Carbon nitride,metal nitrides,phosphides, chalcogenides,perovskites and carbides nanophotocatalysts for environmental applications

Environmental Chemistry Letters - Effective technologies and materials are needed for environmental detoxification and clean energy production. The actual photocatalytic technology is largely...     

Microwave synthesis and antifungal evaluations of some chalcones and their derived diaryl-cyclohexenones

Microwave irradiation (MWI) of acetophenones and substituted benzaldehydes in water resulted in a “green-chemistry” procedure for the preparation of chalcones (1-14), through base catalyzed Claisen-Schmidt condensation reaction, in good yields. Further 3,5-diaryl-6-carbethoxy-2-cyclohexen-1-ones (1a-14a) were prepared through base catalyzed cyclocondensation of above chalcones with ethylacetoacetate using MWI as the energy source and silica as support. Out of fourteen cyclohexenones, ten (1a, 4a, 5a, 6a, 7a, 9a, 10a, 11a, 12a and 13a) are reported for the first time in literature. The synthesized compounds were characterized using various spectroscopic techniques, viz. (¹H NMR and IR) and screened for their antifungal activity in vitro against Sclerotium rolfsii and Rhizoctonia solani by poisoned food technique. The compounds tested were found to be active against R. solani whereas against S. rolfsii, moderate activity was observed, as evident from LC₅₀ values. The most potent compounds against R. solani were 1-(4-Fluoro-phenyl)-3-phenyl-propenone (13) and 1,3-Diphenyl-propenone (14) having LC₅₀ values of 2.36 and 2.49 mgL^{? 1} respectively (LC₅₀ of Hexaconazole = 1.12 mgL^{? 1}) and against S. rolfsii 3-(4-Fluoro-phenyl)-5-(3-nitro-phenyl)-6-carbethoxy-2-cyclohexen-1-one (12a) was most active having LC₅₀ value of 285 mgL^{? 1}compared to Hexaconazole (LC₅₀ = 1.27 mgL^{? 1}).     

Seasonal variations in abundance of nitrifying bacteria in fish pond ecosystem

Seasonal changes in abundance of nitrifiers (ammonia-oxidizing and nitrite-oxidizing bacteria) in surface and bottom water of freshwater ponds were examined with respect to temperature, DO, pH as well as concentration of ammonia and nitrite. The most probable number (MPN) of ammonia-oxidizers in different ponds varied from 1297 +/- 3.6 to 1673.23 +/- 0.36 ml(-1) in bottom and 720.5 +/- 8.1 to 955.3 +/- 10.8 ml(-1) in surface water during the rainy season while the MPN ranged from 1074 +/- 1.07 to 1372.17 +/- 4.6 ml(-1) in bottom and 515 +/- 10.1 to 678 +/- 11.8 ml(-1) in surface water in winter. However, the MPN were greatly reduced in summer and ranged from 435.05 +/- 15.7 to 547.54 +/- 2.12 ml(-1) in bottom and 218.7 +/- 7.3 to 368.4 +/- 9.32 ml(-1) in surface water. Similar seasonal trends were also observed in MPN of nitrite-oxidizers. Among all the physico-chemical parameters, abundance of nitrifiers was more positively correlated with ammonia and nitrite concentration in all the seasons. The abundance of nitrifiers in surface and bottom water was highest in rainy season followed by winter and modest in summer. The potential nitrification activities and oxidation rates were shown to be linear and activity of ammonia-oxidizing and nitrite-oxidizing bacteria was highest during rainy season.     

Biodegradation of Pro-oxidant Filled Polypropylene Films and Evaluation of the Ecotoxicological Impact

The biodegradability of calcium stearate (CaSt) and cobalt stearate (CoSt) filled polypropylene (PP) films were investigated in this work. The PP films were prepared using melt blending technique followed by hot press moulding. On the basis of their tensile properties, the optimum amount of pro-oxidants was taken as 0.2 phr. Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were used for the characterization of optimized films. Presence of pro-oxidant in the PP was confirmed by the FTIR studies. Addition of pro-oxidants in the films decreased the thermal stability as revealed by TGA analysis. Crystallinity of the pro-oxidant filled PP decreased with addition of pro-oxidants as showen by DSC. The maximum biodegradation of CaSt and CoSt containing PP films was showen 7.65 and 8.34%, respectively with 0.2 phr. Both the microbial test and plant growth test (on corn and tomato) indicated that biodegradation intermediates were non toxic.     

