Atmospheric NH3 as plant nutrient: a case study with Brassica oleracea

Nutrient-sufficient and nitrate- or sulfate-deprived plants of Brassica oleracea L. were exposed to 4 microl l(-1) NH3 (2.8 mg m(-3)), and effects on biomass production and allocation, N-compounds and root morphology investigated. Nitrate-deprived plants were able to transfer to atmospheric NH3 as nitrogen source, but biomass allocation in favor of the root was not changed by exposure to NH3. NH3 reduced the difference in total root length between nitrate-sufficient and nitrate-deprived plants, and increased the specific root length in the latter. The internal N status, therefore, might be involved in controlling root length in B. oleracea. Root surface area, volume and diameter were unaffected by both nitrate deprivation and NH3 exposure. In sulfate-deprived plants an inhibitory effect of NH3 on root morphological parameters was observed. These plants, therefore, might be more susceptible to atmospheric NH3 than nitrate-deprived plants. The relevance of the present data under field conditions is discussed.     

Secondary organic aerosols in Jinan, an urban site in North China: Significant anthropogenic contributions to heavy pollution

Secondary organic aerosols(SOAs) are an important component of particulates, but whether biogenic SOAs(BSOAs) or anthropogenic SOAs(ASOAs) are the dominant contributors to haze pollution remains poorly characterized. In this study, particulate samples were collected from September 2014 to August 2015 at an urban site in Jinan, which is the capital of Shandong Province and a typical city in the North China Plain. The PM2.5 samples were analyzed for BSOA(isoprene(SOAI) and monoterpenes(SOAM)) and ASOA(aromatic(SOAA)) tracers. The concentrations of the SOAAtracer(1.1 ± 1.0 ng/m3) were lowest, and those of SOAItracers(41.8 ± 86.2 ng/m3) were highest, with the concentrations of SOAMtracers(19.4 ± 9.9 ng/m3) being intermediate. The SOAItracers were more abundant in the summer and less abundant in the winter. Both SOAIand SOAMincreased with increasing ozone level but decreased with increasing NOx level. Correlation analysis revealed a good correlation between 2,3-dihydroxy-4-oxopentanoic acid and levoglucosan levels in three seasons. These results suggested that biomass burning activities occurring in the NCP can enhance the emissions of aromatics and should be controlled, especially in the autumn and winter. SOA tracers were classified according to pollution degree, and the results showed that as pollution increases, the contributions of SOAAincrease. These results indicate that reducing anthropogenic emissions is necessary to prevent SOA pollution, especially during heavy pollution episodes.     

Emission factors, ozone and secondary organic aerosol formation potential of volatile organic compounds emitted from industrial biomass boilers

To evaluate the potential benefits of biomass use for air pollution control, this paper identified and quantified the emissions of major reactive organic compounds anticipated from biomass-fired industrial boilers. Wood pellets(WP) and straw pellets(SP) were burned to determine the volatile organic compound emission profiles for each biomass-boiler combination. More than 100 types of volatile organic compounds(VOCs) were measured from the two biomass boilers. The measured VOC species included alkanes, alkenes and acetylenes, aromatics, halocarbons and carbonyls. A single coal-fired boiler(CB) was also studied to provide a basis for comparison. Biomass boiler 1(BB1) emitted relatively high proportions of alkanes(28.9%–38.1% by mass) and alkenes and acetylenes(23.4%–40.8%),while biomass boiler 2(BB2) emitted relatively high proportions of aromatics(27.9%–29.2%)and oxygenated VOCs(33.0%–44.8%). The total VOC(TVOC) emission factors from BB1(128.59–146.16 mg/kg) were higher than those from BB2(41.26–85.29 mg/kg). The total ozone formation potential(OFP) ranged from 6.26 to 81.75 mg/m~3 with an average of 33.66 mg/m~3 for the two biomass boilers. The total secondary organic aerosol potential(SOAP) ranged from 61.56 to 211.67 mg/m~3 with an average of 142.27 mg/m~3 for the two biomass boilers.The emission factors(EFs) of TVOCs from biomass boilers in this study were similar to those for industrial coal-fired boilers with the same thermal power. These data can supplement existing VOC emission factors for biomass combustion and thus enrich the VOC emission inventory.     

Urgently reveal longly hidden toxicant in a familiar fabrication process of biomass-derived environment carbon material

Biomass-derived N-doped carbon (BNC) is an important environmental material and widely used in the fields of water purification and soil remediation. However, the toxicant in the commonly used synthesis process of BNC materials have been largely ignored. Herein, we firstly report the presence of a highly toxic by-product (KCN) in the activation process of BNC materials consequential of the carbothermal reduction reaction. Because this carbothermal reduction reaction also regulates the N-doping and pore development of BNC materials, the KCN content directly relates with the properties of BNC material properties. Accordingly, a high KCN content (∽ 611 mg) can occur in the production process of per g BNC material with high specific surface area (∽ 3600 m²/g). Because the application performance of BNC material is determined by the surface area and available N doping, therefore, production of a BNC material with high performance entails high risk. Undoubtedly, this study proves a completely new risk recognition on a familiar synthesis process of biomass-based material. And, strict protective device should be taken in fabrication process of biomass-derived carbon material.     

