富硅肥料和水分管理对稻米镉污染阻控效果研究

在已筛选出的施硅方式(基施和叶面喷施相结合)基础上,选择典型单一镉污染稻田土壤(pH=4.97,总Cd 4.1 mg·kg~(-1)),并结合2种稻田水分管理方式,进一步开展不同水肥管理方式对常规早稻(湘早籼45)和杂交晚稻(丰源优299)的3个生育期内各部位中Cd含量及成熟期生物量的影响研究.实验设计4个处理:不施硅肥+常规间歇淹水措施(CK)、不施硅肥+全生育期淹水措施(W)、2种硅肥配施+常规间歇淹水措施(SiLsi)、2种硅肥配施+全生育期淹水措施(SiLsi+W).结果表明,4个处理下,早晚稻试验结果基本一致,但各试验处理对晚稻的阻镉效果更加明显;与CK相比,各处理都能显著降低水稻籽粒中Cd的含量且不会明显影响水稻产量,其中以SiLsi+W对籽粒的降Cd效果最佳(晚稻精米中Cd的含量为0.12 mg·kg~(-1),达到了国家粮食安全生产标准:Cd0.2 mg·kg~(-1)),分别使晚稻谷壳、糙米和精米的降Cd幅度达到93.65%、86.70%和91.18%,W和Si Lsi处理的降Cd效果次之.因此,SiLsi+W可作为一种有效的稻米镉污染控制技术.     

含腐蚀缺陷的X80高钢级管道失效评估研究

综合对比分析了ASME B31G、RSTRENG、DNV RP-F101等6种含腐蚀缺陷管道剩余强度的评估方法。将各方法应用到含腐蚀缺陷的X80高钢级管道进行失效压力预测,并将计算结果与全尺寸爆破实验结果进行对比,研究不同评估方法评估结果的准确性,以及管壁厚度、缺陷深度比和流动应力取值对评估结果的影响。研究结果表明,DNV RP-F101、PCORRC和LPC-1这3种方法更适用于含腐蚀缺陷的X80高钢级管道的失效评估。     

电化学方法检测海水中铁的研究进展

海水中的痕量铁作为限制海洋浮游植物初级生产力的关键因素之一,在海洋生物地球化学循环中起着重要的作用.及时分析海水中铁的不同存在形态及其含量,对于进一步认识铁循环机制和有效预防海洋环境污染具有重要意义.电化学方法较其他分析方法在检测海水中痕量铁的含量,尤其是形态分析方面具有独特的优势.本文总结了运用电化学方法检测海水及其他自然水体中铁的分析方法,以期为发展准确、快速测定海水中痕量铁的形态及其含量的分析技术提供基础性参考.     

The evaluation of an analytical protocol for the determination of substances in waste for hazard classification

The classification of waste as hazardous could soon be assessed in Europe using largely the hazard properties of its constituents, according to the the Classification, Labelling and Packaging (CLP) regulation. Comprehensive knowledge of the component constituents of a given waste will therefore be necessary. An analytical protocol for determining waste composition is proposed, which includes using inductively coupled plasma (ICP) screening methods to identify major elements and gas chromatography/mass spectrometry (GC–MS) screening techniques to measure organic compounds. The method includes a gross or indicator measure of ‘pools’ of higher molecular weight organic substances that are taken to be less bioactive and less hazardous, and of unresolved ‘mass’ during the chromatography of volatile and semi-volatile compounds. The concentration of some elements and specific compounds that are linked to specific hazard properties and are subject to specific regulation (examples include: heavy metals, chromium(VI), cyanides, organo-halogens, and PCBs) are determined by classical quantitative analysis. To check the consistency of the analysis, the sum of the concentrations (including unresolved ‘pools’) should give a mass balance between 90% and 110%. Thirty-two laboratory samples comprising different industrial wastes (liquids and solids) were tested by two routine service laboratories, to give circa 7000 parameter results. Despite discrepancies in some parameters, a satisfactory sum of estimated or measured concentrations (analytical balance) of 90% was reached for 20 samples (63% of the overall total) during this first test exercise, with identified reasons for most of the unsatisfactory results. Regular use of this protocol (which is now included in the French legislation) has enabled service laboratories to reach a 90% mass balance for nearly all the solid samples tested, and most of liquid samples (difficulties were caused in some samples from polymers in solution and vegetable oil). The protocol is submitted to French and European normalization bodies (AFNOR and CEN) and further improvements are awaited.     

Critical Review of Environmental Forensic Techniques: Part I

A multitude of forensic techniques are available for age dating and source identification, including aerial photography interpretation, corrosion models, the commercial availability of a compound, chemical associations with discrete type processes, chemical profiling, degradation models and contaminant transport models. These techniques, however, are rarely challenged or discussed in the literature relative to the scrutiny encountered in environmental litigation. When introduced as scientific evidence, the governing assumptions and quality of the data are critically evaluated and frequently successfully challenged. The purpose of this paper is to review five types of forensic techniques and discuss their merits so that a user can decide which technique, or combination of techniques, is most appropriate for developing the technical portion of a case.     

