水合氧化铁对痕量铀的吸附行为

研究了水合氧化铁的制备条件及其对痕量铀的吸附行为，结果表明，当加碱温度和反应温度均为80℃时，吸附剂具有最大比表面积172．8m^2.g^-1，当吸附平衡时间为30min，吸附温度为90－95℃，溶液pH≈6时，铀吸附量可达122mg.g^-1，但吸附体系中硼酸和硫酸镁的存在导致铀吸附量下降。     

Larval chemical defence and evolution of host shifts in Chrysomela leaf beetles

Summary. Larvae of Chrysomela leaf beetles release for defence volatile compounds belonging to various chemical families. This study focuses on the defensive strategy based on the esterification of isobutyric acid and 2-methylbutyric acid with a wide variety of alcohols taken up from the host plant. To date, only two species are known to produce these repellents C. interrupta, which is associated with Betulaceae and C. lapponica which occurs either on Betulaceae or Salicaceae.? In order to know if other species have developed this chemical defence and how the food plant influences the secretion of these toxins, we targeted by mass spectrometry the presence of iso- and 2-methylbutyric acids and esters of them in the defensive secretions of Chrysomela larvae exclusively associated with Betulaceae or Salicaceae. ?Screening analyses reveal that the synthesis of these compounds is a common character restricted to all the members belonging to the C. interrupta group sensu Brown (1956) regardless of the host-plant family. These results suggest that the biochemical mechanism leading to the synthesis of these compounds could be considered as a synapomorphy meaning that the group is probably monophyletic. ?Defensive secretions of the members of the interrupta group are quantitatively assayed for iso- and 2-methylbutyric acids and their (Z)-3-hexenyl esters. Results reveal a chemical plasticity developed by Chrysomela species associated with Salicaceae. The amounts of iso- and 2-methylbutyric acids derivatives and of salicylaldehyde in their larval secretions depend on the food plant and on its content in phenolglucosides. Received 5 October 1998; accepted 25 November 1998.     

Acoustic concomitants of the defensive discharges of a primitive bombardier beetle (Metrius contractus)

Summary. Metrius contractus, a primitive paussoid bombardier beetle, emits its defensive quinonoid froth with accompanying sound (a faint “hiss”), but the sound is not pulsed, indicating that the secretory emission itself is not pulsed. Pulsed secretory delivery in bombardier beetles appears to occur in Brachinini only. Received 8 July 2001; accepted 23 July 2001.     

Benzoic acid, a stimulant of odorant receptors of Bombyx mori, is rapidly metabolized to N-benzoylserine on the antennae

Summary. Benzoic acid is a known stimulant of olfactory receptor cells in trichoid sensilla on the antennae of adult females of Bombyx mori. Exposure of freshly excised antennae, from B. mori females and males, to vapours of [¹⁴C]-benzoic acid revealed that the adsorbed acid is rapidly metabolized (15% conversion in 10 s), suggesting the presence of a highly active enzymatic system. The major product could be identified as N-benzoylserine by use of [²H₅]-benzoic acid, and mass spectrometry linked to a gas chromatograph (GC-MS) or a liquid chromatograph (LC-MS), for analysis of the metabolites. The conjugation of benzoic acid with an amino acid apparently represents a novel mode for the rapid deactivation of odorant molecules. Received 26 March 2001.     

Spray mechanism of crepidogastrine bombardier beetles (Carabidae; Crepidogastrini)

Summary.   The defensive glandular apparatus of primitive bombardier beetles of the tribe Crepidogastrini (Carabidae) is described for the first time. As exemplified by two African species (Crepidogaster ambreana and C. atrata), the apparatus conforms to the basic bombardier plan, in that the glands are bicompartmented and the secretion is quinonoid (it contains 1,4-benzoquinones and hydrocarbons), hot, and discharged audibly. In a number of morphological respects the crepidogastrine apparatus resembles that of the classical bombardiers of the tribe Brachinini (rather than that of bombardiers of the paussoid lineage), reinforcing the view, already held on taxonomic grounds, that the Crepidogastrini and Brachinini are closely related. That the Crepidogastrini may be primitive relative to Brachinini is underscored by the finding that, unlike brachinines, crepidogastrines do not pulse their secretory emissions. Moreover, they discharge their secretion as a mist, rather than forcibly in the form of jets. Received 22 May 2001; accepted 29 May 2001.     

Hazardous waste indicators for national decision makers

Indicators and indices are important tools that assist decision makers to formulate and implement plans for management at local, national and international levels. Four indicators for hazardous waste management are described that have recently been adopted within the United Nations framework of Indicators of Sustainable Development. Although these four indicators will be useful tools, the need for a broader range of policy-relevant qualitative and quantitative indicators, proxy indicators and indices is outlined. The argument is advanced that in order for all nations to better manage the range of hazardous waste issues, including waste generation, export/import and disposal, a set of innovative indicators and indices is required. Useful indicators and indices are described that could be used to link and quantify likely environmental, ecosystem and health impacts and risks especially from hazardous waste disposal. Indicators are also suggested that could be used to illustrate the shift in industrial strategy away from end-of-pipe processes towards waste recycling, cleaner production and integrated life-cycle analysis. It was concluded that until the lack of reliable and harmonized data on hazardous waste is addressed, indicator development and use by national and international decision makers cannot readily be implemented.     

