金堆城超大型钼矿床水-岩δD-δ~(18)O同位素交换体系理论模型及成矿流体来源

基于水-岩δD-δ18O同位素交换体系理论模型的建立和计算，对金堆城超大型斑岩钼矿四个不同成矿期中成矿流体的演化和来源进行了研究，发现在成矿前期和早期，成矿流体为岩浆水与围岩在较低水／岩比值（0．1W／R＞0．001）和中、高温（t=250～500℃）条件下反应后的残余流体，而主成矿期和成矿晚期的成矿流作为大气降水在相对较高水／岩比值（0．5＞W／R0．1）和中、低温（t＝150～310℃）条件下与围岩反应后的残留流体。大气降水在金堆城钼矿成矿过程中起了重要作用。在主成矿期水／岩比值达到最高。     

Efficient degradation of organic pollutants by S-NaTaO3/biochar under visible light and the photocatalytic performance of a permonosulfate-based dual-effect catalytic system

Removing large concentrations of organic pollutants from water efficiently and quickly under visible light is essential to developing photocatalytic technology and improving solar energy efficiency. This study used a simple hydrothermal method to prepare a non-metallic, S-doped NaTaO₃ (S-NTO) photocatalyst, which was then loaded onto biochar (BC) to form a S-NTO/BC composite photocatalyst. After uniform loading onto BC, the S-NTO particles transformed from cubic to spherical. The photogenerated electron-hole pair recombination probability of the composite photocatalyst was significantly lower than those of the NTO particles. The light absorption range of the catalyst was effectively widened from 310 nm UV region to visible region. In addition, a dual-effect catalytic system was constructed by introducing peroxymonosulfate (PMS) into the environment of the pollution to be degraded. The Rhodamine B, Methyl Orange, Acid Orange 7, tetracycline, and ciprofloxacin degradation efficiency at 40 mg/L reached 99.6%, 99.2%, 84.5%, 67.1%, and 70.7%, respectively, after irradiation by a 40 W lamps for 90 min. The high-efficiency visible-light catalytic activity of the dual-effect catalytic system was attributed to doping with non-metallic sulfur and loading of catalysts onto BC. The development of this dual-effect catalytic system provides new ideas for quickly and efficiently solving the problem of high-concentration organic pollution in aqueous environments, rationally and fully utilizing solar energy, and expanding the application of photocatalytic technology to practice.     

In-situ-reduced synthesis of cyano group modified g-C3N4/CaCO3 composite with highly enhanced photocatalytic activity for nicotine elimination

Graphite carbon nitride has many excellent properties as a two-dimensional semiconductor material so that it has a wide application prospect in the field of photocatalysis. However, the traditional problems such as high recombination rate of photogenerated carriers limit its application. In this work, we introduce nitrogen deficiency into g-C₃N₄ to solve this problem a simple and safe in-situ reduction method. g-C₃N₄/CaCO₃ was obtained by a simple and safe one-step calcination method with industrial-grade micron particles CaCO₃. Cyano group modification was in-situ reduced during the thermal polymerization process, which would change the internal electronic structure of g-C₃N₄. The successful combination of g-C₃N₄ and CaCO₃ and the introduction of cyanide have been proved by Fourier transform infrared spectroscopy and X-ray photoelectron spectrometer. The formation of the cyano group, an electron-absorbing group, promotes the effective separation of photogenic electron hole pairs and inhibits the recombination of photogenic carriers. These advantages result in the generation of more •O₂⁻ and ¹O₂ in the catalytic system, which increases the photocatalytic efficiency of nicotine degradation by ten times. Furthermore, the degradation process of nicotine has been studied in this work to provide a basis for the degradation of nicotine organic pollutants in the air.     

清洁的胡椒基T醚生产工艺的研究I,5-丙基-1,3-苯并二氧杂茂的氯甲基化废水的处理

报道了胡椒基丁醚生产中５－丙基－１，３－苯并二氧杂茂的氯甲基化的废水处理，该废水经蒸馏可回收９４％的盐酸，此酸吸收氯化氢后浓度在３６％以上，可再用于氯甲基化反应。蒸馏残液经分油、Ｆｅｎｔｏｎ试剂处理和五次生炭柱吸附后ＣＯＤＣｒ等项指标均可国家二类污染物的一级排放标准。     

Upgrading of organic waste: production of the copolymer poly-3-hydroxybutyrate-co-valerate by Ralstonia eutrophus with organic waste as sole carbon source

