rurallivelihoods, they must be designed andimplemented carefully and participatively.     

活性炭性质对其吸附水中硝基苯性能的影响

通过对活性炭进行HNO3氧化及热处理改性,研究了活性炭性质对其吸附硝基苯性能的影响.以低温液氮(N2/77 K)吸附测定活性炭的比表面积和孔容、孔径分布;以Boehm滴定、零电荷点pHPZC的测定及元素分析定量表征活性发表面含氧官能团变化.结果表明:经改性后,活性炭比表面积及总孔容略有减小,表面性质发生较大变化.改性活性炭对硝基苯的吸附容量明显改变,吸附容量大小依次为:AC1′＞AC0′＞AC0＞AC1.经硝酸氧化后,比表面积下降、存在过多表面含氧官能团是导致AC1吸附硝基苯能力降低的主要原因;而AC1'表面适量酚羟基所提供的氢键吸附是其对硝基苯吸附量增加的主要原因.     

Framing the Long-Term <Emphasis Type="Italic">In Situ</Emphasis> Liability Issue for Geologic Carbon Storage in the United States

This paper examines how legal standards of liability may apply to geologic carbon storage. The liability regime governing geologic carbon storage will shape the technology's cost-effectiveness and overall attractiveness. We classify potential sources of liability into operational, in situ, and climate liability. As a first step, we explore in situ liability in the United States. After summarizing legal standards of liability including negligence, breach of implied warranty, strict liability, and product liability, we discuss how liability may be addressed at the level of the federal government, state government, industry, and the firm. Finally, we address the implications of judicial treatment of liability for carbon storage, including the apportionment of liability and the adequacy of current regulations.     

Climate Change and Energy Technologies

The long time scale of the climate change problem and the inherent nature of the carbon cycle bring important implications for present technology development efforts. Even if major technology improvements are achieved for non-carbon-emitting technologies such as energy-intensity improvements, wind, solar, biomass, and nuclear over the course of the 21^st century, most examinations of potential future greenhouse emissions conclude that additional technology development will be required to stabilize greenhouse gas concentrations. The evelopment of an expanded suite of technologies including carbon capture and disposal, hydrogen systems and biotechnology hold the potential to dramatically reduce the cost of stabilizing greenhouse gas concentrations. This paper examines these technologies in the context of a global integrated assessment model of energy, agriculture, land-use, economics, and carbon cycle processes.