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21.
Min Song Chenchen Chi Min Guo Xueqing Wang Lingxiao Cheng Xueyou Shen 《环境科学学报(英文版)》2015,28(2):157-162
The pollution status and characteristics of PAEs(phthalate esters) were investigated in indoor air of offices, and PAEs of both gas-phase and particulate-phase were detected in all the samples. The concentration(sum of the gas phase and the particulate phase) was4748.24 ng/m3, ranging between 3070.09 and 6700.14 ng/m3. Diethyl phthalate, dibutyl phthalate, and di(2-ethylhexyl) phthalate were the most abundant compounds, together accounting for 70% of the ∑ 6PAEs. Dividing the particulate-phase PAEs into four size ranges( 2.5, 2.5–5, 5–10, 10 μm), the result indicated that PAEs in PM2.5were the most abundant,with the proportion of 72.64%. In addition, the PAE concentration in PM2.5correlated significantly with the total particulate-phase PAEs(R2= 0.85). Thus, the amount of PAEs in PM2.5can be estimated from the total amount of particulate-phase PAEs using this proportion. In a comparison between the offices and a newly decorated study room, it was found that pollution characteristics were similar between these two places. Thus, it is implied that the PAE concentration decreased by 50% 2 yr after decorating. 相似文献
22.
The concentrations of phthalate esters(PAEs) in Chinese hospitals were investigated by simultaneously determining concentrations of gas- and particle-phase PAEs. PAEs were detected in two third-class first-grade hospitals, two second-class first-grade hospitals, and a community health service center. Hospital drugstores had the highest concentration(24.19 μg/m3), which was 1.54 times that of newly decorated houses. The second highest concentration was found in the transfusion rooms, averaging 21.89 μg/m3; this was followed by the concentrations of PAEs in the nurse's workstations, the wards, and the doctor's offices, with mean concentrations of 20.66, 20.0, and 16.92 μg/m3, respectively. The lowest concentrations were found in the hallways(16.30 μg/m3). Of the six different kinds of PAEs found, major pollutants included diethyl phthalates, dibutyl phthalates, butylbenzyl phthalates and di(2-ethylhexyl) phthalates, comprising more than 80% of all PAEs present.Meanwhile, a comparison between different wards showed that PAE concentrations in the maternity wards were 1.63 times higher than in the main wards. Based on known health hazards, our results suggest that the PAEs seriously influence the health of the pregnant women and babies; therefore, it is of great importance to take the phthalate concentrations in hospitals into consideration. In addition, hospital indoor air was more seriously contaminated than the air of newly decorated houses. 相似文献
23.
E. Vartiainen M. Kulmala T.M. Ruuskanen R. Taipale J. Rinne H. Vehkamki 《Atmospheric environment (Oxford, England : 1994)》2006,40(40):7882-7892
Oxidation of d-limonene, which is a common monoterpene, can lead to new aerosol particle formation in indoor environments. Thus, products containing d-limonene, such as citrus fruits, air refresheners, household cleaning agents, and waxes, can act as indoor air aerosol particle sources. We released d-limonene into the room air by peeling oranges and measured the concentration of aerosol particles of three different size ranges. In addition, we measured the concentration of d-limonene, the oxidant, and the concentration of ozone, the oxidizing gas. Based on the measurements we calculated the growth rate of the small aerosol particles, which were 3–10 nm in diameter, to be about , and the losses of the aerosol particles that were due to the coagulation and condensation processes. From these, we further approximated the concentration of the condensable vapour and its source rate and then calculated the formation rate of the small aerosol particles. For the final result, we calculated the nucleation rate and the maximum number of molecules in a critical cluster. The nucleation rate was in the order of and the number of molecules in a critical-sized cluster became 1.2. The results were in agreement with the activation theory. 相似文献
24.
分析了我国居住建筑室内PM_(2.5)污染水平,总结了现阶段PM_(2.5)的研究方法,主要包括理论分析法、数值模拟法和实验测试法。指出室外源是室内PM_(2.5)的主要污染来源,而室内烟草烟雾、烹饪及人员活动也会严重影响室内PM_(2.5)浓度。针对目前研究中存在的问题,提出了标定典型建筑在不同影响因素下的I/O比范围、研究家具和家电的颗粒物释放状况、加强农村室内外空气颗粒物污染调查等建议。 相似文献
25.
Melissa M. Lunden Kenneth L. Revzan Marc L. Fischer Tracy L. Thatcher David Littlejohn Susanne V. Hering Nancy J. Brown 《Atmospheric environment (Oxford, England : 1994)》2003,37(39-40):5633
Recent studies associate particulate air pollution with adverse health effects; however, the exposure to indoor particles of outdoor origin is not well characterized, particularly for individual chemical species. We conducted a field study in an unoccupied, single-story residence in Clovis, California to provide data and analyses to address issues important for assessing exposure. We used real-time particle monitors both outdoors and indoors to quantify nitrate, sulfate, and carbon particulate matter of particle size 2.5 μm or less in diameter (PM-2.5). The results show that measured indoor ammonium nitrate concentrations were significantly lower than would be expected based solely on penetration and deposition losses. The additional reduction can be attributed to the transformation indoors of ammonium nitrate into ammonia and nitric acid gases, which are subsequently lost by deposition and sorption to indoor surfaces. A mass balance model that accounts for the kinetics of ammonium nitrate evaporation was able to reproduce measured indoor ammonium nitrate and nitric acid concentrations, resulting in a fitted value of the deposition velocity for nitric acid of 0.56 cm s−1. The results indicate that indoor exposure to outdoor ammonium nitrate in Central Valley of California are small, and suggest that exposure assessments based on total particle mass measured outdoors may obscure the actual causal relationships for indoor exposure to particles of outdoor origin. 相似文献
26.
沈阳市室内空气污染现状与控制对策 总被引:1,自引:1,他引:0
论述了由室内装修引起的室内空气污染问题,并通过对沈阳市部分居室和办公场所的监测数据进行统计分析;在有限指标内反映沈阳市室内空气污染的现状,并提出控制对策。 相似文献
27.
活性炭吸附室内空气中挥发性有机化合物 总被引:13,自引:0,他引:13
活性炭吸附室内空气中挥发性有机化合物的10%穿透时间与气相浓度及挥发性有机化合物的种类有关,通过对苯、甲苯和丙酮的实验研究,得出了由高浓度估算室内低浓度时炭床10%穿透时间的经验公式tb,1=tb,h(C0,1/C0,h)^a,其中a值是与炭床性能及挥发性有机化合物种类有关的参数,可通过实验确定。 相似文献
28.
室内空气污染净化研究进展 总被引:3,自引:0,他引:3
介绍了室内空气污染的现状、特点及其危害,指出了室内空气污染的主要污染源和污染物。综述了各种室内空气污染净化技术,并介绍了各种技术的优缺点。本文最后对室内空气污染净化的发展前景进行了展望。 相似文献
29.
30.
室内空气污染影响因素箱模式及应用 总被引:3,自引:0,他引:3
在借鉴大气总量控制箱模式的理论基础上 ,探讨了室内空气污染物浓度的新的计算方法 ,并通过此模式对影响因素作了分析和分情况解释。并举实例加以计算。 相似文献