Two types of fermented organic waste (trade and industry waste and fruit and vegetable waste) were successfully used as a sole carbon source to produce poly-3-hydroxybutyrate-co-valerate (PHBV) by Ralstonia eutrophus (formerly Alcaligenes eutrophus) via oxygen limitation.The production of PHBV could be optimized by optimizing the oxygen transfer through the fermentor. Thereby, a peak concentration of 1.1 g PHBV per liter cell suspension, 40 w% of cell dry weight, was obtained at an aeration rate of 0.24 mol O₂/h·kg biomass. The yield of PHBV on the fatty acid concentration in the organic waste was 0.16 g polymer/g volatile organic matter. The process obtained, compares well with the commercial production process of PHBV based on glucose.     

胰岛素废水处理工程设计

针对某医药公司在制取胰岛素过程中产生的高浓度废水，采用预处理（酒精回收-盐水投配-除油）-倒A2O-接触氧化-化学除磷组合工艺进行调试，其处理效果明显，出水各项指标均能达标，同时对工艺中存在的缺陷进行了分析。     

县域生态功能区划研究——以桐柏县为例

结合桐柏县的实例,对县域生态功能区划分的原则和方法进行初步探讨.综合利用3S技术对县域生态敏感性和生态服务功能重要性的分析和评价,提出桐柏县生态服务功能区划的初步方案.将桐柏县划分为生态支持区,产品供给区,生态调节区.简要分析了各功能区在桐柏县经济可持续发展中的地位和作用,指出各区协调发展的方向和途征.     

In situ preparation of g-C3N4/Bi4O5I2 complex and its elevated photoactivity in Methyl Orange degradation under visible light

A graphite carbon nitride(g-C_3N_4) modified Bi_4O_5I_2 composite was successfully prepared insitu via the thermal treatment of a g-C_3N_4/Bi OI precursor at 400°C for 3 hr.The as-prepared g-C_3N_4/Bi_4O_5I_2 showed high photocatalytic performance in Methyl Orange(MO) degradation under visible light.The best sample presented a degradation rate of 0.164 min~(-1),which is 3.2 and 82 times as high as that of Bi_4O_5I_2 and g-C_3N_4,respectively.The g-C_3N_4/Bi_4O_5I_2 was characterized by X-ray powder diffractometer(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),Raman,X-ray photoelectron spectroscopy(XPS),ultraviolet-visible diffuse reflectance spectra(DRS),electrochemical impedance spectroscopy(EIS) and transient photocurrent response in order to explain the enhanced photoactivity.Results indicated that the decoration with a small amount of g-C_3N_4 influenced the specific surface area only slightly.Nevertheless,the capability for absorbing visible light was improved measurably,which was beneficial to the MO degradation.On top of that,a strong interaction between g-C_3N_4 and Bi_4O_5I_2 was detected.This interplay promoted the formation of a favorable heterojunction structure and thereby enhanced the charge separation.Thus,the g-C_3N_4/Bi_4O_5I_2 composite presented greater charge separation efficiency and much better photocatalytic performance than Bi_4O_5I_2.Additionally,g-C_3N_4/Bi_4O_5I_2 also presented high stability.·O_2~-and holes were verified to be the main reactive species.     

用水基表面活性剂乳液回收废白土中蜡的界面张力研究

通过测定液体与废白土粉末之间的接触角及液体与蜡之间的液液界面张力，对水基表面活性剂乳液的溶剂及配方进行了优选，得到最佳的水基面活性剂乳液的组成为：质量分数０．２％的十二烷基苯磺酸钠＋体积分数为２．５％的乙醇＋体积分数为２５％的混合烃（正己烷＋苯，等体积）＋体积分数为７２．５％的水。实验证明，用该水基表面活性剂乳液处理废白土，蜡的回收率可达８０％，同时不破坏白土的颗粒结构。     

浅析地聚合物的发展和研究动态

地聚合物是一类新型的高性能无机聚合物材料，是碱激活胶凝材料中最具前途的一类。由于其特殊的无机缩聚三维氧化物网络结构，使得地聚合物材料在众多方面具有比高分子材料、水泥、陶瓷和金属更高的高温性能和机械性能；另一方面，地聚合物材料制造过程中的能耗和三废排放量都非常低，材料对环境友好并且可以很好地被回收再年利用，是一种可持续发展的“绿色环保材料”。在比较全面地论述地聚合物材料的发展历史、生产工艺的基础上分析目前存在的问题，提出开发地聚合物材料是兼顾社会发展和减轻环境污染问题的一个较理想的对策。