Jasmonic acid treatment and mammalian herbivory differentially affect chemical defenses and growth of wild mustard (Brassica kaber)

Summary. Jasmonic acid (JA) is a wound-related hormone found in most plants that, when applied exogenously, can induce increases in levels of chemical defenses in patterns similar to those induced by mechanical damage or insect feeding. Relative to responses to insect and pathogen attack, chemical responses of herbaceous plants to mammalian herbivore attack have been little studied. In a field experiment, we compared the effects of JA treatment and naturally occurring mammalian herbivory on the expression of trypsin inhibitors, glucosinolates, peroxidase activity and growth of wild mustard (Brassica kaber). Exogenous JA significantly increased trypsin inhibitor activity and glucosinolate concentration, and moderately increased peroxidase activity in the eighth true leaves of five-week-old plants, relative to untreated controls. In contrast, levels of these chemical defenses in the eighth true leaves or in regrowth foliage of plants that had ∼80% of their leaf area removed by groundhogs (Marmota monax) did not differ from that in undamaged and untreated controls. Although exogenous JA significantly elevated levels of chemical defenses, it did not affect height of plants through the season and only slightly reduced time to first flower. Groundhog herbivory significantly reduced height and delayed or abolished flowering, but these effects were not substantial unless coupled with apical meristem removal. We hypothesize that the lack of effect of groundhog herbivory on chemical defenses may be due in part to the speed and pattern of leaf area removal by groundhogs, or physiological constraints caused by leaf area loss. Despite having no effect on chemical defense production, leaf area loss by groundhogs was more costly to growth and fitness than the effects of JA application in this study, but only substantially so if coupled with apical meristem removal. We suggest that in general, costs of defense production in plants are likely to be minimal when compared to the risk of losing large amounts of leaf area or primary meristematic tissue. Thus, if they are effective at deterring herbivory, the benefits of inducible defense production likely outweigh the costs in most cases. Received 20 December 2000; accepted 3 May 2001     

有机膨润土对苯胺的吸附性能及应用研究

以溴化十六烷基三甲铵为改性剂制备有机膨润土，利用正交实验研究了有机膨润土吸附垃圾渗滤液中极性有机污染物苯胺的性能、条件及改性条件对吸附效果的影响。结果表明，有机改性膨润土对苯胺有很好的吸附效果，实验条件下对苯胺的去除率可达90％以上，绘制了有机膨润土吸附苯胺的吸附等温线，通过与吸附苯酚效果的比较，总结了有机膨润土吸附极性有机污染物的一般规律。     

二氧化氯对有机染料脱色效果的研究

本文对二氧化氯二两种直接染料和两种活性染料脱色效果的影响因素－ClO2的投加量、染料的初始浓度、pH值、温度以及反应时间等进行了研究。结果表明，在适当的条件下，二氧化氯对这几种有机染料均具有很好的脱色效果。     

Watershed management and the Web

Watershed analysis and watershed management are developing as tools of integrated ecological and economic study. They also assist decision-making at the regional scale. The new technology and thinking offered by the advent of the Internet and the World Wide Web is highly complementary to some of the goals of watershed analysis. Services delivered by the Web are open, interactive, fast, spatially distributed, hierarchical and flexible. The Web offers the ability to display information creatively, to interact with that information and to change and modify it remotely. In this way the Internet provides a much-needed opportunity to deliver scientific findings and information to stakeholders and to link stakeholders together providing for collective decision-making. The benefits fall into two major categories: methodological and educational. Methodologically the approach furthers the watershed management concept, offering an avenue for practical implementation of watershed management principles. For educational purposes the Web is a source of data and insight serving a variety of needs at all levels. We use the Patuxent River case study to illustrate the web-based approach to watershed management. A watershed scale simulation model is built for the Patuxent area and it serves as a core for watershed management design based on web applications. It integrates the knowledge available for the Patuxent area in a comprehensive and systematic format, and provides a conceptual basis for understanding the performance of the watershed as a system. Moreover, the extensive data collection and conceptualisation required within the framework of the modeling effort stimulates close contact with the environmental management community. This is further enhanced by offering access to the modeling results and the data sets over the Web. Additional web applications and links are provided to increase awareness and involvement of stakeholders in the watershed management process. We argue that it is not the amount and quality of information that is crucial for the success of watershed management, but how well the information is disseminated, shared and used by the stakeholders. In this respect the Web offers a wealth of opportunities for the decision-making process, but still to be answered are the questions at what scale and how widely will the Web be accepted as a management tool, and how can watershed management benefit from web applications.