新型灌浆添加剂的研究与开发

矿井火灾是煤矿的重大灾害之一 ,在我国造成了严重的经济损失和人员伤亡。黄泥灌浆是防止煤矿自然发火应用最广泛的技术之一 ,但存在着泥浆脱水性差、阻化效果不稳定、与民争地等不足之处。因此 ,笔者提出了一种新的改进方法 ,利用阻化剂技术 ,开展了灌浆添加剂的开发和研究工作 ,最终研制成功了以吸湿性无机盐为基料 ,以多种功能表面活性剂为辅料的新型灌浆添加剂。通过阻化实验、保水实验和堵漏风性能实验表明 :在泥浆中添加少量的该灌浆添加剂 ,可大幅度提高泥浆的阻化效果和保湿性能 ;而当泥浆中的添加剂浓度仅为 5 %时 ,泥浆的阻化率可达到 80 %以上。同时 ,含有该添加剂的泥浆 ,其堵漏风性能并无明显降低。     

预防煤炭自燃的注砂技术实验研究

山砂是我国西北部矿区地表的主要自然资源之一,但如用其直接作为煤矿注浆防灭火的原料,不仅会造成输送管路的堵塞,还会引起输送管路的严重磨损。为此,首先研究了常见增稠剂羧甲基纤维素、聚丙烯酰胺和聚丙烯酸钠等对砂粒的悬浮性能,实验结果表明它们只能延缓砂粒的沉降。进而从理论上分析了砂粒悬浮的条件,发现具有一定屈服应力的假塑性流体特性的液体才能悬浮砂粒;并且悬浮砂粒粒径越大,所需屈服应力也越大。基于理论分析,研制了具有该特性的浆液,山砂在该浆液中不仅具有良好的悬浮性能,浆液还具有输送阻力小的特性。管道输送试验表明,浆液稳定性和流动阻力符合实际要求。     

Impact of Human Activities on Carbon Dioxide (CO<Subscript>2</Subscript>) Emissions: A Statistical Analysis

Summary The balance of evidence suggests a perceptible human influence on global ecosystems. Human activities are affecting the global ecosystem, some directly and some indirectly. If researchers could clarify the extent to which specific human activities affect global ecosystems, they would be in a much better position to suggest strategies for mitigating against the worst disturbances. Sophisticated statistical analysis can help in interpreting the influence of specific human activities on global ecosystems more carefully. This study aims at identifying significant or influential human activities (i.e. factors) on CO₂ emissions using statistical analyses. The study was conducted for two cases: (i) developed countries and (ii) developing countries. In developed countries, this study identified three influential human activities for CO₂ emissions: (i) combustion of fossil fuels, (ii) population pressure on natural and terrestrial ecosystems, and (iii) land use change. In developing countries, the significant human activities causing an upsurge of CO₂ emissions are: (i) combustion of fossil fuels, (ii) terrestrial ecosystem strength and (iii) land use change. Among these factors, combustion of fossil fuels is the most influential human activity for CO₂ emissions both in developed and developing countries. Regression analysis based on the factor scores indicated that combustion of fossil fuels has significant positive influence on CO₂ emissions in both developed and developing countries. Terrestrial ecosystem strength has a significant negative influence on CO₂ emissions. Land use change and CO₂ emissions are positively related, although regression analysis showed that the influence of land use change on CO₂ emissions was still insignificant. It is anticipated, from the findings of this study, that CO₂ emissions can be reduced by reducing fossil-fuel consumption and switching to alternative energy sources, preserving exiting forests, planting trees on abandoned and degraded forest lands, or by planting trees by social/agroforestry on agricultural lands.     

