Recycling of organic materials and solder from waste printed circuit boards by vacuum pyrolysis-centrifugation coupling technology

Here, we focused on the recycling of waste printed circuit boards (WPCBs) using vacuum pyrolysis-centrifugation coupling technology (VPCT) aiming to obtain valuable feedstock and resolve environmental pollution. The two types of WPCBs were pyrolysed at 600°C for 30 min under vacuum condition. During the pyrolysis process, the solder of WPCBs was separated and recovered when the temperature range was 400-600°C, and the rotating drum was rotated at 1000 rpm for 10 min. The type-A of WPCBs pyrolysed to form an average of 67.91 wt.% residue, 27.84 wt.% oil, and 4.25 wt.% gas; and pyrolysis of the type-B of WPCBs led to an average mass balance of 72.22 wt.% residue, 21.57 wt.% oil, and 6.21 wt.% gas. The GC-MS and FT-IR analyses showed that the two pyrolysis oils consisted mainly of phenols and substituted phenols. The pyrolysis oil can be used for fuel or chemical feedstock for further processing. The recovered solder can be recycled directly and it can also be a good resource of lead and tin for refining. The pyrolysis residues contained various metals, glass fibers and other inorganic materials, which could be recovered after further treatment. The pyrolysis gases consisted mainly of CO, CO(2), CH(4), and H(2), which could be collected and recycled.     

有机化纳米粘土基絮凝吸附材料对马铃薯淀粉加工废水的资源化处理

采用物理化学提纯方法制备了有机化纳米粘土基絮凝吸附材料,经过以聚乙二醇2000(PEG-2000)、十六烷基三甲基溴化氨(CTAB)、四丁基氢氧化铵(TBAOH,质量分数25％)和溴化四苯基磷(TPPB)4种表面活性剂对絮凝吸附材料进行有机化修饰,并将其应用于马铃薯淀粉加工废水的资源化处理.实验结果表明,有机化纳米粘土...     

Photocatalytic degradation of five sulfonylurea herbicides in aqueous semiconductor suspensions under natural sunlight

In the present study, the photocatalytic degradation of five sulfonylurea herbicides (chlorsulfuron, flazasulfuron, nicosulfuron, sulfosulfuron and triasulfuron) has been investigated in aqueous suspensions of zinc oxide (ZnO), tungsten (VI) oxide (WO₃), tin (IV) oxide (SnO₂) and zinc sulfide (ZnS) at pilot plant scale under natural sunlight. Photocatalytic experiments, especially those involving ZnO photocatalysis, showed that the addition of semiconductors in tandem with the oxidant (Na₂S₂O₈) strongly enhances the degradation rate of the herbicides in comparisons carried out with photolytic tests. The degradation of the herbicides follows a first order kinetics according to the Langmuir-Hinshelwood model. In our conditions, the amount of time required for 50% of the initial pesticide concentration to dissipate (t_½) ranged from 8 to 27 min (t_30W = 0.3-1.2 min) for sulfosulfuron and chlorsulfuron, respectively in the ZnO/Na₂S₂O₈ system. None of the studied herbicides was found after 120 min of illumination (except chlorsulfuron, 0.2 μg L⁻¹).     

碱激发胶凝材料及其固化Pb^2＋的试验研究

对碱激胶凝材料（碱-偏高岭土、碱-矿渣和碱-粉煤灰）与水-水泥体系固化Ph^2＋进行了试验研究，其中水-水泥体系为对比样。结果表明：对于相同稠度的碱激发胶凝材料，即使Pb^2＋含量达到2．4％，除了碱-粉煤灰的抗压强度略低外，其他都达到30MPa以上，满足填埋或做建筑基材的使用要求；与水泥相比，碱激发胶凝材料能显著降低重金属离子（Ph^2＋）浸出浓度，其规律性与其NH4交换容量大小的规律性一致，与其固化体的抗压强度的大小没有相关性。     

ITERATIVE EVALUATION OF A LAKE WATER QUALITY MANAGEMENT PROGRAM1

ABSTRACT: Local governments often face environmental problems that cross political boundaries. The onus for solution usually falls on the moat severely affected jurisdiction, others do nothing until impacted. Resolution of these problems requires cooperation across political boundaries which means that local governments must be persuaded first that there is a problem, and second that action is required to solve it. This paper presents a method to supply low cost, credible information that can be used to achieve consensus on problem solution. A case study of a lake water quality management problem is described. Formative evaluation techniques was adapted to provide a minimum of evidence which was then used to persuade less impacted local jurisdictions to cooperate in the problem solution.     

小口径弹用密封材料贮存寿命预测

采用美国军用手册，ASTM的方法和数据，以最少的试验和费用，快速地预测硅橡胶贮存寿命。预测结果可以作为评估该弹用密封材料自然长贮寿命的依据。     

Biomethanation of plant materials and agricultural residues using dung samples as wild population of microbes and also with isolated methanogens

Recycling of plant materials and agricultural residues for biomethanation was attempted in vials. The methanogenic activities of certain sewage samples have also been tested. Both sterilized and non-sterilized biomasses were used. Biomethanation was carried out with dung samples (cow, goat, buffalo, piggery wastes and poultry wash) as wild populations of microbes and in combination with other microbial isolates (isolated in the laboratory).Biomethanation had been observed to be good in most cases and particularly with the sterilized biomass. Mixed inoculum (dung samples and poultry wash) was found to be best for biomethanation. Of the microbe isolates, isolates from buffalo, pig and paper mill wastes appear to be most effective. Pretreated sawdust and rice straw were found to be good subtrates for biomethanation. Of the different plant biomass used Spirogyra (algae), Ipomea and water hyacinth were most effective whereas Jatropa gossypifolia and Parthenium sp. were the least effective. Biomethanation of Spirogyra was carried out both in anoxic and oxic conditions. Though methane production decreased enormously under oxic conditions, definite methane production continued indicating that the biomethanation process is not exclusively anoxic. Similarly, biomethanation of sewage samples from different sewage treatment plants were carried out with and without isolated methanogens and methane production was found to be moderate.     

建筑物可靠性鉴定与加固技术的发展

探讨了国内外建筑物可靠性检测鉴定加固技术的现状与发展，并对常用的建筑结构质量检测方法，检测仪器和加固技术进行了介绍和评价。     

高层建筑火灾人员疏散和人员伤亡的模拟

基于建筑火灾全风网网络模型的基础上 ,结合紧急疏散模型 ,模拟火灾时期疏散时间和建筑物内人员滞留的情况 ,同时也可以模拟可能出现的伤亡情况 ,有助于高层建筑的疏散系统设计 ,为火灾的再现提供了一个有效的分析工具 ,也为高层建筑火灾的风险评价提供了理论数据     

基于小波包分析的爆破振动危害评价初探

结合振动主频的质点振速判据是对单一质点振速判据的补充和完善.但该判据的振动主频是通过FFT变换的频谱分析的方法获得的,不能体现爆破振动波形的多主振频带特征,而且由于方法本身的局限性使得主振频率发生的时间段不能确定.小波包分析法则克服了FFT频谱分析的局限,有效地分解和重构原始信号中的细节信号,并将其作为评价不同频率细节信号的爆破振动危害效果的基础.本文针对爆破振动的小波包分析法进行了研究,对各小波包细节信号加载条件下的不同危害效果进行了讨论,得到了相应的质点振速判据,并将该方法所得到的判据与FFT变换的频谱分析方法所得到的判据进行了对比.结果表明,基于小波包分析法的质点振速判据更加符合爆破振动危害的真实情况.