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71.
Identification of relevant micropollutants in Austrian municipal wastewater and their behaviour during wastewater treatment 总被引:1,自引:0,他引:1
Clara M Windhofer G Weilgony P Gans O Denner M Chovanec A Zessner M 《Chemosphere》2012,87(11):1265-1272
The European Union has defined environmental quality standards (EQSs) for surface waters for priority substances and several other pollutants. Furthermore national EQSs for several chemicals are valid in Austria. The study investigated the occurrence of these compounds in municipal wastewater treatment plant (WWTP) effluents. In a first screening of 15 WWTPs relevant substances were identified, which subsequently were monitored in 9 WWTPs over 1 year (every 2 months). Out of 77 substances or groups of substances (including more than 90 substances) 13 were identified as potentially relevant in respect to water pollution and subjected to the monitoring, whereas most other compounds were detected in concentrations far below the respective EQS for surface waters and therefore not further considered. The preselected 13 compounds for monitoring were cadmium (Cd), nickel (Ni), copper (Cu), selenium (Se), zinc (Zn), diuron, polybrominated diphenyl ethers (PBDEs), di(ethyl-hydroxyl)phthalate (DEHP), tributyltin compounds (TBT), nonylphenoles (NP), adsorbable organic halogens (AOX) and the complexing agents ethylenediaminetetraacetic acid (EDTA) as well as nitrilotriacetic acid (NTA). In the effluents of WWTPs the concentrations of the priority substances Cd, NP, TBT and diuron frequently exceeded the respective EQS, whereas the concentrations for DEHP and Ni were below the respective EQS. The effluent concentrations for AOX, EDTA, NTA, Cu, Se and Zn frequently are in the range or above the Austrian EQS for surface waters. Besides diuron and EDTA all compounds are removed at least partially during wastewater treatment and for most substances the removal via the excess sludge is the major removal pathway. For the 13 compounds which were monitored in WWTP effluents population equivalent specific discharges were calculated. Since for many compounds no or only few information is available, these population equivalent specific discharges can be used to assess emissions from municipal WWTPs to surface waters as well as to make a first assessment of the impact of a discharge on surface waters chemical status. Comparing discharges and river pollution on a load basis, the influence of diffuse sources becomes obvious and therefore should also be taken into consideration in river management. 相似文献
72.
Abstract: The potential of remotely sensed time series of biophysical states of landscape to characterize soil moisture condition antecedent to radar estimates of precipitation is assessed in a statistical prediction model of streamflow in a 1,420 km2 watershed in south‐central Texas, Moderate Resolution Imaging Spectroradiometer (MODIS) time series biophysical products offer significant opportunities to characterize and quantify hydrologic state variables such as land surface temperature (LST) and vegetation state and status. Together with Next Generation Weather Radar (NEXRAD) precipitation estimates for the period 2002 through 2005, 16 raw and deseasoned time series of LST (day and night), vegetation indices, infrared reflectances, and water stress indices were linearly regressed against observed watershed streamflow on an eight‐day aggregated time period. Time offsets of 0 (synchronous with streamflow event), 8, and 16 days (leading streamflow event) were assessed for each of the 16 parameters to evaluate antecedent effects. The model results indicated a reasonable correlation (r2 = 0.67) when precipitation, daytime LST advanced 16 days, and a deseasoned moisture stress index were regressed against log‐transformed streamflow. The estimation model was applied to a validation period from January 2006 through March 2007, a period of 12 months of regional drought and base‐flow conditions followed by three months of above normal rainfall and a flood event. The model resulted in a Nash‐Sutcliffe estimation efficiency (E) of 0.45 for flow series (in log‐space) for the full 15‐month period, ?0.03 for the 2006 drought condition period, and 0.87 for the 2007 wet condition period. The overall model had a relative volume error of ?32%. The contribution of parameter uncertainties to model discrepancy was evaluated. 相似文献
73.
周崴 《环境监测管理与技术》2013,25(4):13-17
通过对2011年常州地区各类植物VOC排放因子,以及各类植被分布面积等数据统计分析,采用BEIS模型为参考的估算方法,建立起常州地区植被VOC的排放清单。结果表明,植被所排放VOC的变化规律既与植物本身有关又与气温和太阳辐射有关,区域内年植被VOC的总排放量为1.13×104 t。 相似文献
74.
Katerina Zemankova Josef Brechler 《Environmental pollution (Barking, Essex : 1987)》2010,158(2):462-469
This paper describes a method of estimating emission fluxes of biogenic volatile organic compounds (BVOCs) based on the approach proposed by Guenther et al. (1995) and the high-resolution Corine land-cover 2000 database (1 × 1 km resolution). The computed emission fluxes for the Czech Republic (selected for analysis as being representative of a heavily cultivated, central European country) are compared with anthropogenic emissions, both for the entire country and for individual administrative regions. In some regions, BVOC emissions are as high as anthropogenic emissions; however, in most regions the BVOC emissions are approximately 50% of the anthropogenic emissions. The yearly course of BVOC emissions (represented by monoterpenes and isoprene) is presented, along with the spatial distribution of annual mean values. Differences in emission distributions during winter (January) and summer (June) are also considered. 相似文献
75.
