Experiments on vertical transverse mixing in a large-scale heterogeneous model aquifer

Vertical transverse mixing is known to be a controlling factor in natural attenuation of extended biodegradable plumes originating from continuously emitting sources. We perform conservative and reactive tracer tests in a quasi two-dimensional 14 m long sand box in order to quantify vertical mixing in heterogeneous media. The filling mimics natural sediments including a distribution of different hydro-facies, made of different sand mixtures, and micro-structures within the sand lenses. We quantify the concentration distribution of the conservative tracer by the analysis of digital images taken at steady state during the tracer-dye experiment. Heterogeneity causes plume meandering, leading to distorted concentration profiles. Without knowledge about the velocity distribution, it is not possible to determine meaningful vertical dispersion coefficients from the concentration profiles. Using the stream-line pattern resulting from an inverse model of previous experiments in the sand box, we can correct for the plume meandering. The resulting vertical dispersion coefficient is approximately approximately 4 x 10(-)(9) m(2)/s. We observe no distinct increase in the vertical dispersion coefficient with increasing travel distance, indicating that heterogeneity has hardly any impact on vertical transverse mixing. In the reactive tracer test, we continuously inject an alkaline solution over a certain height into the domain that is occupied otherwise by an acidic solution. The outline of the alkaline plume is visualized by adding a pH indicator into both solutions. From the height and length of the reactive plume, we estimate a transverse dispersion coefficient of approximately 3 x 10(-)(9) m(2)/s. Overall, the vertical transverse dispersion coefficients are less than an order of magnitude larger than pore diffusion coefficients and hardly increase due to heterogeneity. Thus, we conclude for the assessment of natural attenuation that reactive plumes might become very large if they are controlled by vertical dispersive mixing.     

Indoor pollutant mixing time in an isothermal closed room: an investigation using CFD

We report on computational fluid dynamics (CFD) predictions of mixing time of a pollutant in an unventilated, mechanically mixed, isothermal room. The study aims to determine: (1) the adequacy of the standard Reynolds Averaged Navier Stokes two-equation (k−) turbulence model for predicting the mixing time under these conditions and (2) the extent to which the mixing time depends on the room airflow, rather than the source location within the room. The CFD simulations modeled the 12 mixing time experiments performed by Drescher et al. (Indoor Air 5 (1995) 204) using a point pulse release in an isothermal, sealed room mechanically mixed with variable power blowers. Predictions of mixing time were found in good agreement with experimental measurements, over an order of magnitude variation in blower power. Additional CFD simulations were performed to investigate the relation between pollutant mixing time and source location. Seventeen source locations and five blower configurations were investigated. Results clearly show large dependence of the mixing time on the room airflow, with some dependence on source location. We further explore dependence of mixing time on the velocity and turbulence intensity at the source location. Implications for positioning air-toxic sensors in rooms are briefly discussed.     

Quality standard codes of reference of Jordanian coastal waters of the Gulf of Aqaba,Red Sea

Back in 1992, the Gulf of Aqaba Environmental Action Plan (GAEAP), a collaboration between the Aqaba Region Authority (ARA), Jordan and the World Bank, gave considerable emphasis to the environmental protection of the Gulf of Aqaba [The World Bank. Gulf of Aqaba Environmental Action Plan. Report No. 12244JO (1993).]. The document recommended the establishment of a marine reserve and the long term monitoring of the coastal habitats’ environmental quality. The combination of a dedicated follow up, the collaborative efforts of ARA and the Marine Science Station (MSS), and the founding of the Aqaba Special Economic Zone Authority (ASEZA) have turned the recommendations into reality. A comprehensive monitoring program of the Jordanian coastal habitats commenced in 1999. The first three years of the program were financed by a donation from The Global Environmental Facility (GEF). In return, Jordan has committed itself to the maintenance of the monitoring program as an ongoing tool for sustainable coastal management. The monitoring program includes observations on benthic habitat, fish communities, bottom sediments and seawater quality. This paper focuses on the results of seawater-quality monitoring in the first three years. Records of weather conditions, coastal currents, seawater temperature, transparency, salinity, density, pH, alkalinity, dissolved oxygen, ammonia, nitrate, nitrite, phosphate, silicate, particulate matter, chlorophyll a, zooplankton biomass, total coliform, fecal coliform, hydrocarbons and sedimentation rate have been generated monthly since January 1999 at six coastal stations, and one offshore reference station, in the Jordanian waters of the Gulf of Aqaba. The coastal stations are located at sites with different benthic habitats and are occupied by different human activities. Offshore records of density (thermohaline structure), nutrients and chlorophyll a depicted two well-defined seasons; a nutrient-/chlorophyll a-rich, mixed water winter from December to April and a nutrient-/chlorophyll a-poor, stratified water summer from June to October. Short transition seasons appeared in May and November. The mixing and stratification seasons were also clearly depicted in the coastal waters. Statistical analysis of the three-year data collected at the offshore station revealed no significant inter-annual differences in the upper 125 m of the water column with respect to any of the measured parameters. At coastal stations, the water quality at the two northernmost stations was significantly different in comparison to the upper 125 m at the offshore station and to the other coastal stations, with respect to the two key indicator parameters: inorganic nitrogen and chlorophyll a. The three-year findings of the monitoring program are employed to suggest standard codes of reference for the coastal water quality.     

