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Eleven surface sediment samples, from Hangzhou section of Qiantang River and Jinghang Canal, west Lake the inland river were collected to investigate 17 polycycUc aromatic hydrocarbons(PAHs) pollution in aquatic sediments of Hangzhou. Accelerated solvent extraction(ASE) was used to extract PAHs from sediments with satisfactory recoveries. It was found that the total PAHs in the sediments ranged from 308.4 to 3037 ng/g dw, and PAHs pollution in sediments from Jinghang Canal were the heaviest. Lowest effect level(LEL) and severe effect level (SEL) sediment quality guidelines were introduced to perform risk assessment for PAHs pollution in aquatic sediments. Only one sample in Jinghang Canal had adverse impact on benthic organism. 2-3 ring PAHs had a noticeable contribution to total PAHs, especially NA, PHEN. A quantity method was used to determine the major source, the results showed petroleum origin was the chief source to PAHs pollution in all sediments with the exception of sediments from Jinghang Canal where combustion sources had a larger contribution. 相似文献
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应用等温吸附法研究京杭大运河苏南三城市段(常州、苏州和无锡)表层沉积物对Cu和Zn的吸附行为,并结合国家地表水环境质量标准(GB3838—2002),估算运河城市段表层沉积物对Cu和Zn的理论环境安全吸附容量(QⅢ)。结果表明:大运河表层沉积物的Cu和Zn等温吸附符合Langmuir模型;表层沉积物Cu最大吸附量(Cu-Qmax)为5.20~9.03 mg·g-1,Zn最大吸附量(Zn-Qmax)为2.40~5.07 mg·g-1;最大吸附量与沉积物的性质密切相关,但与总有机碳质量分数无关。根据Langmuir拟合方程估算,在我国地表水环境质量标准三类水标准阈值时,Cu的理论环境安全吸附容量为沉积物总Cu量的19倍以上,而Zn则为2~6倍。因此,Zn对三城市段大运河沉积物的环境风险要高于Cu。 相似文献