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Technological improvements in automotive battery recycling 总被引:2,自引:0,他引:2
M.A. Kreusch M.J.J.S. Ponte H.A. Ponte N.M.S. Kaminari C.E.B. Marino V. Mymrin 《Resources, Conservation and Recycling》2007,52(2):368-380
Recycling of automotive batteries for the recovery of secondary lead is extremely important in Brazil, for the country does not possess large reserves of this metal. Lead is one of the most widely used metals in the world, but it is highly toxic, posing risks for humans and for the environment if not utilized or treated adequately. Industrial waste containing lead in Brazil are classified by the Brazilian Residue Code (NBR—10004:2004) as hazardous. The lead recycling process employed by the recycling industry in Brazil is the pyrometallurgical process in a rotary furnace. This process consists of four stages: (1) grinding of the battery to separate plastic, electrolyte and lead plates; (2) lead reduction in a rotary furnace; (3) separation of metallic lead from slag; and (4) refining of recycled lead. The purpose of this work is to propose process improvements aimed primarily at increasing production output by reducing the loss of lead in slag and particulates, thereby providing a healthier work environment in line with Brazilian environmental and labor laws. 相似文献
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不同条件下高炉渣吸附水中无机磷的研究 总被引:2,自引:1,他引:1
高炉渣(BFS)是在冶炼生铁过程中产生的固体废弃物,开展高炉渣的资源化研究具有重要意义.为了对水淬高炉渣净化含磷污水的应用提供理论依据,采取等温吸附的实验方法,比较了不同水淬炉渣的吸附磷效果,研究了不同pH和不同温度下水淬炉渣吸附磷的特点,结果如下:利用Langmuir等温吸附方程炉渣吸附磷的过程进行拟合,其相关系数均能达到显著水平.炉渣的碱度越高,吸附磷的效果越好;炉渣对磷的吸附能力随溶液pH的增加而降低,且初始为酸性(pH=2、4)的溶液在吸附达到平衡后pH有所上升,而初始为碱性的溶液(pH=10、12)在吸附达到平衡后pH有所下降;炉渣对磷的吸附是一个自发放热过程. 相似文献
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Removal kinetics of phosphorus through use of basic oxygen furnace slag (BOF-slag) was investigated through batch experiments. Effects of several parameters such as initial phosphorus concentration, temperature, BOF-slag size, initial pH, and BOF-slag dosage on phosphorus removal kinetics were measured in detail. It was demonstrated that the removal process of phosphorus through BOF-slag followed pseudo-first-order reaction kinetics. The apparent rate constant (kobs) significantly decreased with increasing initial phosphorus concentration, BOF-slag size, and initial pH, whereas it exhibited an opposite trend with increasing reaction temperature and BOF-slag dosage. A linear dependence of kobs on total removed phosphorus (TRP) was established with kobs = (3.51 ± 0.11) × 10− 4 × TRP. Finally, it was suggested that the Langmuir–Rideal (L–R) or Langmuir–Hinshelwood (L–H) mechanism may be used to describe the removal process of phosphorus using BOF-slag. 相似文献
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Removal kinetics of phosphorus through use of basic oxygen furnace slag(BOF-slag)was investigated through batch experiments. Effects of several parameters such as initial phosphorus concentration, temperature, BOF-slag size, initial p H, and BOF-slag dosage on phosphorus removal kinetics were measured in detail. It was demonstrated that the removal process of phosphorus through BOF-slag followed pseudo-first-order reaction kinetics. The apparent rate constant(kobs) significantly decreased with increasing initial phosphorus concentration, BOF-slag size, and initial p H, whereas it exhibited an opposite trend with increasing reaction temperature and BOF-slag dosage.A linear dependence of kobson total removed phosphorus(TRP) was established with kobs=(3.51 ± 0.11) × 10- 4× TRP. Finally, it was suggested that the Langmuir–Rideal(L–R)or Langmuir–Hinshelwood(L–H) mechanism may be used to describe the removal process of phosphorus using BOF-slag. 相似文献
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The aim of the study was to prepare a porous sound-absorbing material using steel slag and fly ash as the main raw material, with coal powder and sodium silicate used as a pore former and binder respectively. The influence of the experimental conditions such as the ratio of fly ash, sintering temperature, sintering time, and porosity regulation on the performance of the porous sound-absorbing material was investigated. The results showed that the specimens prepared by this method had high sound absorption performance and good mechanical properties, and the noise reduction coefficient and compressive strength could reach 0.50 and 6.5 MPa, respectively. The compressive strength increased when the dosage of fly ash and sintering temperature were raised. The noise reduction coefficient decreased with increasing ratio of fly ash and reducing pore former, and first increased and then decreased with the increase of sintering temperature and time. The optimum preparation conditions for the porous sound-absorbing material were a proportion of fly ash of 50% (wt.%), percentage of coal powder of 30% (wt.%), sintering temperature of 1130°C, and sintering time of 6.0 hr, which were determined by analyzing the properties of the sound-absorbing material. 相似文献
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本文在分析锰渣填埋场区渗滤液及周边水体水化学组成的基础上,运用改进的水质量指数(WQI)进行了水质评价,阐述了填埋场渗滤液对下游水体的影响过程。结果表明,研究区渗滤液pH呈中性偏酸性,EC在1 780~44 500μS/cm之间,渗滤液中NH4-N、Mn2+、Mg2+、SO2-4、NO-3的浓度较高,并呈现SO2-4Mn2+Mg2+NH+4-N的特征,并且浓度与堆存时间呈负相关性。填埋场下游水体的重金属浓度微量,但NH4-N和Mn2+浓度较高,均超过GB 3838—2002和GB/T 14848—93规定的限值,其中2014年5月份某地下水的这两个参数分别超标243倍和488倍。改进的WQI指数评价结果显示,地表水的渗滤液水污染指数(LWPI)值在2.89~7.83之间,受影响的地下水为172,说明渗滤液已对锰渣填埋场下游水体造成严重影响。 相似文献