测定高锰酸盐指数考核样品时的计算方法修正

针对测定高锰酸盐指数考核样品时的结果偏高现象，经过查找，其原因是由于按公式计算没有考虑稀释用纯水的空白值响应。经修正公式后计算，其考核样品的结果则均为正确。     

Determination of levoglucosan and its isomers in size fractions of aerosol standard reference materials

The present study tested the extraction efficiency and quantification reproducibility of anhydrosugars in a series of NIST SRMs using two extraction protocols and isotopically-labeled (d₇-levoglucosan) vs. chemically analogous (sedoheptulosan) surrogates. In both instances, levoglucosan concentrations in the different versions of the Washington, D.C. urban dust standard (SRM 1649, 1649a, 1649b, and RM 8785) were similar. The present test also showed that levoglucosan concentrations were not affected by long-term shelf storage of dry material. Variability of analyses were similar for both surrogates and averaged <5%. Surrogate recoveries were shown to average 103 ± 7% and 97 ± 7% for d₇-levoglucosan and sedoheptulosan, respectively. The choice of solvent was shown to affect recoveries the most (but not variability). Levoglucosan concentrations were either seriously underestimated or overestimated with ethyl acetate extraction when d₇-levoglucosan or sedoheptulosan was used as surrogate, respectively. These results point to the need to use some fraction of polar solvent (i.e. methanol) in the solvent mixture. Anhydrosugar concentrations in the urban dust from the Czech Republic (candidate SRMs 2786 and 2787) were characterized by 3- to 7-fold higher anhydrosugar concentrations than those observed in the Washington, D.C. urban dust. The internal anhydrosugar signatures (i.e. levoglucosan/mannosan ratio: L/M) confirm the predominance of biomass combustion sources in both SRM series with mixed inputs from hardwood and softwood combustion in the Washington, D.C. urban dust and a predominantly softwood source in the Prague urban dust. The uniform distribution of anhydrosugars, across the particle size distribution of both SRM series, confirms earlier studies that low temperature charred materials contribute significant inputs to atmospheric ultrafine particles with long atmospheric residence time and transport ranges.     

Long-Term Monitoring of Scots Pine Litter Decomposition Rates Throughout Sweden Indicates Formation of a More Recalcitrant Litter in the South

Decomposition studies were carried out at sites throughout Sweden, including the four Integrated Monitoring sites. Scots pine needle litterbag weight loss measurements over 3 or 5 years were determined at 26 sites and repeated up to 27 times, depending on the site. Humus layer respiration rates were determined for 20 sites in 1987–1989 and repeated in 2007–2008. Partial Least Squares (PLS) regression was used to elucidate the relative importance of climatic and soil factors. Annual needle weight losses decreased only slowly (20–10%) over 3–5 years for all northern (>60°N) sites but decreased sharply from 30 to 10% in the third year in southern (<60°N) sites. Respiration rates of southern sites were less (40% on average) than those of northern sites. Humus layer N was positively correlated to needle weight loss during the first and the second years, but negatively correlated in the third year and to respiration rates. The results indicated that litter formed in southern Sweden became more recalcitrant in later stages of decomposition compared to litter produced in northern Sweden.     

大叶火焰草生物学特征的修订与补充

通过标本查阅、实地考察、扫描等方法和手段,对大叶火焰草的生物学特征进行了全面修订与补充。首次修正了该物种是2年生草本而非1年生草本植物,基生叶和茎生叶的形状和排列方式均不相同,并首次发现茎上可生腋芽,花药呈红色。同时,首次报道了大叶火焰草倒梯形状的心皮鳞片,扫描电镜下大叶火焰草的种子呈近矩圆球形,外壁被高脊状纵棱。     

适应信息化发展要求,努力实现PPE标准制修订科学化和正规化管理——PPE标准化技术委员会标准全程控制系统介绍

PPE标准化技术委员会标准全程控制系统是基于互联网的PPE信息管理系统平台。该系统采用便捷的B/S架构,利用先进的计算机信息技术,将标准制修订的全过程集成到一个系统中,使标准的制修订流程实现了全程自动化管理,极大地方便了标准制修订各个环节的工作,提高了PPE标准化工作的管理水平,促进了整个行业信息化的发展,确保了国家标准计划按期高水平的完成。     

对环境监测中产生的可疑结果的分析

文章先是介绍了实验室检测的相关规定,即〈检验和校准实验能力认可准则在化学检测领域的应用说明〉,在此基础上,对可疑结果进行了定义,以及简单分析了如何判断出可疑结果,最后对处理可疑结果以及防御可疑结果的产生进行了分析探索,希望可以文章能有参考的价值.     

