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用酸碱指示剂滴定法测定废水的中的OH-,CO3^2-,HCO3^-碱度时,S^2-对测定有干扰,此干扰可用H2O2掩蔽。 相似文献
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以新配和含有一定H_2S的MDEA溶液为吸收液,以聚偏氟乙烯(PVDF)膜组件为接触器,通过对操作参数的调节和改变膜孔大小等方法对脱硫率和总传质系数进行研究。结果表明:气液压力差以及膜孔孔径的增加均有利于脱硫率和总传质系数的提升,即均有利于脱硫。降低进气流量和低气液比均对H_2S传质有积极作用。 相似文献
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针对UV/H_2O_2对氯化消毒副产物三氯甲烷(TCM)和一溴二氯甲烷(DCBM)的去除效果及影响因素进行研究,结果表明UV/H_2O_2方法对TCM和DCBM去除效果的影响因素有过氧化氢(H_2O_2)投加量、紫外光照强度、反应p H值和反应物初始浓度。通过不同的反应条件得出:H_2O_2在一定投加量变化范围(10~35 mmol/L)内,随投加量的增加,TCM和DCBM的去除率均呈先上升后下降趋势,H_2O_2最佳投加量分别为25,20 mmol/L;增大紫外光照(UV)强度,TCM和DCBM的去除率均显著提高;随初始p H值的增大,去除率均呈先上升后下降趋势,p H值为7.0时,去除率达到最佳;TCM和DCBM反应初始浓度分别为150,160μg/L时,其去除率最高,在有效时间内去除率分别为95.88%、92.56%。 相似文献
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Formic acid was used for the nitrate reduction as a reductant in the presence of Pd:Cu/γ-alumina catalysts. The surface characteristics of the bimetallic catalyst synthesized by wet impregnation were investigated by SEM, TEM-EDS. The metals were not distributed homogeneously on the surface of catalyst, although the total contents of both metals in particles agreed well with the theoretical values. Formic acid decomposition on the catalyst surface, its influence on solution pH and nitrate removal efficacy was investigated. The best removal of nitrate (50 ppm) was obtained under the condition of 0.75 g/L catalyst with Pd:Cu ratio (4:1) and two fold excess of formic acid. Formic acid decay patterns resembled those of nitrate removal, showing a linear relationship between kf (formic acid decay) and k (nitrate removal). Negligible amount of ammonia was detected, and no nitrite was detected, possibly due to buffering effect of bicarbonate that is in situ produced by the decomposition of formic acid, and due to the sustained release of H2 gas. 相似文献
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采用极化曲线、旋转圆盘电极试验和失重(质量损失)法研究了低合金钢在添加了H。o:的海水中腐蚀加速的主要影响因素。结果发现低合金钢在添加H2O2的海水中腐蚀加速主要受到了H2O2浓度、温度、搅拌速度和H2O2添加周期的影响。研究表明,搅拌速度不变、H2O2添加周期相同的条件下,在H2O2浓度为0.8mol/L的70℃海水中,低合金铜的腐蚀加速最显著;在试验的转速范围内,加速作用随搅拌速度增大变得更为显著;H2O2加入后350min内加速作用较明显。 相似文献
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Meeta Lavani Priyangshu M. Sarm Ajoy K. Man Simrita Cheem Banwari La 《环境科学学报(英文版)》2011,23(8):1394-1402
We compared the efficacy of a natural biocide with four chemical tetrakishydroxymethyl phosphonium sulfonate, benzyl trimethyl
ammonium chloride, and formaldehyde, glutaraldehyde, to control microbial induced corrosion in oil pipelines. The efficacy of biocides
were monitored against Desulfovibrio vulgaris and Desulfovibrio gigas in experimental pipes by measuring cell counts, H2S production,
Fe(II) production, production of extracellular polymeric substances and structure of biofilm. The treatment with cow urine had minimum
planktonic cell counts of 3 102 CFU/mL as well as biofilm cell counts of 9 101 CFU/mL as compared with tetrakishydroxyl methyl
phosphonium sulfonate, benzyl trimethyl ammonium chloride, formaldehyde and glutaraldehyde. Sulfide production was the lowest
with cow urine (0.08 mmol/L), followed by tetrakishydroxymethyl phosphonium sulfonate 0.72 mmol/L. On day 90 of treatment,
Fe(II) production was also found to be the lowest with cow urine. The scanning electron microscopic studies indicated that the biofilm
bacteria were killed by cow urine. These results demonstrate the cow urine mediated control of microbially induced corrosion, and this
is indicative of its potential as a viable substitute of toxic biocides. To the best of our knowledge, this seems to be the first report which
screens possible biocidal activity by cow urine as compared to the most common biocides which oil industry is currently using. 相似文献