Long-range atmospheric transport of three toxaphene congeners across Europe. Modeling by chained single-box FATEMOD program 总被引:1,自引:1,他引:0
Jaakko Paasivirta Seija Sinkkonen Vladimir Nikiforov Fedor Kryuchkov Erkki Kolehmainen Katri Laihia Arto Valkonen Manu Lahtinen 《Environmental science and pollution research international》2009,16(2):191-205
Background, aims, and scope Since toxaphene (polychlorocamphene, polychloropinene, or strobane) mixtures were applied for massive insecticide use in the
1960s to replace the use of DDT, some of their congeners have been found at high latitudes far away from the usage areas.
Especially polychlorinated bornanes have demonstrated dominating congeners transported by air up to the Arctic areas. Environmental
fate modeling has been applied to monitor this phenomenon using parallel zones of atmosphere around the globe as interconnected
environments. These zones, shown in many meteorological maps, however, may not be the best way to configure atmospheric transport
in air trajectories. The latter could also be covered by connecting a chain of simple model boxes. We aim to study this alternative
approach by modeling the trajectory chain using catchment boxes of our FATEMOD model. Polychlorobornanes analyzed in biota
of the Barents Sea offered one case to study this modeling alternative, while toxaphene has been and partly still is used
massively at southern East Europe and around rivers flowing to the Aral Sea.
Materials and methods Pure model substances of three polychlorobornanes (toxaphene congeners P26, P50, and P62) were synthesized, their environmentally
important thermal properties measured by differential scanning calorimetry, as evaluated from literature data, and their temperature
dependences estimated by the QSPR programs VPLEST, WATSOLU, and TDLKOW. The evaluated property parameters were used to model
their atmospheric long-range transport from toxaphene heavy usage areas in Ukraine and Aral/SyrDarja/AmuDarja region areas,
through East Europe and Northern Norway (Finnmarken) to the Barents Sea. The time period used for the emission model was June
1997. Usual weather conditions in June were applied in the model, which was constructed by chaining FATEMOD model boxes of
the catchment’s areas along assumed maximal air flow trajectories. Analysis of the three chlorobornanes in toxaphene mixtures
function as a basis for the estimates of emission levels caused by its usage. High estimate (A) was taken from contents in
a Western product chlorocamphene and low estimate (B) from mean contents in Russian polychloroterpene products to achieve
modeled water concentrations. Bioaccumulation to analyzed lipid of aquatic biota at the target region was estimated by using
statistical calculation for persistent organic pollutants in literature.
Results The results from model runs A and B (high and low emission estimate) for levels in sea biota were compared to analysis results
of samples taken in August 1997 at Barents Sea. The model results (ng g−1 lw): 4–95 in lipid of planktovores and 7–150 in lipid of piscivores, were in fair agreement with the analysis results from
August 1997: 21–31 in Themisto libellula (chatka), 26–42 in Boreocadus saida (Polar cod), and 5–27 in Gadus morhua (cod) liver.
Discussion The modeling results indicate that the application of chained simple multimedia catchment boxes on predicted trajectory is
a useful method for estimation of volatile airborne persistent chemical exposures to biota in remote areas. For hazard assessment
of these pollutants, their properties, especially temperature dependences, must be estimated by a reasonable accuracy. That
can be achieved by using measurements in laboratory with pure model compounds and estimation of properties by thermodynamic
QSPR methods. The property parameters can be validated by comparing their values at an environmental temperature range with
measured or QSPR-estimated values derived by independent methods. The chained box method used for long-range air transport
modeling can be more suitable than global parallel zones modeling used earlier, provided that the main airflow trajectories
and properties of transported pollutants are predictable enough.
Conclusions Long-range air transport modeling of persistent, especially photo-resistant organic compounds using a chain of joint simple
boxes of catchment’s environments is a feasible method to predict concentrations of pollutants at the target area. This is
justified from model results compared with analytical measurements in Barents Sea biota in August 1997: three of six modeled
values were high and the other three low compared to the analysis results. The order of magnitude level was similar in both
modeled (planktovore and piscivore) and observed (chatka and polar cod) values of lipid samples. The obtained results were
too limited to firm validation but are sufficient to justify feasibility of the method, which prompts one to perform more
studies on this modeling system.
