基于数据挖掘的化工生产事故致因主题抽取

为充分挖掘化工生产事故数据中的有效信息和潜在规律,提高对化工事故认知水平,针对某化工集团2010—2016年共1 578起事故数据,利用社会网络分析等方法揭示事故要素间的关联关系;运用潜在狄利克雷分配（LDA）模型进行事故聚类,并抽取到5个事故致因主题。研究结果表明:LDA主题模型等数据挖掘技术能有效挖掘大量事故数据中的潜在信息;5个事故致因主题中,4个涉及到人因或组织层面的缺陷;员工注意力不集中和现场风险管理不足这2个致因主题间具有较强相关性;员工注意力不集中、现场风险管理不足以及设备问题是导致事故发生的主要原因。     

全国重点城市工业废水污染物排放总量分配研究

总量控制是目前我国遏制污染趋势,改善环境质量,实现经济持续发展的重要手段,其核心内容是污染物排放总量的合理分配。文章依据基尼系数的基本概念,构建了重点城市污染物总量分配的基尼系数法,评价各市污染物总量分配的合理性公平性,比较全国重点城市污染物排放的差距,为总量分配的调整提供依据,为衡量经济的可持续发展提供参考。研究结果表明:工业废水污染物COD和氨氮在全国46个重点城市的排放差距较大,城市环境保护发展不均衡是造成基尼系数逐渐变大的主要原因,工业废水的污染治理需进一步推进。     

Assigning results of the Tool for Sustainability Impact Assessment (ToSIA) to products of a forest-wood-chain

A Tool for Sustainability Impact Assessment (ToSIA) has been developed for assessing sustainability impacts of forest-wood-chains (FWCs). Sustainability is determined by analysing environmental, economic, and social sustainability indicators for all the production processes along the FWC. Results of the tool can be analysed at an aggregated level for complete FWCs, but for some applications it is useful to assign the indicator results to products of the chain.This paper presents a procedure in ToSIA to assign sustainability impacts to multiple output products of FWC. The procedure was tested and demonstrated with an example FWC from Scandinavia that included furniture and bio-energy production. Two different allocation criteria, carbon-based and economic value-based, were applied with different options for assigning the impacts on the sub-products of the chain. Three indicators representing the three pillars of the sustainability were chosen to demonstrate the procedure: production costs (economic), employment (social) and transport intensity (environmental).The results indicated that the allocation criteria greatly affect the indicator results assigned to the different products of FWCs. The selection of the allocation criterion depends on the question approached and on the availability of the needed process related data. The data availability is assured for the carbon-based allocation within ToSIA, as following the carbon flows within the chain is mandatory for any ToSIA application. Economic values of products, on the other hand, are more closely linked to the aims of the production processes of the value chains and are thereby meaningful allocation criteria in many cases. The allocation procedure of ToSIA was proved to be flexible allowing different criteria and still consistent in allocation of the various sustainability impacts of the FWCs.     

Safety investment optimization in process industry: A risk-based approach

Process plant safety is a critical indicator of organizational performance. Adequate investment into safety practices to avoid future accident cost is therefore a beneficial strategy. The current approach to such investments in the process industry is driven largely by simple risk-based heuristics, insurance market premiums, organizational culture and management judgment. There is, however, an absence of an overarching methodology to assist such an effort. Therefore, there is a need for developing a robust decision-making framework for enabling systematic and optimal allocation of financial resources across all significant risk elements within a process plant.The present work proposes a safety investment optimization (SIO) framework for a typical process plant. Such an optimization approach targets maximal reduction of risk values across all potential hazards within the constraint of a given safety investment budget at the incipient stage of establishing a plant such that it saves future cost to company by reducing the risk from accidents. At the same time the framework takes into account the need to comply with the regulatory requirements imposed by the government. Additionally, access to insurance market as a strategy to transfer risk is also integrated. Finally, the residual risks are managed through investments in selective safeguards while ensuring that the benefits over-weigh the cost of such an exercise. For illustrating the application of the framework, a representative process plant with a select number of risk scenarios is chosen and all steps suggested by the framework are demonstrated quantitatively. It is anticipated that the proposed SIO framework will help optimal resource allocation for managing the risks implicit in a typical process plant.     

