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161.
162.
A.K. Seta A.D. Karathanasis 《Journal of environmental science and health. Part. B》2013,48(5):949-968
Abstract This study evaluated the role of water dispersible colloids with diverse physicochemical and mineralogical characteristics in facilitating the transport of metolachlor through macropores of intact soil columns. The soil columns represented upper solum horizons of an Alfisol in the Bluegrass region of Kentucky. Three different colloid suspensions tagged with metolachlor [2‐chloro‐N‐(2‐ethyl‐6‐methylphenyl)‐N‐(2‐methoxy‐l‐methylethyl)acetamide] were introduced at a constant flux into undisturbed soil columns. The eluents were collected and analyzed periodically for colloid and metolachlor concentrations. Colloid recovery in the eluents ranged from 54 to 90 %. The presence of colloids enhanced the transport of metolachlor by 22 to 70 % depending on the colloid type and mobility. Colloids with higher pH, organic carbon, cation exchange capacity (CEC), total exchangeable bases (TEB), surface area (SA), and electrophoretic mobility (EM), showed better mobility, greater affinity for interaction with the herbicide and, thus, greater potential to co‐transport metolachlor. In contrast, increased level of kaolinite, Fe, and Al inhibited metolachlor adsorption and transport. In spite of the increased transportability of metolachlor by the presence of soil colloids, the colloid bound herbicide portion accounted for a very small part of the observed increase. This suggests that surface site exclusion mechanisms and preferential sorption induced by the presence of colloids are more important than ion exchange phenomena in promoting herbicide mobility in subsurface environments. 相似文献
163.
Antony A Bassendeh M Richardson D Aquilina S Hodgkinson A Law I Leslie G 《Chemosphere》2012,86(8):829-836
Granular activated carbon (GAC) exhaustion rates on pulp and paper effluent from South East Australia were found to be a factor of three higher (3.62 cf. 1.47 kg m−3) on Kraft mills compared to mills using Thermomechanical pulping supplemented by Recycled Fibre (TMP/RCF). Biological waste treatment at both mills resulted in a final effluent COD of 240 mg L−1. The dissolved organic carbon (DOC) was only 1.2 times higher in the Kraft effluent (70 vs. 58 mg L−1), however, GAC treatment of Kraft and TMP/RCF effluent was largely different on the DOC persisted after biological treatment. The molecular mass (636 vs. 534 g mol−1) and aromaticity (5.35 vs. 4.67 L mg−1 m−1) of humic substances (HS) were slightly higher in the Kraft effluent. The HS aromaticity was decreased by a factor of 1.0 L mg−1 m−1 in both Kraft and TMP/RCF effluent. The molecular mass of the Kraft effluent increased by 50 g mol−1 while the molecular mass of the TMP/RCF effluent was essentially unchanged after GAC treatment; the DOC removal efficiency of the GAC on Kraft effluent was biased towards the low molecular weight humic compounds. The rapid adsorption of this fraction, coupled with the slightly higher aromaticity of the humic components resulted in early breakthrough on the Kraft effluent. Fluorescence excitation-emission matrix analysis of the each GAC treated effluent indicated that the refractory components were higher molecular weight humics on the Kraft effluent and protein-like compounds on the TMP/RCF effluent. Although the GAC exhaustion rates are too high for an effective DOC removal option for biologically treated pulp and paper mill effluents, the study indicates that advanced organic characterisation techniques can be used to diagnose GAC performance on complex effluents with comparable bulk DOC and COD loads. 相似文献
164.
再生粗骨料混凝土柱耐火性能试验与理论分析 总被引:2,自引:0,他引:2
为研究再生粗骨料混凝土柱的耐火性能,进行了1个足尺的再生粗骨料混凝土柱和足尺的1个普通混凝土柱在竖向恒定荷载和温度场耦合作用下的耐火性能试验研究,2个试件的混凝土设计强度均为C30,2个柱采用相同的轴压比施加竖向荷载。在试验研究基础上,比较分析了2个试件的耐火极限以及各个测点的温度变化、侧向挠度、轴向变形和破坏过程;用有限元软件ABAQUS对试件截面温度场进行了模拟分析,测点温度增量模拟结果与实测温度增量符合较好。研究表明:相同初始轴压比条件下,混凝土强度接近的再生粗骨料混凝土柱比普通混凝土柱升温速度慢,具有相对较好的隔热性能;再生粗骨料混凝土柱比普通混凝土柱的抗爆裂性能好,耐火极限长;因再生粗骨料混凝土柱比普通混凝土柱的孔隙率相对较高,在高温作用下其内部蒸汽应力可得到一定释放,由此引起的柱子轴向压缩变形相应也较大;一定条件下的再生粗骨料混凝土柱可用于建筑工程。 相似文献
165.