Recommendations and perspectives For assessment of the risk of environmental damages, chemical fate determination is an essential tool for chemical control,
e.g., for EU following the REACH rules. The present conclusion of applicability of the chained single-box multimedia modeling
can be validated by further studies using analyses of emissions and target biota in various other cases. To achieve useful
results, fate models built with databases having automatic steps for most calculations and outputs accessible to all chemical
control professionals are essential. Our FATEMOD program catchments at environments and compound properties listed in the
database represent a feasible tool for local, regional, and, according our present test results, for global exposure predictions.
As an extended use of model, emission estimates can be achieved by reversed modeling from analysis results of samples corresponding
to the target area.
This article is dedicated to the memory of Professor Alexander B Terentiev (who passed away in November 2006), our true friend.
With his Institute of Organo-Element Compounds, Russian Academy of Science, Moscow, he was an important main organizer of
the six joint Finnish–Russian seminars (every third year since 1989) on the field (‘Chemistry and Ecology of Organo-Element
Compounds’). He prompted us especially to search properties and environmental fates for various polyhalogen compounds. We
remember him for his friendly character and great sense of humor. 相似文献
76.
ABSTRACT: A climate factor, CT, (T = 2–, 25-, and 100-year recurrence intervals) that delineates regional trends in small-basin flood frequency was derived using data from 71 long-term rainfall record sites. Values of CT at these sites were developed by a regression analysis that related rainfall-runoff model estimates of T-year floods to a sample set of 50 model calibrations. CT was regionalized via kriging to develop maps depicting its geographic variation for a large part of the United States east of the 105th meridian. Kriged estimates of CT and basin-runoff characteristics were used to compute regionalized T-year floods for 200 small drainage basins. Observed T-year flood estimates also were developed for these sites. Regionalized floods are shown to account for a large percentage of the variability in observed flood estimates with coefficients of determination ranging from 0.89 for 2-year floods to 0.82 for 100-year floods. The relative importance of the factors comprising regionalized flood estimates is evaluated in terms of scale (size of drainage area), basin-runoff characteristics (rainfall. runoff model parameters), and climate (CT). 相似文献
77.
ABSTRACT: A procedure of estimating instantaneous flood flows for various return periods on the Island of Newfoundland is presented. The procedure is based on annual maximum instantaneous flows rather than annual maximum daily-mean flows, as the latter requires the conversion of estimated daily-mean flows into instantaneous flows. Regression equations were developed for each of three homogeneous regions for the desired return periods. The flood flow estimation capability of the presented procedure is demonstrated to be better than any other currently available procedure on the Island. 相似文献
78.
Jiri Marsalek 《Journal of the American Water Resources Association》1991,27(2):283-291
ABSTRACT: A review of methods for planning-level estimates of pollutant loads in urban stormwater focuses on transfer of charac. teristic runoff quality data to unmonitored sites, runoff monitoring, and simulation models. Load estimation by transfer of runoff quality data is the least expensive, but the accuracy of estimates is unknown. Runoff monitoring methods provide best estimates of existing loads, but cannot be used to predict load changes resulting from runoff controls, or other changes of the urban system. Simulation models require extensive calibration for reliable application. Models with optional formulations of pollutant build up, washoff, and transport can be better calibrated and the selection of options should be based on a statistical analysis of calibration data. Calibrated simulation models can be used for evaluation of control alternatives. 相似文献
79.
Peter K. Kitanidis 《Journal of the American Water Resources Association》1987,23(4):557-567
ABSTRACT: The usefulness of stochastic models in describing the spatial variability of hydrogeologic quantities, such as permeability, storativity, piezometric head, seepage velocity, and solute concentrations is now widely recognized. In practice, these quantities are represented as the sum of a well-structured component, or drift, and a more erratic fluctuation component which is described statistically through its covariance function. This paper reviews some of the most recent and most promising methods for the estimation of parameters of these covariances from existing data. They are maximum likelihood, restricted maximum likelihood, minimum-variance unbiased quadratic estimation, and minimum-norm (weighted least squares) estimation. The applicability of such methods to conditional and unconditional probability problems is discussed. 相似文献
80.
Stephen E. Draper Srinivas G. Rao 《Journal of the American Water Resources Association》1986,22(6):941-949
ABSTRACT: Percent imperviousness is an important parameter in modeling the urban rainfall-runoff process and is usually determined using manual methods such as random sampling or conventional accounting methods. In this study two computerized methods are used for estimating the percent imperviousness of urban watersheds using high altitude remote sensing imagery. These methods include the Laser Image Processing Scanner and the Video-Tape Camera system. Imperviousness is directly estimated in the former method while in the latter it is estimated as a function of the statistics of the responses on emulsions of the imagery. The percent imperviousness computed by utilizing remote sensing imagery was used with the conceptual models of rainfall-runoff models. The models were applied to four urban watersheds and the runoff prediction results indicate that imperviousness determined by using remote sensing imagery was as accurate as that obtained by the manual methods, and that the use of remote sensing imagery requires significantly less time and money. 相似文献