Synthesis and application of lignin-based copolymer LSAA on controlling non-point source pollution resulted from surface runoff

In this article,alkali lignin separated from paper pulp waste was grafted into a novel copolymer LSAA (a copolymer of lignin,starch, acrylamide,and acrylic acid).Its practical application effect and environmental safety were studied.The results of field simulation experiment indicated that the application of LSAA significantly affected the output of the runoff and pollutants.The runoff quantity was decreased by 16.67%-47.00%and the loads of total suspended solids (TSS),chemical oxygen demand (COD),total ...     

Effects of p,p'-DDE exposure on gonadal development and gene expression in Japanese medaka (Oryzias latipes)

Although 1,1-dichloro-2,2-bis(p-chlorophenyl)-ethylene (p,p'-DDE),the major and most persistent metabolite of dichlorodiphenyl-trichloroethane (DDT),was continually detected in wild fishes that showed abnormal gonad development such as intersex,little is known about the impact of p,p'-DDE exposure on gonad development in fishes.To survey the effects of p,p'-DDE on gonadal development and gene expressions,male juvenile (20-d post hatch) Japanese medaka (Oryzias latipes) was exposed to 1,5,20,and 100 μg/L p,p'-DDE for two months.Increased hepatosomatic index (HSI) and decreased gonadosomatic index (GSI) were found in the p,p'-DDE-treated groups.Intersex was found in 100 μg/L p,p'-DDE exposure group,as well as 100 ng/L 17α-ethynylestradiol (EE2)group.By quantitative real-time RT-PCR,it was found that gene expressions of vitellogenins (VTG-1,VTG-2),choriogenins (CHG-H,CHG-L),and estrogen receptor α (ER-α) in the liver of the fish were significantly up-regulated by p,p'-DDE exposure.VTC-1 and VTG-2 were recommended as the preferred biomarker for assessing anti-androgenic p,p'-DDE because they were the highest up-regulated among the genes and showed good dose-response relationship.The up-regulated ER-α suggested that a potential synergetic effect would occur when p,p'-DDE coexists with other ER-α-binding endocrine-disrupting chemicals (EDCs).     

含TMT的高分子整体多孔滤板去除水中铅的研究

制备含有2,4,6-三硫代三聚氰酸钠(TMT)的多孔高分子滤板,测定了该滤板对水溶液中Pb2+的吸附性能。讨论了溶液温度、pH值和流速对吸附性能的影响。结果表明:它对Pb2+具有较高的吸附容量和较快的吸附速度。铅离子的去除率超过90%,高分子滤板经再生实验后可循环使用。     

氨基黑10B的EM脱色研究

研究采用有效微生物(EM)对偶氮染料氨基黑10B进行脱色试验研究.试验结果表明.通过对 EM 茵种的培养务件的筛选试验.得到了活性强的、种类多的复合微生物茵群,其中酵母茵和乳酸茵占70%左右.其它茵种为光合细茵、放线茵以及霉茵等.而且该茵种在敞开静止培养方式、红糖质量浓度为lg/L、氨基黑10B的质量浓度为24mg/L条件下有利于生长.     

CFB锅炉多点排放大气环境污染风险预测

循环流化床锅炉（CFB）脱硫除尘系统复杂,操作不当容易导致大气污染事故的发生。通过对CFB锅炉多点排放明大气污染因子及其在大气中的扩散分析,建立了多点排放时SO2和总悬浮物颗粒（TSP）的大气环境污染的风险预测模型。模型结果较好地反映了CFB锅炉风险排污的影响因素及其环境容量的限值要求,这对于合理控制风险排污条件,加强现有CFB的运行管理是必要的。     

活性炭对重金属离子铅镉铜的吸附研究

研究了活性炭对水溶液中重金属离子铅镉铜的吸附行为,分析研究了ICP测定重金属铅镉铜的分析方法,并对分析的最佳条件进行了探讨。结果表明,100 mL溶液pH值为4.8,活性炭用量0.2000 g时,活性炭对Pb^2＋、Cd^2＋、Cu^2＋的最大吸附容量分别可达到52.54 mg/g、35.65 mg/g、57.05 mg/g。     

Pollinators,pests, and predators: Recognizing ecological trade-offs in agroecosystems

Ecological interactions between crops and wild animals frequently result in increases or declines in crop yield. Yet, positive and negative interactions have mostly been treated independently, owing partly to disciplinary silos in ecological and agricultural sciences. We advocate a new integrated research paradigm that explicitly recognizes cost-benefit trade-offs among animal activities and acknowledges that these activities occur within social-ecological contexts. Support for this paradigm is presented in an evidence-based conceptual model structured around five evidence statements highlighting emerging trends applicable to sustainable agriculture. The full range of benefits and costs associated with animal activities in agroecosystems cannot be quantified by focusing on single species groups, crops, or systems. Management of productive agroecosystems should sustain cycles of ecological interactions between crops and wild animals, not isolate these cycles from the system. Advancing this paradigm will therefore require integrated studies that determine net returns of animal activity in agroecosystems.