Characterisation of coal washery effluent and optimisation of coagulation behaviour of <Emphasis Type="Italic">Moringa oleifera</Emphasis> seed as a coagulant

The huge quantity of effluent generated in coal washing processes contains large amount of suspended and dissolved solids, clay minerals, coal fines and other impurities associated with raw coal. The present system of recirculation of the effluent is found to be ineffective in removing colloidal fines, which is the major part of the impurities present in washery effluent. Hence, there is a need for the assessment of a better technique for an efficient removal of these impurities. This study deals with detailed characterisation of coal washery effluent and fine particles present in it. For efficient removal of impurities, the suitability of biocoag-flocculation process using Moringa oleifera seed biomass as a natural coagulant was examined. Various doses of M. oleifera ranging from 0.2 to 3 mL/L were used in order to determine the optimal conditions. The impact of the variations in pH of the effluent (2–10), contact time (5–30 min), settlement time (5–50 min), temperature (10–50 °C) and the effluent dilution (1:0–1:5) was also assessed to optimise the treatment process. Post treatment analysis was carried out for determination of the different parameters such as pH, conductivity, turbidity, solids and settling velocity. Excellent reduction in turbidity (97.42%) and suspended solids (97.78%) was observed at an optimum dose of M. oleifera seed coagulant of 0.8 mL/L with an optimum contact time of 15 and at 20 min of settling time. In comparison with very few past studies of M. oleifera in the treatment of coal washery effluent with high dose and inadequate removal, this study stands to be a major highlight with low dose and high removal of the impurities. M. oleifera coagulant is considered to be an environment-friendly material, therefore, its application is recommended for simple and efficient treatment of coal washery effluent.     

Scale dependency of dynamic relative permeability–satuartion curves in relation with fluid viscosity and dynamic capillary pressure effect

Capillary pressure–saturation-relative permeability relationships (P_c–S_w–K_r) are functions of importance in modeling and simulations of the hydrodynamics of two-phase flow in porous media. These relationships are found to be affected by porous medium and fluid properties but the manner in which they are affected is a topic of intense discussion. For example, reported trends in fluid viscosity and boundary conditions effects have been found to be contrary to each other in different studies. In this work, we determine the dependency of dynamic K_r–S_w relationships (averaged data) on domain scale in addition to investigating the effects of fluid viscosity and boundary pressure using silicone oil (i.e. 200 and 1000 cSt) and water as the respective non-wetting and wetting fluids with a view to eliminating some of the uncertainties reported in the literature. Water relative permeability, K_rw, was found to increase with increasing wetting phase saturation but decreases with the increase in viscosity ratio. On the other hand, the oil relative permeability, K_rnw, was found to increase with the increasing non-wetting phase saturation in addition to the increase in viscosity ratio. Also, it was found that with the increasing boundary pressure K_rw decreases while K_rnw increases. The influence of scale on relative permeability was slightly indicated in the non-wetting phase with K_rnw decreasing as domain size increases. Effect of measurement location on dynamic relative permeability was explored which is rarely found in the literature. Comparison was also made between K_r–S_w relationships obtained under static and dynamic condition. Finally, mobility ratio (m) and dynamic coefficient (τ) were plotted as a function of water saturation (S_w), which showed that m decreases as τ increases at a given saturation, or vice versa.     