Influence of allocation methods on the environmental performance of biorefinery products—A case study

Life Cycle Assessment (LCA) methodology is the prevailing framework for estimating the environmental performances of a product/service. The application of LCA frequently requires practitioners to address allocation issues, especially when a large number of co-products are produced. The choice of an allocation approach for multifunctional processes is among the most debated methodological aspects in the LCA community, given its potentially large influence on final outcomes. Despite numerous efforts, a uniform consensus on the best allocation practice is still lacking and no single method appears as the most suitable for all situations.The aim of this paper is to assess how different allocation methods affect the environmental performances of a lignocellulosic biorefinery. Biorefinery systems represent a good example of a multifunctional process, since they co-produce multiple energy and material products. The following allocation procedures are applied: system expansion (also named substitution method), partitioning method according to different features of co-products (mass, energy, exergy and economic value), and hybrid approach (given by a combination of the previous ones). In order to enhance the clarity of the discussion, a mathematical notation for these allocation procedures is adopted, and analytical interrelations are investigated. Results show the influence of the allocation methods on the environmental impacts assigned to the individual products, both on a unit and annual flow basis.     

河口人工湿地植物配置与景观建设维护研究——以沈阳市辉山明渠河口湿地为例

以沈阳市辉山明渠入浑河河口湿地为研究对象,通过植物适应性分析、湿地植物选择、湿地植物优化配置、景观合理性配置等综合调控措施,使辉山明渠入浑河水质得到有效改善、湿地生物多样性得到恢复、人工湿地生态系统稳定性增强、形成独具特色的河口湿地景观。     

环境空气质量改善导向的财政资金分配模型与实施机制

"十三五"时期改进环境空气质量是首要任务,如何充分发挥财政资金对地方环境质量改善的引导和激励功能。文章提出了基于环境空气质量导向的财政激励资金分配模型和实施机制,并以2014~2015年的城市PM监测数据2.5进行了案例分析,结果表明该分配模型和实施机制具有科学性和可操作性,可以为建立环境空气质量导向的财政机制提供管理技术支撑。     

MTBE Transport Screening Analysis in Vadose Zone Risk and Liability Apportionment Assessment

The problem of allocating liability cleanup costs is an arduous task when more than one potentially responsible party has contributed to the groundwater plume. This problem is most likely to be encountered when dealing with methyl- tert -butyl-ether (MTBE) contamination, as MTBE is seen to travel large distances in underlying aquifers. There has been a signi®cant effort in the recent past to develop liability allocation methodologies that incorporate fate and transport behavior and toxicological characteristics of the contaminants. The application of such methods often requires estimation of contaminant input from the vadose zone into the underlying aquifer. A screening level analysis is presented here to develop preliminary insights on relative mass contributions arising from different source types. The analysis illustrates how different vadose zone conceptualizations lead to vastly different contaminant loadings. Parametric studies indicate that the contaminant flux into the aquifer is very sensitive to changes in water infiltration rates. Hence, a reliable estimate of this parameter is critical for equitable allocation of remedial costs. Conceptual model formulation, should focus on identifying whether the fuel present in the aquifer can flow as a separate phase. It is also important to obtain reliable estimates for fluid saturations at the site.     

Design of Mass Exchange Network and Effluent Distribution System for effective water management

The environmental impact of industrial wastewater and higher cost of fresh water are the serious challenges faced by the process industries. It has led to the development of many new techniques to minimize fresh water consumption. Of the many approaches, which have been developed, the Water Source Diagram (WSD) is a flexible and dynamic alternative for the generation of different scenarios for the management of water networks with reduction in total consumption. In the present study WSD concept was coupled with water mains concept to mains simplify the piping network and reduce the cost. A new procedure was developed for integrating the effluent treatment processes to evolve Effluent Treatment Network. Example from literature having multi contaminants was considered. This simple procedure involving hand calculations will be a useful tool for process engineers to design water and effluent treatment networks. Also the WSD and ETN were combined to form an evolutionary WAMEN (Water Allocation and Mass Exchange Network) and the proposed WAMEN aims for minimum fresh water consumption.