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71.
小球藻对水中有机酸类稀土配合物的富集 总被引:7,自引:1,他引:7
通过MINTEQA2程序研究了稀土有机酸类配合物在小球藻中的生物富集作用,结果表明:富集作用可用表面配合模型(SurfaceCoordinationModel)来解释,对同一稀土而言,其富集能力的大小与其有机酸1:1配合物的稳定常数呈负相关,稀土一EDTA,NTA〉Citrate,Tartrate的配合物在小球藻中的富集能力小于相应的稀土离子,而稀土而与Acetate的配合物要大于相应的稀土离子。 相似文献
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安全是一切生产活动的永恒主题。强化安全管理、严防事故发生。一直是铁路企业常抓不懈的首要任务。铁路企业仿佛是一个大的联动机,它点多、线长,各单位、各工种交叉作业,协调配合就显得极为重要。特别是编组站的调车作业,不仅是铁路运输生产过程中最重要的环节,更是铁路系统工伤事故多发的岗位。 相似文献
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以125 W高压汞灯为光源,研究了水中17α-乙炔基雌二醇(EE2)在铁(Ⅲ)-草酸盐(Ox)配合物体系中的光降解;考察了初始pH,c(Fe(Ⅲ))/c(Ox)配比及EE2初始质量浓度对EE2光降解的影响.结果表明:铁(Ⅲ)-草酸盐体系能引发EE2的光降解.在pH为3.50,c(Fe(Ⅲ))/c(Ox)为10.0/120.0时,光照160min;ρ(EE2)为2.0mg/L时的EE2光降解效率可达53.5%.在pH为3.00~6.00的实验范围内,当pH为3.00~4.00时,EE2的光降解效率最高;在ρ(EE2)为2.0~10.0 mg/L时,EE2的光降解效率随溶液中初始ρ(EE2)的增加而降低. 相似文献
76.
雌二醇在铁(Ⅲ)-草酸盐配合物体系中的光降解 总被引:1,自引:0,他引:1
以125W高压汞灯为光源,研究了水中雌二醇(E2)在铁(Ⅲ)-草酸盐体系中的光降解;考查了初始pH值、铁(Ⅲ)/草酸盐配比、E2初始浓度对E2光降解的影响.结果表明,铁(Ⅲ)/草酸盐体系能引发E2光降解.在pH=3·50,Fe(Ⅲ)/草酸盐配比为10·0/120·0μmol·l-1时,2mg·l-1E2光照160min可降解48·0%.在pH3·0—6·0范围内,pH值为3·0—4·0时E2降解率较高;在2·0—10·0mg·l-1范围内,光降解效率随水溶液中E2初始浓度的增加而降低. 相似文献
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在B3LYP/6-311+G(d,p)基组水平下采用密度泛函理论方法系统开展了以下工作:(1)优化得到1∶1、1∶2和1∶3铝-麦芽酚配合物10种可能构型的静态结构、NPA电荷以及能量参数,计算得到Al(ma)3配合物4种异构体的核磁共振、紫外和红外等光谱学数据并与文献实验值比较,证明本文采用的计算方法和模型适用于铝-麦芽酚体系的研究;(2)模拟1∶1和1∶2铝-麦芽酚配合物9种可能位点的水交换反应,其中3个位点计算得到的水交换反应速率对数log kex(s-1)分别为2.4(Al(ma)(H2O)2+4(cis to ma))、2.6(cis-Al(ma)2(H2O)+2(I))和3.0(trans-Al(ma)2(H2O)+2(I)),与实验值2.5(Al(ma)2+)和3.3(Al(ma)+2)相符,说明相应位点为反应活性位点;(3)探讨铝-麦芽酚配合物毒性与其形态结构之间的相关机制。 相似文献
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Feihu Yao Hailong Liu Guangquan Wang Liming Du Xiaofen Yin Yunlong Fu 《环境科学学报(英文版)》2013,25(6):1245-1251
Paraquat (PQ), a nonselective herbicide, is non-fluorescent in aqueous solutions. Thus, its determination through direct fluorescent methods is not feasible. The supramolecular inclusion interaction of PQ with cucurbit[7]uril was studied by a fluorescent probe titration method. Significant quenching of the fluorescence intensity of the cucurbit[7]uril-coptisine fluorescent probe was observed with the addition of PQ. A new fluorescent probe titration method with high selectivity and sensitivity at the ng/mL level was developed to determine PQ in aqueous solutions with good precision and accuracy based on the significant quenching of the supramolecular complex fluorescence intensity. The proposed method was successfully used in the determination of PQ in lake water, tap water, well water, and ditch water in an agricultural area, with recoveries of 96.73% to 105.77%. The fluorescence quenching values (ΔF) showed a good linear relationship with PQ concentrations from 1.0×10-8 to 1.2× 10-5 mol/L with a detection limit of 3.35×10-9 mol/L. In addition, the interaction models of the supramolecular complexes formed between the host and the guest were established using theoretical calculations. The interaction mechanism between the cucurbit[7]uril and PQ was confirmed by 1H NMR spectroscopy. 相似文献
80.
The amidoximated polyacrylonitrile (PAN) fiber Fe complexes were prepared and used as the heterogeneous Fenton catalysts for the degradation of 28 anionic water soluble azo dyes in water under visible irradiation. The multiple linear regression (MLR) method was employed to develop the quantitative structure property relationship (QSPR) model equations for the decoloration and mineralization of azo dyes. Moreover, the predictive ability of the QSPR model equations was assessed using Leave-one-out (LOO) and cross-validation (CV) methods. Additionally, the effect of Fe content of catalyst and the sodium chloride in water on QSPR model equations were also investigated. The results indicated that the heterogeneous photo-Fenton degradation of the azo dyes with different structures was conducted in the presence of the amidoximated PAN fiber Fe complex. The QSPR model equations for the dye decoloration and mineralization were successfully developed using MLR technique. MW/S (molecular weight divided by the number of sulphonate groups) and NN=N (the number of azo linkage) are considered as the most important determining factor for the dye degradation and mineralization, and there is a significant negative correlation betweenMW/S or NN=N and degradation percentage or total organic carbon (TOC) removal. Moreover, LOO and CV analysis suggested that the obtained QSPR model equations have the better prediction ability. The variation in Fe content of catalyst and the addition of sodium chloride did not alter the nature of the QSPR model equations. 相似文献