一种适合我国国情的烟气脱硫技术--荷电干式吸收剂喷射脱硫系统(CDSI)

介绍目前我国的几种主要脱硫技术,并且在脱硫率、工程投资、占地等方面进行一些简单的比较,并着重介绍荷电干式吸收剂喷射脱硫系统的基本工作原理及其在应用上的主要优点.     

Ca5（AsO4）3OH的溶解度与稳定性研究

通过在不同pH值,温度等条件下Ca5（AsO4）3OH的溶解,确定其稳定存在的pH值范围,得出它的溶度积和生成的自由能（ΔG0f）。结果表明,Ca5（AsO4）3OH在水中的溶解度和稳定范围与pH和温度有关,在酸性条件下（初始pH=2）它的溶解度较大,而且在水中的溶解度随着温度的升高而降低。利用PHREEQC程序计算确定Ca5（AsO4）3OH的溶度积为10-40.86,生成自由能ΔG0f为-5 063.53 kJ/mol。利用JADE5软件计算得到其晶格参数a=b=9.696,c=6.967和晶胞体积为567.304 3。     

K-Ca-Mg-Cl-H2O体系中硫酸钙结晶介稳区的研究

对K-Ca-Mg-Cl-H2O体系中硫酸钙结晶介稳区进行了研究.以一定浓度氯化钙溶液与硫酸镁溶液反应结晶的方式,采用激光散射法测定了不同浓度复合盐溶液和温度下硫酸钙过饱和度与结晶之间的关系,并测定了与之平衡的溶解度,从而确定该体系中硫酸钙结晶介稳区宽度,探讨了影响结晶介稳区的因素,以及硫酸钙结晶和结晶相与复合盐溶液浓度...     

混合胺MEA＋DETA吸收CO2的影响因素

以MEA为主体，DETA为添加剂，考察1h内，在温度298～338K，压力300～700kPa，混合胺溶液初始浓度（质量分数）4％～20％范围内，MEA＋DETA不同配比的混合吸收剂吸收CO2的特性。获得MEA＋DETA混合胺吸收CO2的最佳吸收条件为：308K、500kPa、总胺质量浓度为20％，MEA与DETA的配比为8：2。     

贵阳市小车河“白水”现象的初步分析

通过对小车河从阿哈水库大坝取水口至南明河入口段采集的水样进行p H值、温度及主要离子浓度测定分析,研究该段水体的水化学特征,并从溶解度方面初步分析,发现小车河"白水"现象是由于水中Ca2+浓度过高,使水体形成过饱和的Ca SO4和Ca CO3水溶液,析出大量白色Ca SO4和Ca CO3颗粒,与河水形成溶胶导致。     

一种批量制备药物共晶的新方法——高速气流法

药物共晶能改善药物物理化学特性、提高药效,机械化学合成法作为一种高效、绿色的合成法在药物共晶合成中得到了广泛应用。首次应用与传统机械法不同的高速气流对撞法批量制备了4种茶碱药物共晶(每种290~320 g),并采用红外光谱(FT-IR)、X射线衍射(XRD)、差热分析(DTA)、扫描电子显微镜(SEM)对4种药物共晶进行了表征。此外,测定了药物共晶的溶解度,结果表明,4种药物共晶在30℃磷酸盐缓冲溶液(pH=7.4)中的溶解度较茶碱显著提高。     

一起夹套式结晶罐失稳的原因分析及处理

制药厂常用夹套容器作为结晶罐，罐内待结晶的物料在搅拌器作用下，通过往夹套内加入冷冻介质(往往是冷冻盐水)，使罐内物料温度下降。溶解度也下降，从而加快结晶速度，提高生产效率。     

β-Cyclodextrin and its derivatives-enhanced solubility and biodegradation of 2-nitrobiphenyl

This paper investigated the effects of β-cyclodextrins （I3-CD） and its two derivatives, hydroxypropyl-β-cyclodextrin （HPCD） and carboxymethyl-β-cyclodextrin （CMCD）, on the solubility and biodegradation of 2-nitrophenyl by an A cinetbacter sp. Results showed that β-CD, HPCD and CMCD could not be utilized by A cinetbacter sp. as sole carbon source and none of the CDs had toxic effects on the growth of the bacteria in the experiments; all the CDs could enhance the apparent solubility and accelerate the biodegradation of 2-nitrobipheny. It showed that biodegradation-accelerating effects of CDs on 2-nitrobiphenyl were correlated with their solubility-enhancing effects. Among three CDs investigated, CMCD had the most obvious effects both on the apparent solubility and the biodegradation, followed by β-CD and HPCD.     

Fractionation and solubility of cadmium in paddy soils amended with porous hydrated calcium silicate

Previous studies have shown that porous hydrated calcium silicate （PS） is very effective in decreasing cadmium （Cd） content in brown rice. However, it is unclear whether the PS influences cadmium transformation in soil. The present study examined the effect of PS on pH, cadmium transformation and cadmium solubility in Andosol and Alluvial soil, and also compared its effects with CaCO3, acidic porous hydrated calcium silicate （APS） and silica gel. Soil cadmium was operationally fractionationed into exchangeable （Exch）, bound to carbonates （Carb）, bound to iron and manganese oxides （FeMnOx）, bound to organic matters （OM） and residual （Res） fraction. Application of PS and CaCO3 at hig rates enhanced soil pH, while APS and silica gel did not obviously change soil pH. PS and CaCO3 also increased the FeMnOx-Cd in Andosol and Carb-Cd in Alluvial soil, thus reducing the Exch-Cd in the tested soils. However, PS was less effective than CaCO3 at the same application rate. Cadmium fractions in the two soils were not changed by the treatments of APS and silica gel. There were no obvious differences in the solubility of cadmium in soils treated with PS, APS, silica gel and CaCO3 except Andosol treated 2.0% CaCO3 at the same pH of soil-CaC12 suspensions. These findings suggested that the decrease of cadmium availability in soil was mainly attributed to the increase of soil pH caused by PS.     

影响海水石油烃溶解度的各种因素研究

本文用实验室模拟的方法研究了海水中石油烃-正烷烃的溶解特征。测定了在不同盐度、温度,pH和不同浓度的脂肪酸、腐殖酸条件下海水中石油烃的组成和浓度,考查了某些环境因素对石油溶解过程的影呵和垂直扩散规律。用气相色谱法研究了三种油:O#轻柴油、15#机油和渤海原油。