Tracking land cover change along the western edge of the U.S. Corn Belt from 1984 through 2016 using satellite sensor data: observed trends and contributing factors

The Cropland Data Layers (CDL) are high-resolution geo-referenced data products made available by the U.S. Department of Agriculture. However, the CDL lacks in its ability to be employed as a tool to identify the impact of the gradually evolving drivers of land use change, e.g., climate change, due to its limited historical depth. We implement a robust, phenology-based satellite image classification algorithm to identify historical cropland allocation in eastern South Dakota and North Dakota predating the initial CDL by 13 and 22 years, respectively. Five major land covers, i.e., corn, soybeans, wheat, alfalfa and grass (including native grass, hay and pasture) are identified using archived Landsat-5 surface reflectance data, while achieving CDL-like accuracy. The long-term rate of grassland loss during 1985–2011 is found to be significantly lower (26,781 hectares or 1.5% annually) relative to the near-term rate of grassland loss during 2006-’11 (84,545 hectares or 5.2% annually). We find similar discrepancy in regional corn expansion rates. Our value-added raster data provide opportunities for improved identification of land use drivers, whereas relying solely on the CDL’s restricted historical extent may lead to biased land use change estimates and misguide policy.     

Degradation of Commercial Biodegradable Packages under Real Composting and Ambient Exposure Conditions

The use of long-lasting polymers as packaging materials for short lived applications is not entirely justified. Plastic packaging materials are often soiled due to foodstuffs and other biological substances, making physical recycling of these materials impractical and normally unwanted. Hence, there is an increasing demand for biodegradable packaging materials which could be easily renewable. Use of biopolymer based packaging materials allows consideration of eliminating issues such as landfilling, sorting and reprocessing through taking advantage of their unique functionality, that is compostability. Composting allows disposal of biodegradable packages and is not as energy intensive compared to sorting and reprocessing for recycling, although it requires more energy than landfilling. The aim of this work was to study the degradation of three commercially available biodegradable packages made of poly (ld-lactide) (PLA) under real compost conditions and under ambient exposure by visual inspection, gel permeation chromatography, differential scanning calorimetry, and thermal gravimetric analysis. A novel technique to study the degradability of these packages and to track the degradation rate under real compost conditions was used. The packages were subjected to composting for 30 days, and the degradation of the physical properties was measured at 1, 2, 4, 6, 9, 15 and 30 days. PLA packages made of 96% l-lactide exhibited lower degradation than PLA packages made of 94% l-lactide, mainly due to their highly ordered structure, therefore, higher crystallinity. The degradation rate changed as the initial crystallinity and the l-lactide content of the packages varied. Temperature, relative humidity, and pH of the compost pile played an important role in the total degradation of the packages. A first order degradation of the molecular weight as a function of time was observed for the three packages.     

Computational energy estimation tools for machining operations during preliminary design

The aim of this paper is to develop computational machining energy estimation tools during the early design stage of product development. In the preliminary or embodiment design, a product's shape and materials are determined. At this stage, it is crucial for a designer to be able to compare alternative designs and materials based on many different criteria, such as cost, functionality, energy, etc. Automated tools for estimating energy consumption that could later be used to integrate with CAD/CAM systems are in demand. This study presents computational tools for estimating the energy consumption of machining operations during the early design phase. The computational tools utilize a preliminary computer representation of a product (CAD model), its material and candidate machining operations to automatically analyse and estimate a range of energy consumption during machining operations. Detailed steps for computing turning and milling energy consumption are presented. Case studies of both parts and assemblies were conducted to test the validity of the tools and to evaluate the performance of the tools. Environmental impacts such as carbon weight will also be estimated. The computation tools will assist users with little knowledge about energy computations to estimate energy consumption during the design stage. Such energy estimation can be used to redesign parts and assemblies, leading to the development of products with reduced machining energy. The computation tools are part of a larger research on estimating energy consumption throughout a product's life cycle.     

Metallic and bimetallic phosphides-based nanomaterials for photocatalytic hydrogen production and water detoxification: a review

Environmental Chemistry Letters - Providing sustainable energy and cleaning water pollution are actually&nbsp;major societal issues requiring new catalysts. In particular,&nbsp;transition...