Air Pollution Potential: Regional Study in Argentina

/ Air pollution potential is a measure of the atmospheric conditions that are unable to transport and dilute pollutants into the air, independently of the existence of sources. This potential can be determined from two atmospheric parameters: mixing height and transport wind. In this paper a statistical analysis of the mixing height and transport wind, in order to determine the areas with high or poor atmospheric ventilation in Argentina, is presented. In order to achieve this, meteorological data registered during 1979-1982 at eight meteorological stations were used. Daily values of the maximum mixing height were calculated from observations of daily temperatures at different heights and maximum surface temperature. At the same time as the maximum mixing height, the values of the transport wind were determined from the surface windspeed and the characteristics of the ground in the surroundings of each meteorological station. The mean seasonal values for both parameters were obtained. Isopleths of the mean seasonal of the maximum mixing heights were drawn. The percentage of seasonal frequencies of poor ventilation conditions were calculated and the frequency isopleths were also drawn to determine areas with minor and major relative frequencies. It was found that the northeastern and central-eastern regions of Argentina had a high air pollution potential during the whole year. Unfavorable atmospheric ventilation conditions were also found in the central-western side of the country during the cold seasons (37.5% in autumn and 56.9% in winter). The region with the greatest atmospheric ventilation is located south of 40 degrees S, where the frequency of poor ventilation varies between 8.0% in summer and 10.8% in winter.     

Choice of dispersion coefficients in reactive transport calculations on smoothed fields

Local dispersion dominates the mixing of compounds that are introduced separately into the subsurface and do not partition into any other than the aqueous phase. Thus, reactions between these compounds are controlled by dispersive mixing if they are not limited by kinetics. I quantify longitudinal dispersive mixing by the longitudinal effective dispersion coefficient of a conservative tracer introduced by a point-like injection [Water Resour. Res. 36 (12) (2000) 3591-3604]. In the upscaling of mixing-controlled reactive transport, I apply the mean velocity and the effective dispersion coefficient to the macroscopic transport calculations, whereas the reactive parameters on the macro-scale are identical to those on the local scale. The applicability of the approach is demonstrated for the transport of compounds undergoing a second-order irreversible bimolecular reaction. Ten realizations of a two-dimensional heterogeneous log-conductivity field are considered. Using the effective dispersion parameters, the overall mass balance is met in the ensemble average, whereas solute spreading is underestimated. I assess the lack of spreading by the difference between the expected macrodispersion and effective dispersion coefficients. I extend the approach to simulations on log-conductivity fields obtained by kriging of regularly spaced conductivity measurements. These fields contain the large-scale features of the true fields but do not resolve the small-scale variability. For the calculations on the kriged fields, the corresponding conditional covariance is substituted into the analytical expressions of effective dispersion, yielding a correction effective dispersion coefficient. The comparison between simulations on the fully resolved fields and on the kriged fields indicates that the approach is valid for wide plumes meeting the ergodicity condition. The high variability of mixing on small scales unresolved by kriging, however, leads to severe uncertainty when mixing-controlled reactions are predicted for narrow plumes.     

Study on the effect of landfill leachate on nutrient removal from municipal wastewater

In this study, landfill leachate with and without pre-treatment was co-treated with municipal wastewater at different mixing ratios. The leachate pre-treatment was achieved by air stripping to removal ammonia. The objective of this study was to investigate the effect of landfill leachate on nutrient removal of the wastewater treatment process. It was demonstrated that when landfill leachate was co-treated with municipal wastewater, the high ammonia concentration in the leachate did not have a negative impact on the nitrification. The system was able to adapt to the environment and was able to improve nitrification capacity. The readily biodegradable portion of chemical oxygen demand (COD) in the leachate was utilized by the system to improve phosphorus and nitrate removal. However, this portion was small and majority of the COD ended up in the effluent thereby decreased the quality of the effluent. The study showed that the 2.5% mixing ratio of leachate with wastewater improved the overall biological nutrient removal process of the system without compromising the COD removal efficiency.     

