环糊精对苯砜基乙酸酯的增溶作用及QSPR研究

以10种苯砜基乙酸酯化合物为对象,测定了β-环糊精(β-CD)对该类化合物的增溶作用效应;并应用K_ow和电性拓扑态指数对包合物稳定常数(Ks)进行了模拟分析,构建了QSPR模型.模型的相关系数(R²_adj)和标准偏差(SD)分别为0.972、0.971和0.057、0.059,模型具有较高的预测能力和可靠性.研究表明,β-CD与该类化合物形成1:1包合物,增加了苯砜基乙酸酯类化合物的水溶性;包合物形成类似于化合物在辛醇相和水相之间的分配,CD腔体内高能水分子的释放、化合物苯基与CD腔体间的范德华相互作用及砜基氧原子和CD端口羟基的氢键作用是包合物稳定性的决定因素.     

The impact of workplace exclusion on the humanitarian response to the refugee crisis in Lebanon

A contemporary issue of major concern is the millions of people fleeing homelands owing to political and socioeconomic challenges and seeking assistance elsewhere throughout the world. An effective response to this crisis includes support models that meet the various needs of refugee populations. In the complex system of humanitarian action, aid workers, among a multiplicity of actors, are the most important assets. This study utilised an inclusion–exclusion theoretical lens to examine the impact of their workplace experiences on activities in the context of the refugee crisis in Lebanon. In-depth interviews were held with 36 humanitarian practitioners, representing five international organisations that are involved in refugee aid programmes in the country. The study led to a new understanding of the link between inclusion and exclusion and the effectiveness of the humanitarian response to emergencies. In addition, it yielded new insights into apprehension about the national–international divide and its consequences for humanitarian assistance.     

Marginal recycling: place and informal recycling in St. John's,Newfoundland

Informal recycling networks are systems through which impoverished populations earn money and residents recycle waste which might otherwise go into a landfill. These networks, in which people voluntarily self-organise to collect recyclables, occur throughout the world. This article discusses results of an exploratory, qualitative study of one such network in St. John's, Newfoundland and Labrador which identifies motivational characteristics of the network and their implications for public policy. Through close attention to particularities of place, the research identified community interaction and community inclusion as two of the most active motivating factors within the studied network. The findings suggest public recycling programmes can increase public participation through greater attention to place-based motivational factors. Such participation could contribute to increased sustainability and reach of recycling programmes.     

Making space for social inclusion in conceptualising climate change vulnerability

Impacts from climate change pose a raft of challenges for societies, governments and policy-makers internationally. The anticipated changes are well documented, including rising sea levels, increased floods and other extreme weather conditions. Much research and policy emphasis has focused on technical and economic aspects. Less debated are questions about different communities' vulnerabilities, inequitable distributional impacts, social justice issues and how vulnerability links to social inclusion/exclusion. This paper explores a case study mapping social exclusion and vulnerability in Brisbane, Queensland, which found that while communities can be vulnerable through physical aspects of an area when social dimensions are added to the equation it amplifies or exacerbates the scale of vulnerability. The findings also suggest that in developing research agendas and policy debates around climate change, there could be benefits from interlinking the currently separate areas of work on social vulnerability to extreme weather events, to forms and processes of social inclusion/exclusion.     

山东沂南金矿床流体包裹体特征及地质意义

本文从流体包裹体出发,讨论了沂南金矿床的成矿物质来源和成矿机制。各成矿阶段的矽卡岩矿物、石英和方解石中流体包裹体岩相学和显微测温研究结果表明,包裹体主要类型有气液水包裹体、含子矿物多相包裹体、CO2-H2O包裹体和晶质熔体包裹体,其中熔体包裹体在较早期的石榴石、绿帘石和石英中发育。Ⅰ、Ⅱ成矿阶段的成矿流体具有高温和高盐度的特征,均一温度分别为430~520℃、340~430℃,盐度分别为56.7 wt%NaCl2、2.2~53.5 wt%NaCl,代表铁矿化时的流体特征;Ⅲ成矿阶段流体具有中低温(190~250℃)、盐度范围变化较大(6.45~53.5 wt%NaCl)的特征,代表了Cu,Au矿化时的流体活动情况;Ⅳ成矿阶段包裹体均一温度100~190℃,盐度为2.07~15.76 wt%NaCl。根据不同类型包裹体共生组合及流体演化特征,认为流体的不混溶性是导致大量金属沉淀的主要原因,岩浆热液在成矿流体中占主导地位。     

