SBR法处理垃圾渗滤液及其同时硝化反硝化生物脱氮研究

采用SBR系统处理城市垃圾渗滤液，研究了不同C／N、130和MLSS对同时硝化反硝化脱氮效率的影响。结果表明：总氮去除率随着C／N、MLSS升高而上升；DO越低，总氮去除率越高；当进水CODCr与NH3-N浓度分别为420mg／L和112mg／L,DO和MLSS分别为1．5mg／L和5016mg／L时，CODCr、NH3-N及TN去除率分别为81．54％、96．57％和46．66％。根据试验结果，对同时硝化反硝化一个代表周期作了分析。     

螺旋升流反应器氧传递性能的试验研究

本文主要针对螺旋升流反应器技术特性，对工艺的好氧反应器进行了氧传递性能的试验研究，考察了反应器水深、曝气量等对螺旋升流反应器氧转移过程的影响；并对试验数据进行回归，得到了氧传质总系数与螺旋升流反应器内表现气速的数学关系。试验结果表明，螺旋升流反应器具有良好的氧传递特性，是一种新型的高效、节能的污水处理反应技术。     

新型生物转筒处理食品生产废水的试验研究

生物转盘（筒）是处理中、小流量废水的一种较经济有效的方法，本试验采用新型填料式生物转筒作为关键设备处理食品加工废水，结果表明：系统对COD、BOD5、SS和LAS有显著的去除效果，当进水COD为1200～1700mg/L，BOD5为600～1200mg/L时，出水水质可以达到广东省地方标准《水污染物排放限值》（DB44／26-2001）中的二级标准。     

云天化3#循环流化床锅炉项目技术经济分析

云天化股份公司在2004年建造了3#循环流化床锅炉，以煤代气。它可以缓解公司原料天然气的紧张状况，并能带来很大的经济效益。从技术经济的角度对该项目的技术先进性、可靠性及内部收益率、投资回收期、净现值等技术指标进行了分析。     

厌氧-好氧一体化反应器处理高浓度有机废水的运行特性研究

本实验采用新型厌氧—好氧一体化反应器处理高浓度有机废水,主要研究了系统的启动与运行性能,并对系统的NH3 N去除效果作了初步考察。实验结果表明:在16℃～24℃的自然温度下,采用递增负荷、厌氧和好氧分期启动的方式,系统可在38天内达到较好的启动效果;在系统负荷运行期内,当系统总进水COD浓度平均值为3601 8mg/L,总出水COD浓度平均值为384 0mg/L,系统容积负荷平均值为2 54kgCOD/(m3·d),系统总HRT平均值为35 1h时,系统总COD去除率平均值达90 6%。实验还发现:当进水NH3 N浓度为280 3～350 7mg/L,整个系统的NH3 N去除率在68 5%～91 7%,平均为81 0%。由此说明,本反应器具有很好的COD去除性能和NH3 N去除效果,适合于处理COD浓度高且含有中等NH3 N浓度的有机废水。     

电化学反应器吸附去除氟离子的研究

采用改性活性炭粉末对用纯净水加氟化钠配制而成的含氟水溶液进行动态电吸附去除实验.研究不同电压、电吸附时间,以及Cl-和SO2-4对氟离子去除的影响,并探讨吸附动力学和吸附方程.实验结果表明:活性炭对氟离子的吸附等温方程符合Freundlich方程,吸附动力学符合一级动力学方程;活性炭对氟离子去除与所施加的电位、吸附时间等因素有关,施加的电位越大,去除效果越好;随着吸附去除时间的延长,氟离子浓度下降趋缓;Cl-对氟离子去除影响很小,而SO2-4对氟离子去除有显著的不利影响.     

Hydrothermal liquefaction phase behavior of microalgae & model compounds in fused silica capillary reactor

A fused silica capillary reactor combined with a heating/cooling stage, a microscope and a digital camera were used to investigate phase behavior during the hydrothermal liquefaction of microalgae (Dunaliella tertiolecta) and model compounds, including soya protein and glycine, starch, glucose and xylose, stearic acid and palmitic acid. Bubbles were generated at 246°C and disappeared at 360°C upon heating when Dunaliella tertiolecta used as feedstocks. Moreover, liquid products were generated at 300°C upon heating and oily liquid products began to separate out at 250°C upon cooling. The phase behavior of soya protein was similar to that of the Dunaliella tertiolecta. Meanwhile, there only observed the bubbles generation during hydrothermal liquefaction of glycine. Heating the starch, glucose and xylose above 350°C generated black solids from carbonization. Stearic acid and palmitic acid only had the process of melting, dissolution, dispersion and precipitation.     

Emergency shutdown of fluidized bed reaction systems

With several industrial applications of fluidized bed technology recently commercialized worldwide, it becomes essential to develop safe operation methods for fluidized bed reaction systems (FBRSs) to prevent any influence on their process values, which lead to accidents. To preventing any disaster or malfunction in an FBRS, an emergency shutdown system (ESD) is initiated, closing the reaction system in case of any abnormality by effectively isolating the flammable gas. However, an ESD is also prone to the “inactivation problem,” in which in the case of failure it initiates the emergency shutdown, even when the operating conditions of the reaction system are abnormal. It is also vulnerable to a “malfunction problem,” where the emergency shutdown is performed even when the operating conditions of the reaction system are normal. In this study, these problems were solved by investigating a reaction system through the monitoring of appropriate parameters and setting up of trigger levels, which reflect the uniqueness of an FBRS using an ESD. The parameters were identified by analyzing the scenario leading to an accident. The trigger levels were determined as the points at which the loss is smaller in the presence of an ESD, as compared to the value of the loss function in the presence or absence of an ESD. Furthermore, the ESD design model was applied as a case study in the ammoxidation process of propylene. The results showed that an ESD can prevent an approximately 8 billion yen of loss due to accidents in plant operations, against an investment of 200 million yen.     

Application of 1D and 2D MFR reactor technology for the isolation of insecticidal and anti-microbial properties from pyrolysis bio-oils

Valuable chemicals can be separated from agricultural residues by chemical or thermochemical processes. The application of pyrolysis has already been demonstrated as an efficient means to produce a liquid with a high concentration of desired product. The objective of this study was to apply an insect and microorganism bioassay-guided approach to separate and isolate pesticidal compounds from bio-oil produced through biomass pyrolysis. Tobacco leaf (Nicotianata bacum), tomato plant (Solanum lycopersicum), and spent coffee (Coffea arabica) grounds were pyrolyzed at 10°C/min from ambient to 565°C using the mechanically fluidized reactor (MFR). With one-dimensional (1D) MFR pyrolysis, the composition of the product vapors varied as the reactor temperature was raised allowing for the selection of the temperature range that corresponds to vapors with a high concentration of pesticidal properties. Further product separation was performed in a fractional condensation train, or 2D MFR pyrolysis, thus allowing for the separation of vapor components according to their condensation temperature. The 300–400°C tobacco and tomato bio-oil cuts from the 1D MFR showed the highest insecticidal and anti-microbial activity compared to the other bio-oil cuts. The 300–350 and 350–400°C bio-oil cuts produced by 2D MFR had the highest insecticidal activity when the bio-oil was collected from the 210°C condenser. The tobacco and tomato bio-oil had similar insecticidal activity (LC₅₀ of 2.1 and 2.2 mg/mL) when the bio-oil was collected in the 210°C condenser from the 300–350°C reactor temperature gases. The 2D MFR does concentrate the pesticidal products compared to the 1D MFR and thus can reduce the need for further separation steps such as solvent extraction.