Integrating selected ecological effects of mixed European beech–Norway spruce stands in bioeconomic modelling

The simplicity of many bioeconomic models has been criticised several times, due to their lack of realism resulting from a deterministic nature and a single-species focus. In this context it was interesting to test the financial sensitivity of bioeconomic modelling against fairly well documented ecological effects in mixed forests. For this purpose our study linked existing results of ecological research with bioeconomic modelling. The presented methodological approach could not only show the importance of considering ecological effects in bioeconomic models; it in fact enabled prioritising ecological research from a financial point of view.In a first step, the possible influence of the tree species mixture on forest stand resistance, productivity and timber quality was derived from existing studies. In a second step, the available Monte Carlo simulations for Norway spruce (Picea abies [L.] Karst.) and European beech (Fagus sylvatica L.), simulated under site conditions and risks typical of southern Germany, were extended by the mentioned ecological effects and then evaluated from a financial perspective.The results showed a clear influence of all tested ecological effects on the financial indicators, financial risk and return. While testing each ecological effect separately, an increased resistance against wind, snow and insect attacks had the greatest influence on financial risk and return. It over-proportionally enhanced the financial return while simultaneously the financial risk was reduced. In contrast, a degraded timber quality could eliminate the positive effect of risk compensation in mixed forests almost completely. The least influence on the financial indicators finally showed a changed volume growth in mixed forests.A combination of the separately tested ecological effects (increased resistance, changed volume growth and decreased timber quality), between both tree species, underlined the dominating importance of the stand resistance. The integration of ecological effects, induced by interdependent tree species, in our bioeconomic model resulted in significantly lower financial risk than ignoring these effects. Moreover, the financial return of mixed stand variants with a proportion of Norway spruce greater than 60% even exceeded that of the most profitable pure stand.In conclusion this paper clearly confirmed that ignoring ecological effects in bioeconomic models could lead to seriously biased financial results. While a changed volume growth proved rather to be of minor importance for European beech/Norway spruce stands, tree resistance and timber quality may change the financial results significantly.     

Enhanced mixing state of black carbon with nitrate in single particles during haze periods in Zhengzhou, China

Black carbon（BC） plays an important role in air quality and climate change, which is closely associated with its mixing state and chemical compositions. In this work the mixing state of BC-containing single particles was investigated to explore the evolution process of ambient BC particles using a single particle aerosol mass spectrometer（SPAMS） in March 2018 in Zhengzhou, China. The BC-containing particles accounted for 61.4% of total detected ambient single particles and were classified into f...     

Investigation of an accidental explosion due to unintended mixing involving reactive chemicals at a waste storage tank

An accidental explosion occurred in a waste storage tank at an incineration plant in Kawasaki, Japan, on May 11, 1997. The accident was caused primarily by unintended mixing involving reactive chemicals, such as organic peroxides (POs) and acrylonitrile (AN). The PO initiated polymerization of AN and the heat released during the polymerization led to a runaway reaction and explosion. POs are widely used in the chemical industry and can be self-reactive and hazardous when mixed with other chemicals such as acids and alkalis. The goal of this study was to obtain a better understanding of the mixing hazard of chemicals through an evaluation of POs with other chemicals using conventional experimental techniques such as glass test-tube tests, Dewar vessel tests, and differential scanning calorimetry (DSC). Seven types of POs were mixed with AN. Test results were classified into four ranks based on the hazard criteria. In addition, di(2-ethylhexyl)-peroxydicarbonate/AN mixtures were investigated in detail and the influences of the mixing ratio and the stirring rate were examined.     

楼梯井内烟囱效应对着火房间燃烧和溢出烟气的影响研究

实验研究了楼梯井内的烟囱效应对着火房间燃烧速率、补风速度、羽流温度等的影响.实验在一个模拟尺寸的十二层的楼梯井实验台内进行,实验时开启楼梯井顶层直通室外门.火灾时楼梯井内的烟囱效应加速了空气在楼梯井内的对流,使火源区从外界单侧卷吸空气,形成着火房间单侧强补风下的燃烧,燃烧速率比开放空间下的燃烧快,同时使得火焰向前室一侧倾斜,出现火焰"分岔"现象.与火源位于一层的工况相比,当火源位于六层,且首层门开启时,楼梯井内下部空气向上部烟气的掺混较大,着火房间门口进风速度减小,羽流的倾斜角度变小,温度较高,而当首层门关闭时,则减小了楼梯井下部空气与上部烟气的掺混,使得楼梯井内的上部烟气温度较高.