Physicochemical characterization of forest and sugarcane leaf combustion's particulate matters using electron microscopy, EDS, XRD and TGA

Physical characteristics and quantitative elemental composition of PM and residual ash produced from sugarcane leaves (SCL) combustion were investigated using TEM-EDS compared with forest leaves (FRL). SEM-EDS was used to analyze the microstructure and chemical composition of biomass raw leaves and PM. XRD analysis was also performed to investigate the characterization of the crystalline nanostructure, structure of PM, and residual ash compared to the TEM image processing method. The oxidation kinetics of biomass raw materials, PM, and residual ash were investigated by TGA. The morphology of fine and ultrafine agglomerate structure of SCL soot and residual ash are not significantly different from the FRL soot and residual ash. The average diameter sizes of single primary nanoparticles of SCL and FRL soot are approximately 37 nm and 35 nm, while the sizes of residual ash are about 18 nm and 22 nm, respectively. The single primary nanoparticles of soot are mainly composed of curve line crystallites of carbon fringes, while residual ash is composed of straight-line lattice fringes. The average fringe lengths of SCL and FRL soot are about 1.25 nm and 1.04 nm from the outer shell and 0.89 nm and 0.74 nm from the inner core. The interlayer spacing of curve line carbon fringes of SCL and FRL soot is approximately 0.359 nm and 0.362 nm by the TEM image analysis and it was matched with XRD analysis. The biomass PMs are mainly composed of soot, Si, Ca, and K compounds: SiO₂, CaCO₃, and KCl.     

Least cost electricity generation options based on environmental impact abatement

The power sector in Thailand is the largest contributor to CO₂ emissions. There is high potential to mitigate CO₂ emission via alternative power generating plants. Alternative plants considered in this study include nuclear plants, integrated gasification combined cycle plants, biomass-based plants and supercritical thermal power plants. The biomass-based plants considered here are fueled with four types of biomass; paddy husk, municipal solid waste (MSW), fuel wood and corncob. The methodology for the optimal expansion plan of the power generating system over the planning horizon is based on the least-cost approach. The results from the least-cost planning analyses show that the nuclear alternative has the highest potential to mitigate not only CO₂ but also other airborne emissions. Moreover, the nuclear option is the most effective abatement strategy for CO₂ reduction due to its negative incremental cost of CO₂ reduction.     

循环流化床锅炉结渣特性研究

循环流化床燃烧技术是近年来在国际上发展起来的新一代高效、低污染清洁燃烧技术,生物质燃料是具有广阔发展前景的新型燃料。本文通过循环流化床锅炉中混燃时的结渣问题进行了分析研究,并对解决发电厂锅炉结渣问题给出了相应的技术措施。     

Effect of grazing on plant attributes and hydrological properties in the sloping lands of the East African highlands

Extending livestock grazing to the steep slopes has led to unstable grazing systems in the East African Highlands, and new solutions and approaches are needed to ameliorate the current situation. This work was aimed at studying the effect of livestock grazing on plant attributes and hydrological properties. The study was conducted from 1996 to 2000 at the International Livestock Research Institute at Debre Ziet Research Station. Two sites were selected: one at 0–4% slope, and the other at 4–8% slope. The treatments were: (1) no grazing (control); (2) light grazing, 0.6 animal unit months per hectare (aum/ha); (3) moderate grazing, 1.8 aum/ha; (4) heavy grazing, 3.0 aum/ha; (5) very heavy grazing, 4.2 aum/ha; (6) initially plowed and continuously very heavily grazed, 4.2 aum/ha. The result showed that species richness, infiltration rate, bare ground, and soil loss significantly varied with grazing pressure. Species richness was higher in grazed plots compared to nongrazed plots. Biomass yield improved on heavily grazed plots as cow dung accumulated over years. Cynodon dactylon plant species persisted with livestock grazing pressure in both sites. Infiltration rate improved and soil erosion declined in all treatments after the first year.     

Impact of Grazing on Plant Species Richness, Plant Biomass, Plant Attribute, and Soil Physical and Hydrological Properties of Vertisol in East African Highlands

Understanding the problems of grazing land in vertisol areas and seeking long-lasting solutions is the central point where mixed crop livestock is the second stay for the majority of the population. In order to understand this, the current study was conducted at two sites, one with 0–4% slope and the other with 4–8% slope at Ginchi watershed, 80 km west of Addis Ababa, Ethiopia. The specific objectives of the study were to quantify changes in plant species richness, biomass, plant cover, and soil physical and hydrological properties. The grazing regimes were: moderate grazing (regulated), heavy grazing (free grazing), and no grazing (closed to any grazing), which was considered the control treatment. The results showed that the biomass yield in nongrazed plots was higher than in the grazed plots. However, the biomass yield in grazed plots improved over the years. Species richness and percentage of dominant species attributes were better in medium grazed plots than the other treatments. Soil compaction was higher in very heavily grazed plots than in nongrazed and medium-grazed plots. In contrast to that, the soil water content and infiltration rate were better in nongrazed plots than in grazed plots. Soil loss in grazed plots decreased with the increase of biomass yields and as the soil was more compacted by livestock trampling during the wet season. Finally since the medium stocking rate is better in species richness and plant attributes, and lies between nongrazed and heavily grazed plots in the rest of the measured parameters, it could be the appropriate stocking rate to practice by the smallholder farmer.     

Recovery of biomass cellulose from waste sewage sludge

In our previous work, the primary sludge from wastewater treatment plants was shown to contain a considerable amount of cellulose (about 20%, based on suspended solids) owing to the discharge of toilet paper. For the purpose of using the cellulose as a biomass resource, this study examined a simple method for its recovery. When fibrous cellulose was suspended in 0.3% sulfuric acid and autoclaved at 130°C for 60 min, 85%–88% of the initial solids remained without dissolving. Under these conditions, an activated sludge sample not containing cellulose was strongly hydrolyzed and only 7% of the initial solids remained. The prescribed amounts of cellulose added to the activated sludge sample were quantitatively recovered by the autoclaving treatment. In the treatment of primary sludge containing >20% cellulose, residual solids with relatively high levels of cellulose (>69%) could be obtained. The results indicate that the method proposed here could recover cellulose practically from waste sewage sludge for biomass utilization. Received: July 17, 2000 / Accepted: July 4, 2001