Comparison of particle emissions from small heavy fuel oil and wood-fired boilers

Flue gas emissions of wood and heavy fuel oil (HFO) fired district heating units of size range 4–15 MW were studied. The emission measurements included analyses of particle mass, number and size distributions, particle chemical compositions and gaseous emissions. Thermodynamic equilibrium calculations were carried out to interpret the experimental findings.In wood combustion, PM1 (fine particle emission) was mainly formed of K, S and Cl, released from the fuel. In addition PM1 contained small amounts of organic material, CO₃, Na and different metals of which Zn was the most abundant. The fine particles from HFO combustion contained varying transient metals and Na that originate from the fuel, sulphuric acid, elemental carbon (soot) and organic material. The majority of particles were formed at high temperature (>800 °C) from V, Ni, Fe and Na. At the flue gas dew point (125 °C in undiluted flue gas) sulphuric acid condensed forming a liquid layer on the particles. This increases the PM1 substantially and may lead to partial dissolution of the metallic cores.Wood-fired grate boilers had 6–21-fold PM1 and 2–23-fold total suspended particle (TSP) concentrations upstream of the particle filters when compared to those of HFO-fired boilers. However, the use of single field electrostatic precipitators (ESP) in wood-fired grate boilers decreased particle emissions to same level or even lower as in HFO combustion. On the other hand, particles released from the HFO boilers were clearly smaller and higher in number concentration than those of wood boilers with ESPs. In addition, in contrast to wood combustion, HFO boilers produce notable SO₂ emissions that contribute to secondary particle formation in the atmosphere. Due to vast differences in concentrations of gaseous and particle emissions and in the physical and chemical properties of the particles, HFO and wood fuel based energy production units are likely to have very different effects on health and climate.     

DNA damage in workers exposed to formaldehyde at concentrations below occupational exposure limits

Formaldehyde has been classified in group 1 as a potential source of human carcinogen by the International Agency for Research on Cancer. In this study, we evaluated the DNA damage in workers who were occupationally exposed to formaldehyde during the manufacture of melamine dinnerware.

Age, sex, smoking habits, and socioeconomic status were matched by the controls (n = 34) of workers not occupationally exposed to formaldehyde. The median value of formaldehyde time weighted average exposure in three workshops was 0.086 mg/m³. No significant difference was observed between sex and smoking habit in the assessed workers. Alkaline comet assay of peripheral blood lymphocytes was used to determine the DNA damage in the subjects. Olive moment was significantly higher in the exposed group compared with the control group.

Overall, the results suggest that respiratory exposure to low concentrations of formaldehyde causes DNA damage in peripheral blood lymphocyte. Therefore, exposure to formaldehyde should be reduced to the lowest possible level.     

Management of old landfills by utilizing forest and energy industry waste flows

The lack of landfill capacity, forthcoming EU waste disposal and landfill management legislation and the use of non-renewable and energy intensive natural resources for the end-treatment of old landfills increase pressures to develop new landfill management methods. This paper considers a method for the end-management of old landfills in Finland, which is based on the utilization of forest and paper industry waste flows, wastes from paper recycling (de-inking) and wastes from forest industry energy production. Fibre clay wastes from paper mills, de-inking sludges from de-inking of recovered waste paper and incineration ash from forest industry power plants serve to substitute the use of natural clay for the building of landfill structures for closed landfills. Arguably, this method is preferable to existing practices of natural clay use for landfill building, because it (1) substitutes non-renewable natural clay, (2) consumes less energy and generates less CO2 emissions than the use of natural clay, and (3) eliminates considerable amounts of wastes from paper production, paper consumption and from forest industry energy production. Some difficulties in the application of the method are considered and the waste flow utilization is incorporated into a local forest industry recycling network.     

Industrial ecosystem evolution of North Karelia heating energy system

Within the emerging concept of industrial ecology (IE) that belongs to the research and practical field of sustainable development (SD), the natural ecosystem evolution over time has been described as a metaphor that presents systems of type I, type II and type III ecology. Type I describes a situation when there was little life on earth and plenty of resources. In type II, the ecosystem starts to develop material cycles and energy cascades between organisms and species due to increasing amount of life and emerging scarcity of resources. In type III, the mature ecosystem stage, the system actors have developed nearly completely cyclic flows of matter, energy cascades and diverse interdependencies between them. This paper uses the metaphor in the three systems to develop practical models of type I, II and III industrial ecosystems for an economic system of heating energy and its evolution over time. First, the physical flows of matter and energy are described by using two contrasting case system characteristics, 'throughput' and 'roundput'. Throughput means linear material and energy flows. Roundput means material cycles, energy cascades and sustainable use of renewables, i.e., ecosystem type III. Second, the more structural and organisational features are considered with the characteristic of 'diversity' meaning diversity in resources, human involvement and economic actors and technology used. The case system development over time shown with our practical model of type I–III is radically different from the ecosystem evolution as described in the literature on the industrial ecosystem metaphor of type I–III. This conclusion as a research result, however, is tentative, because of the fuzzy and vague meaning assigned to a metaphor and its confusion with a practical model of industrial development in the industrial ecology literature.     

