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61.
北京市某高层建筑高空电磁辐射环境影响分析 总被引:1,自引:0,他引:1
王璟 《环境监测管理与技术》2014,26(1):61-65
选取北京市某代表性高层居民楼顶平台作为高空电磁辐射环境水平监测点进行综合场强和选频监测,评价总体电磁辐射环境水平,并分析监测区域电磁辐射能量的来源。结果表明:该高空监测区域的电磁辐射环境总体水平低于国家规定的公众照射导出限值,但高于地面水平。监测区域主要受30 km 外的中波台影响,其次是9 km 外的中央电视塔。影响最大的是639 kHz频率的中波信号,占100 kHz~300 MHz总场强的95%以上,其次是1.28 MHz频率的中波信号。提出,开展敏感建筑物规划建设时,应考虑中波的传播特性和对环境的影响。 相似文献
62.
Based on the China high resolution emission gridded data (1 km spatial resolution), this article is aimed to create a Chinese city carbon dioxide (CO2) emission data set using consolidated data sources as well as normalized and standardized data processing methods. Standard methods were used to calculate city CO2 emissions, including scope 1 and scope 2. Cities with higher CO2 emissions are mostly in north, northeast, and eastern coastal areas. Cities with lower CO2 emissions are in the western region. Cites with higher CO2 emissions are clustered in the Jing-Jin-Ji Region (such as Beijing, Tianjin, and Tangshan), and the Yangtze River Delta region (such as Shanghai and Suzhou). The city per capita CO2 emission is larger in the north than the south. There are obvious aggregations of cities with high per capita CO2 emission in the north. Four cities among the top 10 per capita emissions (Erdos, Wuhai, Shizuishan, and Yinchuan) cluster in the main coal production areas of northern China. This indicates the significant impact of coal resources endowment on city industry and CO2 emissions. The majority (77%) of cities have annual CO2 emissions below 50 million tons. The mean annual emission, among all cities, is 37 million tons. Emissions from service-based cities, which include the smallest number of cities, are the highest. Industrial cities are the largest category and the emission distribution from these cities is close to the normal distribution. Emissions and degree of dispersion, in the other cities (excluding industrial cities and service-based cities), are in the lowest level. Per capita CO2 emissions in these cities are generally below 20 t/person (89%) with a mean value of 11 t/person. The distribution interval of per capita CO2 emission within industrial cities is the largest among the three city categories. This indicates greater differences among per capita CO2 emissions of industrial cities. The distribution interval of per capita CO2 emission of other cities is the lowest, indicating smaller differences of per capita CO2 emissions among this city category. Three policy suggestions are proposed: first, city CO2 emission inventory data in China should be increased, especially for prefecture level cities. Second, city responsibility for emission reduction, and partitioning the national goal should be established, using a bottom-up approach based on specific CO2 emission levels and potential for emission reductions in each city. Third, comparative and benchmarking research on city CO2 emissions should be conducted, and a Top Runner system of city CO2 emission reduction should be established. 相似文献
63.
应用自动化前处理设备和气相色谱串联四级杆质谱仪建立了淡水鱼体中10种有机磷阻燃剂的检测方法。该方法先采用自动索氏提取仪进行样品的提取,再应用凝胶渗透色谱净化仪和florisil柱对提取液进行两级净化,最后用气相色谱串联四级杆质谱法(多反应监测模式)对样品中的有机磷阻燃剂(OPFRs)定性定量。实验表明,凝胶渗透色谱净化系统在以乙酸乙酯∶环己烷(1∶1,V/V)为流动相,流速为5.0 m L·min-1的条件下,收集OPFRs的最佳时间为900~1 680 s;方法的检出限为0.002~0.192 ng·g~(-1)湿重,加标水平为5.000 ng·g~(-1)湿重时,平均加标回收率为48.7%~122%,相对偏差除磷酸三乙酯(TEP)(17.7%)和磷酸三(1,3-二氯异丙基)酯(TDCP)(11.9%)外均小于10%。应用该方法测定采集于东江某污水处理厂入河排污口的鱼类样品时,回收率指示物(d27-TBP)的回收率为82.4%~114%,鱼类样品中∑OPFRs的浓度范围为nd~6.41 ng·g~(-1)湿重。 相似文献
64.
Anna Stachniuk Agnieszka Szmagara Renata Czeczko Emilia Fornal 《Journal of environmental science and health. Part. B》2017,52(7):446-457
The aim of the research is to evaluate pesticide residue contamination of fresh and frozen fruits and vegetables, agricultural raw material, purchased from Polish farmers for production of frozen fruits and vegetables, and the estimation of the multiresidue method effectiveness expressed as the proportion of pesticides detected in food samples to the total number of pesticides analyzed by multiresidue methods. A total of 144 samples (of black currants, red currants, raspberries, cherries, strawberries, blackberries, cauliflowers and broccoli) were analyzed using LC-MS/MS method for the determination of 60 pesticides. QuEChERS extraction, matrix-matched calibration and dynamic multiple reaction monitoring method were used. Residues of 15 compounds, mainly fungicides and insecticides, were detected in 46 samples. The percentage of samples with residues above the maximum residue levels (MRL) was 15%, whereas samples with residues below MRL were 17%. A total of 13 samples contained more than one pesticide residue. Pesticide residues were detected most often in samples of black currants (50%), broccoli (36.4%), raspberries (29%) and red currants (21.8%). The most frequently detected pesticides were carbendazim and acetamiprid. The proportion of pesticides detected during our study to the total number of analyzed pesticides amounted to 25%. It was compared to literature findings. For three fourth of multiresidue methods, the proportion was below 50% for methods developed for the analysis of less than 100 pesticides, and below 30% for methods developed for the analysis of more than 100 pesticides. It appears that a lot of efforts and means is lost on pesticides never or rarely detected in examined samples. The workload and cost effectiveness of the development and application of multiresidue methods along with the range of pesticides covered by the method should be carefully and thoroughly considered anytime when a new method or workflow is developed. Including non-targeted screenings in pesticide residue control seems to be an alternative worth considering. 相似文献
65.