某“W”型锅炉炉效低的综合治理

针对某锅炉经济性差的问题，从设备、运行及自动控制等方面分析，并进行了相应整改。影响炉效的主要因素有煤质恶化、灰渣含碳量高、排烟温度高和CO浓度高等，同时炉膛燃烧不稳定也是影响燃烧效率的重要因素。通过漏风整改、制粉系统优化、燃烧优化调整和控制系统优化等方法有效提高了锅炉经济性。研究表明：分析锅炉经济性降低的影响因素时应抓住主要因素，兼顾其他，科学的生产管理是保证锅炉运行经济性的重要基础；入炉煤质恶化是最主要的外在因素；良好的自动控制系统能有效稳定燃烧参数，提高燃烧效率；降低飞灰含碳量的主要工作应集中在制粉系统优化调整；完整而系统的燃烧调整试验能够保证锅炉运行控制参数的科学合理，并需要正确调整氮氧化物排放和锅炉效率之间的关系。     

复合链式结构下中国林业碳库系统测度模型构建

温室气体上升导致的全球气候变暖问题不容忽视,增加森林碳汇和木质林产品碳储是缓解温室效应的有效途径。根据森林碳汇功能与林产品碳储功能的关联理论与模型,推导和改进包括森林子碳库、土壤子碳库及木质林产品子碳库在内的林业碳库核算模型及方法,以实现目标碳从森林碳库向木质林产品碳库的过渡与转移。基于气候变化背景下森林-林产品产业链的发展现状,构建包括森林子碳库和林产品子碳库的复合一体化林业碳库模型,使之为中国林业碳库的计量与评价提供判据。首先,对包含森林子碳库和木质林产品子碳库在内的世界林业碳库的发展现状进行探讨,归纳和比较国内外主流的关联林业碳库评估方法模型,从而对中国林业碳库模型的构建提供理论背景支持和逻辑方法支撑。其次,分析现有中国林业碳库评估存在的优势和弊端,找出适合中国林业特点的国家碳库创新评估路径,运用政府间气候变化专门委员会指定的生产法的思路,通过分析目标碳在林产品产业链生产、加工等过程中的流入和支出,提出创新中国林业碳库的模型构想并对其系统内涵进行分析。最后,赋予中国林业碳库系统模型数学表达,分析其数理结构并进行逻辑演绎,在森林子碳库和木质林产品子碳库两个复合链式体系下构建中国林业碳库系统测度模型(ForestProducts Carbon Model/FPCM)。     

Characterizing the Width of Amphibian Movements During Postbreeding Migration

Habitat linkages can help maintain connectivity of animal populations in developed landscapes. However, the lack of empirical data on the width of lateral movements (i.e., the zigzagging of individuals as they move from one point to point another) makes determining the width of such linkages challenging. We used radiotracking data from wood frogs (Lithobates sylvaticus) and spotted salamanders (Ambystoma maculatum) in a managed forest in Maine (U.S.A.) to characterize movement patterns of populations and thus inform planning for the width of wildlife corridors. For each individual, we calculated the polar coordinates of all locations, estimated the vector sum of the polar coordinates, and measured the distance from each location to the vector sum. By fitting a Gaussian distribution over a histogram of these distances, we created a population‐level probability density function and estimated the 50th and 95th percentiles to determine the width of lateral movement as individuals progressed from the pond to upland habitat. For spotted salamanders 50% of lateral movements were ≤13 m wide and 95% of movements were ≤39 m wide. For wood frogs, 50% of lateral movements were ≤17 m wide and 95% of movements were ≤ 51 m wide. For both species, those individuals that traveled the farthest from the pond also displayed the greatest lateral movement. Our results serve as a foundation for spatially explicit conservation planning for pond‐breeding amphibians in areas undergoing development. Our technique can also be applied to movement data from other taxa to aid in designing habitat linkages. Caracterización de la Amplitud de Movimiento de Anfibios durante la Migración Pos‐Reproducción     

Performance,combustion and emission characteristics of a single-cylinder,four-stroke,direct injection diesel engine operated on a dual-fuel mode using Honge oil methyl ester and producer gas derived from biomass feedstock of different origin