Two Paths to Industrial Ecology: Applying the Product-based and Geographical Approaches

The development of the practical side of the concept of industrial ecology has taken two different but interrelated paths during the last two decades: the product-based systems perspective; and the geographically defined local-regional industrial ecosystem approach. Both approaches focus on material and energy flows aiming at reducing the industrial system's virgin resource use and waste and emission outputs. The ideal has arisen to mimic the model of a sustainable natural ecosystem, which relies solely on solar energy as the input and creates cyclical flows of materials (and related energy cascades) between organisms and in the food chain. It is argued in the industrial ecology literature that wastes, as defined in human industrial system terms, are non-existent in the natural recycling system. In this paper, an application of the product-based systems approach is given with paper life cycles and a basic life cycle inventory model. An application to the regional approach is presented in the regional energy supply system of the city of Jyväskylä in Finland. The paper aims at discussing the two approaches in industrial ecology and considers their contradictory characteristics as well as their similarities. When the basic vision and the overriding goal is the local industrial ecosystem, the product-based approach can serve as an inventory tool to support the project. In this situation, the two approaches would seem to be each other's complement. When the two approaches are adopted as each other's substitute, they may support conflicting decisions for environmental policy and management. This may create difficulties in the implementation of industrial ecology. On the basis of both of the approaches to industrial ecology, the external environment of an organization is considered to comprise the societal material and energy flow environment and the natural material and energy flow environment .     

Quantifying sources of climate uncertainty to inform risk analysis for climate change decision-making

Quantitative estimates of future climate change and its various impacts are often based on complex climate models which incorporate a number of physical processes. As these models continue to become more sophisticated, it is commonly assumed that the latest generation of climate models will provide us with better estimates of climate change. Here, we quantify the uncertainty in future climate change projections using two multi-model ensembles of climate model simulations and divide it into different components: internal, scenario and model. The contributions of these sources of uncertainty changes as a function of variable, temporal and spatial scale and especially lead time in the future. In the new models, uncertainty intervals for each of the components have increased. For temperature, importance of scenario uncertainty is the largest over low latitudes and increases nonlinearly after the mid-century. It has a small importance for precipitation simulations on all time scales, which hampers estimating the effect which any mitigation efforts might have. In line with current state-of-the-art adaptation approaches, we argue that despite these uncertainties climate models can provide useful information to support adaptation decision-making. Moreover, adaptation decisions should not be postponed in the hope that future improved scientific understanding will result in more accurate predictions of future climate change. Such simulations might not become available. On the contrary, while planning adaptation initiatives, a rational framework for decision-making under uncertainty should be employed. We suggest that there is an urgent need for continued development and use of improved risk analysis methods for climate change adaptation.     

Female encounter rates and fighting costs of males are associated with lek size in Drosophila mycetophaga

Male costs and benefits associated with male display size in field populations of an Australian lekking Drosophila species were examined. Results suggested that male mating success increased with display size, since matings appeared to be more common in large displays, and since the probability of males encountering a female increased as displays contained more males. Female encounter probabilities did not increase once about 20 males or more were present on a display. Male size and fighting costs tended to increase with display size. The distribution of males among displays did not follow the ideal free distribution in the sense that each male did not have equal mating opportunity per unit time. Deviation from an ideal free distribution may have been due to female preference for mating in aggregations rather than with solitary males, since in a field experiment females were more willing for mating in an aggregation of five males than with solitary males. Received: 22 May 1997 / Accepted after revision: 1 November 1997     

Enchytraeid population dynamics: Resource limitation and size-dependent mortality

Enchytraeids are regarded as keystone soil organisms in forest ecosystems. Their abundance and biomass fluctuate widely. Predicting the consequences of anthropogenic disturbances requires an understanding of the mechanisms underlying enchytraeid population dynamics. Here I develop a simple model, which predicts that the type of dynamics is controlled by resource input rate. If fungal resource input is a discrete event once a year, an exponential growth phase is followed by starvation and sharp decline of enchytraeid abundance. Model simulations with three different forcing functions were compared to field data. Initial parameter values were obtained from various independent sources, and parameters were estimated by minimizing the residual sum of squares. The best fitting model with resource addition once a year explained 39% of the variation in enchytraeid biomass over an 8-year study period. Further, variation in rainfall explained 59% of the variation in R² of the exponential phase models, which is also an index of the stability of population size-structure. The results emphasize the importance of resource limitation for enchytraeid population dynamics and support the hypothesis that the mortality during the decline phase is size-dependent.