Evaluation of the interaction between soil and antibiotics

The aim of this study was to investigate the occurrence of tetracycline and sulfonamide antibiotics in 13 different soil samples collected from agricultural fields. As well as the antibiotic analysis 18 different physicochemical properties of the soil samples were determined in order to establish a relationship between the recovery rates of antibiotics from the samples and the characteristics of the samples that provide critical information for the reliability of an applied antibiotic analysis method. While the concentrations of tetracyclines were 0.025–0.105 mg kg^?1 sulfonamide antibiotics were not detected in any investigated soil samples. The mean recovery rates of tetracyclines and sulfonamides were 84.57 ± 14.92% and 65.88 ± 8.56%, respectively. Although, the organic carbon contents and cation exchange capacities of the soil samples exhibited a great variation the results of multivariate statistical analysis indicated that the metal content of soils was the major factor significantly influenced the recovery rates of the antibiotics. The sulfonamide recovery rates were positively influenced by the calcium and magnesium amounts in the soil samples, whereas tetracycline recovery rates were markedly diminished by increasing the amount of these polyvalent metals.     

基于国际河流开发的国家水质标准差异对比分析

就国际河流相邻国家用水特点,分析我国与俄罗斯在地表水用于生活饮用水和农田灌溉水2个方面的水质标准进行对比分析,具体分析这2个标准在两国之间的总体差异和具体指标差异。分析的总体结论是俄罗斯的水质标准在项目分类、具体评价指标方面比我国丰富,具体指标的限值要稍严于我国标准。针对两国水质标准的不同,分析在国际河流开发利用中可能导致的冲突及这种差异对我国的影响,并从社会经济发展需求、水资源开发及相关政策关注重点等方面揭示两国水质标准存在差异的原因,为有效解决由于水质标准差异导致的争端提供科学依据。     

Evaluating water quality investments using cost utility analysis

This study borrows concepts from healthcare economics and uses cost utility analysis (CUA) to select an optimum portfolio of water quality enhancement projects in Perth, Western Australia. In CUA, costs are handled via standard discounted cash flow analysis, but the benefits, being intangible, are measured with a utility score. Our novel methodology combines CUA with a binary combinatorial optimisation solver, known as a 'knapsack algorithm', to identify the optimum portfolio of projects. We show how water quality projects can be selected to maximise an aggregate utility score while not exceeding a budget constraint. Our CUA model applies compromise programming (CP) to measure utility over multiple attributes in different units. CUA is shown to provide a transparent and analytically robust method to maximise benefits from water quality remediation investments under a constrained budget.     

试论以物质流分析方法为基础建立我国循环经济指标体系

为了更好地推动我国循环经济建设的发展。本文介绍了当前国际上用来分析资源问题的物质流分析（MFA．Material Flow Analysis）方法：描述了日本以MFA方法表述国家资源投入、废弃物产生和废弃物再生利用．并在此基础上提出国家循环经济社会发展目标的经验：指出MFA方法将是我国分析评价社会经济活动中资源使用状况的重要方法；并以此为依据．结合我国国情进一步提出我国的循环经济指标体系应包括的主要指标。这些指标将为我国制定循环经济发展目标、推进循环经济发展提供理论依据。也会成为循环经济社会建设中我国与国际比较，找出差距，调整战略的重要技术指标。     

Research on Indicator System of Regional Eco-efficiency:A Case Study of Chengyang District

Eco-efficiency is a valuable tool for managing and solving issues involving resource consumption and pollution emission in current production processes. Despite the popularity of the term “eeo-efficiency“ in business, limited attention has been paid to measuring and reporting regional eco-efficiency for local government policy makers. Based on the concept and method of eco-efficiency, an indicator system of regional eco-efficiency is established in this study. The indicator system comprises 22 indicators, which are divided in to three categories including socio-economic development, resources consumption,environmental pressure. As a promising statistical technique,principle component analysis is used to set the weight of indicators which attempts to calculate the eco-efficiency indices of Qingdao‘s Chengyang District. The results show that the eco-efficiency of Chengyang District has clearly improved 35.1% with small fluctuation from 1995 to 2003. Socio-economic development index and resources consumption index also represent obvious increasing trends. The correlation coefficient between soci-economic development index and resources consumption index is 0.979, which means the social progress and economic growth of Chengyang District depend on an extravagant consumption of resources. The environmental pressure index increased slowly before 1997 and declined gradually after 1997, due to more attention being paid to environmental protection by local government in recent years. Chengyang District still keeps the traditional economic development mode with a high consumption and high production, so the emphases of future development should put on improving the improving the efficient use of natural resources and promoting environmental management sustainability. The results show that the indicators system of regional eco-efficiency is a promising method to quantitatively evaluate resources and environmental efficiency and provide an effective decision-making support for local governments.