Electronic supplementary material

The online version of this article (doi:10.1007/s13280-015-0696-y) contains supplementary material, which is available to authorized users.     

区域分异视角下乡村企业入城意愿分析——基于浙、豫、川三省193家企业的实证研究

乡村企业入城是实现我国城镇化发展的基本路径。利用浙江、河南、四川三省193家乡村企业的实地调查数据,运用多元有序Logistic回归模型进行相关验证,实证分析我国东中西部三个省份的乡村企业入城意愿及其影响因素。通过对调研数据的描述统计发现:有58.55%的乡村企业主有入城意愿,仅有21.24%的乡村企业主不愿意或非常不愿意搬迁,集群环境、土地价格、运输成本等是企业愿意搬迁的主要原因,土地价格政策、当地经济发展水平、产品产销信息、集群环境是影响企业搬迁方向的重要因素,当地的土地、税收和融资等政府政策对于企业是否入城产生重要影响。通过多元有序Logistic回归模型估计结果表明:企业总资产、土地价格、运输成本、集群环境、与政府关系对入城意愿有显著负向影响,税收政策有显著正向影响,这些影响因素主要是通过影响企业的显性成本(土地价格、运输成本),以及企业的交易成本、寻租成本等隐性成本(集群环境、与政府关系和税收政策),进而影响企业的迁移意愿,且浙江、河南与四川三地计量结果差异显著。在上述研究的基础上,本文提出相应的政策建议。     

Environmental impact assessment of a WtE plant after structural upgrade measures

The study focuses on analysing the evolution of environmental impacts caused by a medium–large Italian WtE plant before and after revamping and maintenance operations, with the aim of providing an evaluation of how much these structural upgrade measures may affect the total environmental performance.LCA methodology was applied for the modelling and comparison of six WtE scenarios, each describing the main structural upgrades carried out in the plant over the years 1996–2011. The comparison was conducted by adopting 1 ton of MSW as the functional unit, and the net contribution from energy recovery to power generation was distinguished by defining consistent national grid electricity mixes for every year considered. The Ecoindicator99 2.09 impact assessment method was used to evaluate the contribution to midpoint and endpoint categories (e.g. carcinogens, respiratory inorganics and organics, climate change, damage to human health). Lastly, the “Pedigree quality matrix” was applied to verify the reliability and robustness of the model created.As expected, the results showed better environmental scores after both the implementation of new procedures and the integration of operations. However, while a net reduction of air emissions seems to be achievable through dedicated flue gas treatment technologies, outcomes underscored potentials for improving the management of bottom ash through the adoption of alternative options aimed to use that solid residue mainly as filler, and to decrease risks from its current disposal in landfill. If the same effort that is put into flue gas treatment were devoted to energy recovery, the targets for the WtE plant could be easily met, achieving a higher sustainability. This aspect is even more complex: national policies for implementing greener and renewable energy sources would result in a lower impact of the national energy mix and, hence, in a lower net avoided burden from energy recovery.The study confirmed the expected improvements, indicating quantitatively the lower environmental impact resulting from structural upgrade operations in a WtE plant. Furthermore, the work highlights the importance of considering the evolution of the national energy mix in LCA studies, especially during the present years of transition from fossil fuels to renewable sources.     

Assessing the costs for adaptation of marine constructions to sea-level rise

Marine constructions are highly vulnerable to climate change and sea-level rise (SLR), leading to increased risk rates of destruction and the potential closure of ports, harbors, and marinas along the coast. We present a cost-adjustment analysis for such constructions along the south-eastern Mediterranean coast, which takes into account the physical characteristics of the constructions, and environmental uncertainty factors. At 0.5 m SLR, the estimated adjustment cost is USD 280 million, and at 1 m SLR, the estimated cost is USD 505 million. These costs are equivalent to 0.091% and 0.165% of the Israeli gross domestic production, respectively. Although high, these adjustment costs are lower than the costs of future damage that will accrue if we fail to act. This implies that the adaptation-policy approach to controlling for the risk of SLR will provide benefits to the economic marine sectors and the public at large.