166.
D. Thushari N. Wijesinghe Kithsiri B. Dassanayake Peter Scales Deli Chen 《Journal of environmental science and health. Part. B》2013,48(11):751-760
ABSTRACTDevelopment of digesters with an external zeolite column facilitates the convenient removal of the zeolite with TAN, without disturbing the continuous anaerobic digestion process. A digester with an inside zeolite bed (In-Zeo) and digester without adding zeolite (No-Zeo) were employed to compare the process performance with digester with external zeolite column (EX-Zeo). The cumulative, CH4 yields were 5% and 15% greater in the EX-Zeo, and the In-Zeo digesters respectively compared to the No-Zeo digesters. Also, the % VS reduction was 49%, 55% and 41%, respectively in the Ex-Zeo, In-Zeo and No-Zeo digesters. The results indicated that treatment with 7% zeolite during anaerobic digestion has the potential to improve biodegradation of swine manure. The addition of zeolite appeared to reduce TAN from the digestate, thereby enhancing the CH4 yield. Zeolite could be used either internally or externally to enhance CH4 production through anaerobic digestion of swine manure. 相似文献
167.
研究了用高效毛细管电泳对自来水水样中常见金属离子的快速测定方法。结果表明,K+、Na+、Li+、Ca2+、Mg2+、Ba2+、Sr2+7种离子在8 min内可全部分离,回收率为98.0%~103.3%。峰面积和迁移时间的相对标准偏差分别在3.2%和1.1%以下,重现性较好,具有较高的检测灵敏度。 相似文献
168.
某装药弹振动特性的安全分析 总被引:1,自引:0,他引:1
为分析某装药弹的振动特性,并为该弹提供必要的力学数据,建立某装药弹模态方程。采用ANSYS软件对该弹振动特性进行了数值模拟,利用Block Lanczos法求解,得到前10阶振动固有频率和振型。分析结果表明:低阶频率主要以摆动和转动为主,高阶频率主要以弯曲扭动为主,低阶频率对该弹的影响比较小,高阶频率对该弹的影响比较大,尤其是7~10阶频率,该弹的主振频率为1053.8 Hz,为该弹的优化设计提供科学依据,在加工、储存、运输和使用条件下应低于该频率;为验证该方法可信度,采用某小型装药弹进行了实验验证,实验结果和仿真结果偏差小于1%;同时证明该有限元数值分析的方法是经济可靠的。 相似文献
169.
华北型煤矿开采受底板岩溶强含水层威胁,通过对淮南张集矿1613A工作面底板隐伏岩溶陷落柱突水危险性分析,采用FLAC3D方法模拟采动条件下岩溶陷落柱活化过程。模拟结果显示:陷落柱上方的煤层底板岩体发生塑性变形,导致陷落柱附近岩体失稳,陷落柱筒壁产生局部剪切破坏,剪切破坏位置易导致奥灰强含水层发生陷落柱突水。采前采用注浆方法改造岩溶陷落柱,对改造后的陷落柱进行数值模拟分析,其内部注浆岩体对陷落柱筒壁具有良好的支撑作用,抑制了筒壁位置剪切破坏的发生,使有效隔水层厚度增大,降低了陷落柱突水的危险性。 相似文献
170.
采用HP-INNOWAX毛细管柱、气相色谱氢火焰离子化检测器测定工业废气和废水中的N,N-二甲基甲酰胺,可能共存的丙酮、乙醇和乙酰丙酮均对测试无干扰.方法在0.939 mg/L~75.1 mg/L范围内线性良好,对工业废水、无组织排放工业废气和有组织排放工业废气中N,N-二甲基甲酰胺的检出限分别为0.47 mg/L、0.16 mg/m3和0.31 mg/m3,标准溶液平行测定的RSD为1.9% ~2.2%,废水样品加标回收率为94%~ 97%. 相似文献