Renewable and alternative fuels have numerous advantages compared with fossil fuels, as they are renewable and biodegradable, and provide food and energy security and foreign exchange savings besides addressing environmental concerns and socio-economic issues. In this context, present work was carried out to investigate the feasibility of alternative and renewable fuels derived from biomass feedstock of different origin for engine applications. The present study was also extended to study the effect of producer gas composition derived from different biomass feedstock on the performance, combustion and emission characteristics of a single-cylinder, four-stroke, direct injection stationary diesel engine operated on a dual-fuel mode using Honge oil methyl ester (HOME) and producer gas induction. The performance of the engine was evaluated with a constant injection timing of 27° before top dead centre, an injection pressure of 205 bar for the diesel–producer gas combination and 230 bar for the HOME–producer gas combination and a compression ratio of 17.5. The results showed that the performance of the dual-fuel engine varies with the composition of the producer gas and depends on the type of biomass feedstock used in the gasifier. Experimental investigations on the dual-fuel engine showed that brake thermal efficiency values for the engine operated using HOME–producer gas derived from babul, neem and honge woods were found to be 17.2, 14.3 and 11.56% respectively, compared to 23.8% for diesel–producer gas operation at 80% load. However, the results showed better engine performance with lower exhaust emission levels for the operation of HOME–producer gas derived from the ordinary or babul wood compared with the operation of that derived from the neem and Honge woods. In view of this, present study reveals that use of alternative and renewable fuels for dual fuel engine can be considered as an immediate solution for the development of rural areas and emergency use in the event of severe diesel fuel shortage.     

肥煤自燃全过程热动力学特征参数研究

实验测定了林西矿肥煤样品30~900℃煤自燃全过程热动力学特征参数,得出:TG/DTG曲线显示煤样DTG初始临界温度45℃,干裂温度122℃,活性温度195℃,增速温度265℃,质量极大值温度342℃,着火温度465℃,最大热失重速率温度515℃和燃尽温度690℃;DSC曲线显示,煤样初始放热温度60℃、最大热释放速率温度511℃。结合TG-DTG-DSC曲线综合分析可知,煤温达到510℃左右时煤样反应最剧烈。由煤自燃标志气体测定实验系统得出:煤温130℃后CO,CO 2释放量迅速增加,210℃增加速度下降;CH 4,C 2 H 6含量变化具有规律性且两者变化相近;C 2 H 4出现温度为130℃;C 2 H 4/C 2 H 6比值在190~350℃有较强的规律性,呈上升趋势且上升速度较快;350℃之后,CH 4,C 2 H 6,C 2 H 4体积分数均开始急剧增大;C 2 H 4/CO与C 2 H 4/CO 2变化趋势大致相同,在130~350℃时缓慢增长,达到350℃后比值呈指数形式上升。经拟合曲线,得到活化能的3个突变点温度:70,180,220℃,其中180℃与交叉点温度相吻合。通过以上研究,得到了肥煤自燃全过程的热力学特征参数,为实际生产中防治煤自燃提供了理论依据。     

不同自燃倾向性煤的指标气体产生规律实验研究

为研究不同自燃倾向性煤的自燃指标气体变化规律，提高对煤早期自燃预测预报的准确度，采用程序升温实验系统，得到内蒙古褐煤、神东长焰煤、河南气煤及枣庄焦煤4种不同变质程度煤的氧化时间随温度的变化关系，以及指标气体浓度在煤氧化过程中的变化规律。结果表明:自燃倾向性最高的褐煤应以CO和乙烯作为煤自燃早期预报的首选指标气体；易自燃的长焰煤应采用乙烯和烯烷比为主、以CO为辅的煤自燃判定指标；自燃倾向性较低的气煤应以乙烯和烯烷比作为煤自燃预报指标；CO是自燃倾向性最低的焦煤的最佳自燃预报指标气体。     

氢安全研究现状及面临的挑战

氢能具有储运便捷、来源多样、洁净环保等突出优点,许多国家把发展氢能作为重要的能源战略。氢安全是氢能大规模商业化应用的重要保障。在分析国内外氢安全领域近年来最新研究进展的基础上,依次从氢泄漏与扩散、氢燃烧与爆炸、氢与金属材料相容性及氢风险评价等方面,系统总结了国内外氢安全研究面临的挑战,并对我国氢安全的发展提出了建议。