我国非煤矿山标准现状与分析

对1975—2007年间发布的775项非煤矿山标准的统计分析表明,我国非煤矿山标准的制修订、批准发布属于不同的标准化技术委员会和不同的部门;非煤矿山标准属于有色金属、黑色冶金、建筑材料、核工业、化工、轻工、石油、天然气、机械、汽车等行业领域。在775项标准中,推荐性标准有611项,占78.8%,推荐性标准比例高于强制性标准比例;2007—2002年、2001—1997年、1996—1992年、1991—1987年、1986—1982年、1981—1975年间发布的标准分别为218项、190项、270项、76项、12项、9项,发布时间在5年以上的标准占71.9%,平均发布时间为9.6年,我国非煤矿山标准老化、修订周期长问题比较突出,因此,应加强非煤矿山标准的制修订工作。     

Parameters affecting the stability of the digestate from a two-stage anaerobic process treating the organic fraction of municipal solid waste

This paper focused on the factors affecting the respiration rate of the digestate taken from a continuous anaerobic two-stage process treating the organic fraction of municipal solid waste (OFMSW). The process involved a hydrolytic reactor (HR) that produced a leachate fed to a submerged anaerobic membrane bioreactor (SAMBR). It was found that a volatile solids (VS) removal in the range 40-75% and an operating temperature in the HR between 21 and 35 °C resulted in digestates with similar respiration rates, with all digestates requiring 17 days of aeration before satisfying the British Standard Institution stability threshold of 16 mg CO₂ g VS⁻¹ day⁻¹. Sanitization of the digestate at 65 °C for 7 days allowed a mature digestate to be obtained. At 4 g VS L⁻¹ d⁻¹ and Solid Retention Times (SRT) greater than 70 days, all the digestates emitted CO₂ at a rate lower than 25 mg CO₂ g VS⁻¹ d⁻¹ after 3 days of aeration, while at SRT lower than 20 days all the digestates displayed a respiration rate greater than 25 mg CO₂ g VS⁻¹ d⁻¹. The compliance criteria for Class I digestate set by the European Commission (EC) and British Standard Institution (BSI) could not be met because of nickel and chromium contamination, which was probably due to attrition of the stainless steel stirrer in the HR.     

我国《土壤环境质量标准》中重金属污染相关问题探讨

我国《土壤环境质量标准》（GB 15168—1995）的颁布促进了土壤资源的保护、管理与监督,但由于时间跨度过长社会发展较快,已经不能满足目前实际应用的需要。本文概述了发达国家关于土壤重金属污染的相关指导值/筛选值,并总结了我国现行土壤环境质量标准实施以来存在的问题及近年来的研究进展,对我国《土壤环境质量标准》的修订进行了探讨。     

品牌认证对果农线上销售的影响研究——基于线性回归与PSM方法

基于江西省379份果农的实地调研数据,运用线性回归和倾向得分匹配法检验了品牌认证对果农线上销售的影响。结果表明:①获得“三品一标”认证和注册农产品商标对线上销售均具有显著正向影响,但注册农产品商标的影响效果更明显。②电商经验、鲜果经营培训、品牌建设支持和当地快递公司数对线上销售呈正向影响,而果农年龄和果园距最近快递集散点的距离抑制了线上销售比例的提升。基于研究结论,提出政府应积极引导果农进行品牌认证,加强认证后的监督管理,提高果农品牌保护意识,鼓励果农积极主动注册农产品商标,促使果农线上销售显著提升。