利用粉煤灰制备高纯超细氧化铝粉体的研究

利用粉煤灰为原料制备高纯超细氧化铝粉体。给出了采用硅酸二钙晶相转变自粉化、高效分散剂———碳化法从粉煤灰中制备氧化铝方法的工艺路线 ,确定了从粉煤灰制备高纯超细氧化铝粉体的最佳工艺条件 ,为粉煤灰的高价值利用开辟了一条新途径     

循环流化床锅炉床温控制方法

就目前电厂循环流化床锅炉运行中存在的床温波动问题，讨论了导致床温波动的因素，并针对性地提出了控制床温的一些措施。     

Occurence and Distribution of Polycyclic Aromatic Hydrocarbons in Ankara Precipitation

Urban atmospheric environment contains many trace organic pollutants that are related to the incomplete fuel combustion in domestic heating, industrial plants and automobile traffic. Removal of these pollutants from the atmosphere takes place through wet and dry deposition as well as chemical transformations. In this study, concentrations of polycyclic aromatic hydrocarbons (PAHs) in wet deposition samples were determined at an urban site of Turkey. Wet and dry deposition samples were collected using Andersen Rain Sampler. The sampler was modified accordingly for the collection of organic pollutants. Collected samples were preconcentrated by using solid phase extraction (SPE) disks and consecutively analyzed by Gas Chromatography-Mass Spectrometry (GC-MS). Among the 13 compounds quantified in this study, anthracene, fluoranthene, and pyrene were found more frequently and at elevated concentrations (202, 271 and 260 ng L^-1 mean concentrations, respectively).Concentrations of PAHs were found to be high in winter period.     

安庆石化热电厂正压浓相气力输灰系统

详细介绍了安庆石化热电厂正压浓相气力输灰系统的组成、特点及运行情况。该系统自投运以来，运行情况良好。     

事故前期发展过程浅析

任何事故发生之前都有一段发展演变的过程.当失误不断积累,超过系统或组织自身的自适应能力以后,一旦激发事件出现,就有可能导致事故的发生.本文在分析事故致灾条件的基础上,将其前期发展过程分为了7个阶段,得出了事故前期发展过程流程图.     

抽出式通风煤巷掘进过程中粉尘浓度分布规律的数值模拟

根据气固两相流理论，针对矿井掘进工作面的特点，采用计算流体力学的离散相模型（DPM）对掘进工作面通风过程中粉尘浓度进行数值模拟，总结抽出式通风掘进巷道中粉尘浓度的沿程分布及变化规律。     

树脂相分光光度法测定水中痕量苦味酸

建立了树脂相分光光度法测定水中痕量苦味酸的新方法。该法灵敏度高,表观摩尔吸光系数为1.08×105L/(mol·cm);精密度理想(测定苦味酸质量浓度为5μg/mL的实验5次,相对标准偏差为1.0%);线性范围为0～7.0μg/mL;以3σ衡量,检出限为0.14μg/mL;加标回收率为97%～103%。采用该法直接测定水样中的苦味酸、间接测定烟草中的烟碱,结果令人满意。     

Hydrothermal liquefaction phase behavior of microalgae & model compounds in fused silica capillary reactor

A fused silica capillary reactor combined with a heating/cooling stage, a microscope and a digital camera were used to investigate phase behavior during the hydrothermal liquefaction of microalgae (Dunaliella tertiolecta) and model compounds, including soya protein and glycine, starch, glucose and xylose, stearic acid and palmitic acid. Bubbles were generated at 246°C and disappeared at 360°C upon heating when Dunaliella tertiolecta used as feedstocks. Moreover, liquid products were generated at 300°C upon heating and oily liquid products began to separate out at 250°C upon cooling. The phase behavior of soya protein was similar to that of the Dunaliella tertiolecta. Meanwhile, there only observed the bubbles generation during hydrothermal liquefaction of glycine. Heating the starch, glucose and xylose above 350°C generated black solids from carbonization. Stearic acid and palmitic acid only had the process of melting, dissolution, dispersion and precipitation.     

Determination of Au(III) and Pd(II) ions by flame atomic absorption spectrometry in some environmental samples after solid phase extraction

A simple and sensitive solid phase extraction method was developed for simultaneous separation and preconcentration of gold and palladium ions with N-(4-methylphenyl)-2-{[(4-phenyl-5-pyridine-4-yl-4H-1,2,4-triazol-3-yl)thio]acetyl}hydrazine carbo thioamide complex on Amberlite XAD-1180 resin before their determination by flame atomic absorption spectrometry. Some analytical parameters such as HNO₃ concentration of the sample solution, amount of complexing agent, sample volume, eluent type and volume, effects of foreign ions and adsorption capacity of the resin were investigated for quantitative recovery of gold and palladium ions. The effects of some anions and cations were also examined. Under optimum conditions, the detection limits for gold and palladium ions were found to be 0.29 and 0.19 μg L^?1, respectively. The preconcentration factor for gold and palladium was 250. After being validated by standard addition and analysis of standard reference material, the procedure was successfully applied to the analysis of sea and stream water, anodic slime, gold ore, soil and electronic waste.     

顶空固相微萃取-气相色谱法测定水中氯苯类化合物

采用顶空固相微萃取（HS －SPME）技术萃取水中6种氯苯类化合物，全面分析对目标物萃取效率的影响因素，并确定萃取试验的最佳条件。用顶空固相微萃取联合气相色谱法（HS －SPME －GC）测定水中6种氯苯类化合物，方法在0.500 ng／L～2.00×10^5 ng／L范围内线性良好，检出限为0.05 ng／L ～2000 ng／L，空白样品加标回收率为69.8％～121％， RSD为4.8％～18.3％。用该方法测定实际水样，平行双样的相对偏差低于20％。