Hamide Elvan Bayrak Mehmet Tufekci Hacer Bayrak Celal Duran Mustafa Soylak 《毒物与环境化学》2017,99(4):590-600
A simple and sensitive solid phase extraction method was developed for simultaneous separation and preconcentration of gold and palladium ions with N-(4-methylphenyl)-2-{[(4-phenyl-5-pyridine-4-yl-4H-1,2,4-triazol-3-yl)thio]acetyl}hydrazine carbo thioamide complex on Amberlite XAD-1180 resin before their determination by flame atomic absorption spectrometry. Some analytical parameters such as HNO3 concentration of the sample solution, amount of complexing agent, sample volume, eluent type and volume, effects of foreign ions and adsorption capacity of the resin were investigated for quantitative recovery of gold and palladium ions. The effects of some anions and cations were also examined. Under optimum conditions, the detection limits for gold and palladium ions were found to be 0.29 and 0.19 μg L?1, respectively. The preconcentration factor for gold and palladium was 250. After being validated by standard addition and analysis of standard reference material, the procedure was successfully applied to the analysis of sea and stream water, anodic slime, gold ore, soil and electronic waste. 相似文献
66.
采用石墨炉原子吸收法测定水中铊,对样品前处理的多个细节进行改进,使前处理过程耗时缩短,回收率提高。试验表明,方法在0μg/L ~50.0μg/L范围内线性良好,相关系数r为0.9995;检出限为2.0μg/L,取样量为500 mL,富集50倍时,方法检出限为0.04μg/L;实际水样测定结果的 RSD 为4.9%~8.4%;实际样品的加标回收率为94.0%~102%。 相似文献
67.
采用固相萃取法处理水样,气相色谱-高分辨双聚焦磁质谱法测定水中超痕量多氯萘,同位素内标法定量,并对样品前处理条件和仪器条件进行优化。试验表明:方法在0.500 ng/L~500 ng/L范围内线性良好;当取样体积为1 L时,方法检出限为0.005 ng/L~0.01 ng/L;对实际水样进行2个质量浓度水平的加标回收试验,平行测定6次的 RSD为2.7%~8.7%,回收率为70.2%~110%。方法适用性试验表明,水样中复杂的基质对测定无影响。 相似文献
68.
以硝酸银和硫酸铬钾代替硫酸汞来消除 COD 测定中的氯离子干扰,同时将重铬酸钾溶液的浓度降低为0.100 mol/L,并用硫磷混酸代替硫酸,该方法经过对标准样品和实际样品的测定,表现出对于测定氯离子含量低于25000 mg/L的高氯低 COD 值水样具有较好的准确度和精密度,同时可以实现银盐的回收再利用。 相似文献
69.
The popular microblogging service, Twitter, contains a variety of potential orientations—interpersonal, broadcast, news, advertising, public service, political, and so on—in its operation and applications. As an evolving social media platform, specificity and context are essential in understanding its significance and use-value. This paper investigates the multiple modalities of Twitter in the context of formal politics and, in particular, the Greens party in Australia. Presenting original evidence drawn from the Greens Members of Parliament and their advisers, it is shown how Twitter is mobilized in response to particular news agendas and stories, unfolding political events and processes, and an ongoing need for the Greens to speak simultaneously to committed environmentalists and the broader electorate. These uses reveal that Twitter is an important addition to the “media ecology mix” in the conduct of environmental politics, playing a direct role in political communication, strategies, and actions. 相似文献
70.
建立了一种同时测定饮用水中22种邻苯二甲酸酯(PAEs)的高效液相色谱-三重四级杆/复合线性离子阱质谱方法:饮用水样品经针头过滤器过滤,选用Biphenyl液相色谱柱进行分离,以含0.1%甲酸的水溶液和含0.1%甲酸的甲醇溶液为流动相,电离模式为电喷雾正离子,选用多反应监测触发增强子离子扫描模式进行检测。结果表明,22种PAEs的灵敏度良好,定量限为0.001~0.1 μg/L。配制浓度为0.1~100.0 μg/L的混标溶液进行进样分析,分析结果显示,22种PAEs在该范围内的线性关系良好,相关系数均大于0.995,方法的平均回收率为82.9%~108.9%,相对标准偏差为0.9%~11.2%。同时,使用增强子离子扫描谱图进行搜库匹配,定性准确性高。该方法适用于饮用水中PAEs的检测。 相似文献