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41.
人工合成P型沸石对NH4^+交换特性研究 总被引:4,自引:0,他引:4
应用由粉煤灰合成的P型沸石研究对NH_4~ 交换的热力学和动力学特性。结果表明,P型沸石阳离子交换总量为264meq/100g,在其整个阳离子组成范围内对进入的NH_4~ 具有高的选择交换性,该交换过程能自发沿着正方向进行,随着温度的增高,其交换能力也增强。Na~ =NH_4~ 交换过程具有较优越的动力学特性,在16℃和32℃时,P型沸石中NH_4~ 自扩散系数分别为7.14×10~(-10)和1.12×10~(-9)cm~2·s~(-1);活化能为20.74kJ·mol~(-1);活化熵分别为-88.26和-88.71J·(mol·°K)~(-1);自由能分别为43.85和45.26kJ·mol~(-1)。 相似文献
42.
燃煤电厂灰场排水除氟研究 总被引:2,自引:0,他引:2
本文研究了采用天然斜发沸石—硫酸铝钾体系对燃煤电厂灰场排水中氟的吸附效果及影响因素,并对吸附与再生过程的机理进行了探讨。研究结果表明,天然斜发沸石—硫酸铝钾体系除氟效果良好,运行成本也比较低。 相似文献
43.
吸附法处理模拟含磷废水 总被引:4,自引:0,他引:4
以天然沸石、膨润土为基材,经镁、铝等处理并活化而得的FMA、BMA吸附剂,对磷有较高的吸附能力,其动态吸附容量大于17mg·g~(-1),磷的去除率都在95%以上,吸附后的FMA可用Na_2CO_3、NaOH(5%)洗脱,洗脱率达100%,吸附后的BMA可用Al_2(SO_4)_3(10%)洗脱,洗脱率达81.8% 相似文献
44.
天然沸石去除氨氮研究 总被引:24,自引:0,他引:24
研究了生物膜、悬浮物对天然沸石去除氨氮的影响及其沸石去除氨氮的主要途径。结果表明,沸石去除氨氮主要是离子交换作用,吸附很小,可忽略不计;由于生物膜对氨氮的同化作用,使得有生物膜的沸石对氨氮的交换容量高于无生物膜,其等温交换曲线换符合Freundlich吸附等温式:y/m=KC^l/n;沸石的吸附容量随着悬浮物浓度增高而降低,2者呈负指数关系;悬浮物对沸石离子交换的影响主要在孔扩散控制阶段,在膜扩散控制阶段影响较小;如果停留时间较短(少于3h),悬浮物对沸石离子交换的影响不大。 相似文献
45.
46.
Tongyao Ju Siyu Han Fanzhi Meng Li Lin Jinglin Li Kailun Chen Jianguo Jiang 《Frontiers of Environmental Science & Engineering》2023,17(9):112
47.
Geovana D. Savi William A. Cardoso Bianca G. Furtado Tiago Bortolotto Elton T. Zanoni Rahisa Scussel 《Journal of environmental science and health. Part. B》2018,53(3):184-190
Zeolites are often used as adsorbents materials and their loaded cations can be exchanged with metal ions in order to add antimicrobial properties. The aim of this study was to use the 4A zeolite and its derived ion-exchanged forms with Zn2+, Li+, Cu2+ and Co2+ in order to evaluate their antifungal properties against Fusarium graminearum, including their capacity in terms of metal ions release, conidia germination and the deoxynivalenol (DON) adsorption. The zeolites ion-exchanged with Li+, Cu2+, and Co2+ showed an excellent antifungal activity against F. graminearum, using an agar diffusion method, with a zone of inhibition observed around the samples of 45.3 ± 0.6 mm, 25.7 ± 1.5 mm, and 24.7 ± 0.6 mm, respectively. Similar results using agar dilution method were found showing significant growth inhibition of F. graminearum for ion-exchanged zeolites with Zn2+, Li+, Cu2+, and Co2+. The fungi growth inhibition decreased as zeolite-Cu2+>zeolite-Li+>zeolite-Co2+>zeolite-Zn2+. In addition, the conidia germination was strongly affected by ion-exchanged zeolites. With regard to adsorption capacity, results indicate that only zeolite-Li+ were capable of DON adsorption significantly (P < 0.001) with 37% at 2 mg mL?1 concentration. The antifungal effects of the ion-exchanged zeolites can be ascribed to the interactions of the metal ions released from the zeolite structure, especially for zeolite-Li+, which showed to be a promising agent against F. graminearum and its toxin. 相似文献
48.
49.
Marc Clausse Jérôme Merel Francis Meunier 《International Journal of Greenhouse Gas Control》2011,5(5):1206-1213
Post-combustion CO2 capture remains one of the most-challenging issue to lower CO2 emissions of existing power plants or heavy industry installations because of strong economy and energy efficiency aspects. The major issue comes from CO2 dilution (4% for NGCC and 14% for PC) and the high flow rates to be treated. Furthermore, CO2 purity has to be higher than 95% with recovery at 90%, to match the transportation/injection requirements.The MEA absorption process remains the reference today but its energy consumption (about 3 MJ/kgCO2) and the amine consumption are still challenging drawbacks.The interest of CO2 capture by indirect TSA (Temperature Swing Adsorption) was demonstrated experimentally in a previous work. The aim of this paper is to present the results of a numerical parametric study. Two main parameters are explored: the desorption temperature (100–200 °C) and the purge flow rate (0.1–0.5 Ndm3 min−1). Four performance indicators are evaluated: CO2 purity, recovery, productivity and specific energy consumption.Results show that purity above 95% can be achieved. Keeping the 95% target, it is possible to achieve recovery at 81% with productivity at 57.7 gCO2/kgads h and a specific energy consumption of 3.23 MJ/kgCO2, which is less than for the reference MEA process.Comparison with other adsorption processes exhibits that this process has good potential especially since some improvements are still expected from further research. 相似文献
50.
Vinay Kumar Jha Masahiro Nagae Motohide MatsudaMichihiro Miyake 《Journal of environmental management》2009
Zeolitic materials have been prepared from coal fly ash as well as from a SiO2–Al2O3 system upon NaOH fusion treatment, followed by subsequent hydrothermal processing at various NaOH concentrations and reaction times. During the preparation process, the starting material initially decomposed to an amorphous form, and the nucleation process of the zeolite began. The carbon content of the starting material influenced the formation of the zeolite by providing an active surface for nucleation. Zeolite A (Na-A) was transformed into zeolite X (Na-X) with increasing NaOH concentration and reaction time. The adsorption isotherms of the obtained Na-X based on the characteristics required to remove heavy ions such as Ni2+, Cu2+, Cd2+ and Pb2+ were examined in multi-metal systems. Thus obtained experimental data suggests that the Langmuir and Freundlich models are more accurate compared to the Dubinin–Kaganer–Radushkevich (DKR) model. However, the sorption energy obtained from the DKR model was helpful in elucidating the mechanism of the sorption process. Further, in going from a single- to multi-metal system, the degree of fitting for the Freundlich model compared with the Langmuir model was favored due to its basic assumption of a heterogeneity factor. The Extended-Langmuir model may be used in multi-metal systems, but gives a lower value for equilibrium sorption compared with the Langmuir model. 相似文献