The misleading of public participation in environmental assessment – exploring four infrastructure cases in Denmark

The article analyses the recent development of public participation in environmental assessment and indicates some unfortunate and unintended results. A number of Danish cases show how the tools involved are employed for a kind of ‘acceptance planning’, instead of actual environmental protection, and that the legitimacy which public inclusion was supposed to bring to environmental assessment has instead been replaced by considerations of legality, which frees entrepreneurs and authorities from including real environmental considerations in their planning. Thus, the undesirable handling of public participation that the article analyses is not only due to the actual difficulties of practising inclusion and the indisputable complexity of the environmental issues but also to a very large extent due to considerations of economic efficiency and an unwillingness among investors – public as well as private – to take account of environmental consequences as a long-term issue. The article ends with a range of recommendations for securing public inclusion in matters of environmental assessment through independent public initiatives or institutions that do not answer to authorities and entrepreneurs.     

Dilemmas and advances in corporate social responsibility in Brazil. The work of the Ethos Institute

This article discusses the development of corporate social responsibility (CSR) in Brazil from the perspective of the Ethos Institute of Business and Social Responsibility. The Institute is a not‐for‐profit, non‐governmental organization, that has played a leading role in the Brazilian CSR effort. In Brazil, CSR initiatives have a long tradition of philanthropy, a consequence of the country's great social inequalities. The increased attention to corporate social responsibility has paralleled growing concern about sustainable development and the intensifying activities of pressure groups (consumers, customers, investors, NGOs, labour unions, the media, among others) that have been increasing since the 1990s as natural resources are progressively becoming exhausted, social tensions rising and environmental conditions deteriorating worldwide. This article identifies problems and obstacles to the growth of corporate social responsibility in Brazil, as well as advances and alternatives for CSR and towards creating conditions for the country to be internationally competitive and sustainable in the financial, social and environmental areas.     

安徽铜陵鸡冠石银(金)矿床地质地球化学特征

鸡冠石银 (金 )矿床是铜陵地区一个具中型规模的银 (金 )矿床 ,在整个长江中、下游地区都有其代表性。矿床分四个主要成矿阶段 :夕卡岩阶段、氧化物 -硫化物阶段、石英 -硫化物阶段和石英多金属硫化物-碳酸盐阶段。对矿床的微量元素分析结果表明 ,独立的银、金矿物和含Au、Ag低的硫化物、含Ag硫盐矿物 ,主要形成于热液成矿期中晚阶段 ;矿床的轻、重稀土元素总浓度比值与辉石二长闪长岩相近 ,反映出二者的同源特征 ;稳定同位素和流体包裹体成分分析结果 ,反映出该矿床以岩浆热液为主的成因标志 ;成矿热液以岩浆水为主 ,但在成矿晚期有大气降水和地层成分加入 ;成矿流体为NaCl-KCl -H2 O体系 ;矿床成因属夕卡岩 -中低温热液充填 -交代型矿床     

苏胶地体榴辉岩相岩石中流体包裹体的初步研究

高压低温变质岩的流体包裹体研究程度很低。本文选择苏胶地体四个有代表性的榴辉岩相岩石：蓝晶石英钟榴辉岩、石英榴辉岩、蓝晶石石英岩和绿帘石石英脉作了初步研究。研究结果表明：各类榴辉岩相岩石的流体包裹体均程度不同地发生了次生变化．未发现原生包裹体。蓝晶石榴辉岩中的石英包裹体表现为变质峰期的流体成分特征：均—温度较高、冰点相对较低、成分复杂多样，具深源特征；而其它样品则代表退变质阶段之产物：成分简单、盐度较小，且不含碳质包裹体。     

湖南锡矿山地区云斜煌斑岩及其花岗岩包体的意义

湖南锡矿山地区云斜煌斑岩是属碱钙性系列的基性岩脉,其在上侵时捕获了石灰岩包体而发生局部同化混杂,致使煌斑岩褪色蚀变。同时,对岩石包体特征、黑云母与锆石年代,Pb同位素与稀土元素的研究表明,锡矿山深部有隐伏花岗岩体存在,而云斜煌斑岩是在花岗岩浆尚未完全固结时上侵,形成于成矿期末或成矿后;该煌斑岩不是地幔岩浆分异产物,而是中元古代地壳重熔形成的。据推断,在中生代该地区深部有一次较大地质热事件,并对成岩、成矿发生了直接影响。