主成分分析法在三江交汇处水质分析中的应用

本文应用主成分分析法，利用三江交汇处的三个断面从1984年到1998年的监测资料对交汇处的水质做分析，分析前先对量化数据标准化处理，处理后提取主成分，并且计算其贡献率和累计贡献率，再由相应的特征向量得到主成分的线性表达式。结果表明：五项影响因素中，三个断面桔水期均受亚硝酸盐氮的影响比较大，丰水期和平水期均受悬浮物和化学需氧量的影响比较大。交汇前，小南门断面的水质综合污染最严重，凉姜沟断面的水质综合污染最轻；交汇后，三江口断面的水质在两者的缓冲下，水质综合污染居中。则说明主成分分析法为河流的综合治理提供了科学依据。     

Contamination of Oxygen-Consuming Organics in the Yellow River of China

Contamination of oxygen-consuming organics (OCOs) was one of the most serious problems in the Yellow River of China. This study was conducted to analyze monitoring of the data on OCOs contamination for the river in 1980 and during 1992–1999 as well as examining the effect of suspended solids (SS) on chemical oxygen demand (COD_Mn) and biochemical oxygen demand (BOD₅) of river water. Several significant results have arisen from the study. First, COD_Mn and BOD₅ of the river water showed an increasing trend from the upper to the lower reaches of the mainstream. BOD₅ values of river water in 1992 were significantly higher than those in 1980 and showed an increasing trend during 1992–1999. Second, OCOs in river water of the mainstream was attributed mainly to point sources; the ratio of point to non-point sources of BOD₅ was about 2.81. The load from point sources showed an increasing trend during 1992–1998. In contrast, the load from non-point sources manifested a decreasing trend during this period; this was caused by the decreasing trend of SS content in river water. The total load of BOD₅ from point and non-point sources displayed an increasing trend during 1992–1998. Third, as the humic substances in SS can hardly be biologically oxidized in natural conditions but can be oxidized by chemical oxidants such as potassium permanganate, COD_Mn was not suitable for being regarded as a parameter reflecting the pollution degree of OCOs in river water with a high SS content.     

石油污染土壤的生物修复室内模拟实验研究

在实验室模拟的条件下,利用从克拉玛依的石油污染土壤中筛选出的4株高效降解菌,以石油烃降解率、脱氢酶活性、呼吸强度、微生物量碳氮和土壤毒性作为评价指标,研究不加生物菌剂不翻耕、不加生物菌剂翻耕、加生物菌剂不翻耕、加生物菌剂翻耕、加固定化菌剂不翻耕和加固定化菌剂翻耕6种不同实验条件对石油污染土壤修复的效果。结果表明,在63 d的修复过程中,加固定化菌剂翻耕实验F组的石油去除率达到了78.7%,比不加生物菌剂不翻耕实验A组的石油去除率提高了49.5%。随着土壤毒性逐渐降低,玉米(Zea mays L.)和赤子爱胜蚓(Eisenia fetida)可以在F组土壤中良好的生长,达到了修复的效果。     

重金属污染土壤接种丛枝菌根真菌对蚕豆毒性的影响

采用盆栽实验的方法,研究了重金属(包括Cu、Zn、Pb和Cd)复合污染和接种丛枝菌根真菌(arbuscular mycorrhizal fungi,AMF)Glomus mosseae对蚕豆(Vicia faba)生长及DNA损伤的影响.结果表明,虽然接种菌根真菌对蚕豆生物量的影响并不显著,但是却显著影响植物对重金属的吸收,接种菌根真菌对蚕豆吸收4种重金属元素的作用有差异.采用单细胞凝胶电泳(single cell gel electrophoresis,SCGE)法研究接种菌根真菌对蚕豆叶片的DNA损伤的影响,与重金属吸收的结果相吻合.结果表明,接种处理可显著增加蚕豆叶片的DNA损伤程度,这与接种处理可提高植物的重金属吸收相一致.     

Variation of MCPA, metribuzine, methyltriazine-amine and glyphosate degradation, sorption, mineralization and leaching in different soil horizons

Pesticide mineralization and sorption were determined in 75 soil samples from 15 individually drilled holes through the vadose zone along a 28 km long transect of the Danish outwash plain. Mineralization of the phenoxyacetic acid herbicide MCPA was high both in topsoils and in most subsoils, while metribuzine and methyltriazine-amine was always low. Organic matter and soil pH was shown to be responsible for sorption of MCPA and metribuzine in the topsoils. The sorption of methyltriazine-amine in topsoil was positively correlated with clay and negatively correlated with the pH of the soil. Sorption of glyphosate was tested also high in the subsoils. One-dimensional MACRO modeling of the concentration of MCPA, metribuzine and methyltriazine-amine at 2 m depth calculated that the average concentration of MCPA and methyltriazine-amine in the groundwater was below the administrative limit of 0.1 μg/l in all tested profiles while metribuzine always exceeded the 0.1 μg/l threshold value.     

广西一个典型矿业镇环境中重金属污染分析

广西河池市是我国重要的有色金属基地.以该市一个典型的矿业镇作为研究对象,采集了该镇周围23个旱地土壤样品,并在镇里布设两个大气采样点采集了可吸入颗粒物(PM10)样品,运用ICP-MS分析了样品中20种金属元素的含量,采用地积指数法判定旱地土壤和可吸入颗粒物中污染元素及来源.结果表明,这些与人们生活密切的环境介质(旱地土,可吸入颗粒物)均受到了多种重金属元素的复合污染,其共同的污染元素有Cd、As、Sb、Pb、Xn、Cu,而其中致癌元素Cd和As污染最为突出.大气可吸入颗粒物与旱地土壤中各污染元素的污染强度排序相同,均为Cd＞As＞Sb＞Pb＞Zn＞Cu.经过现场调查和识别,污染源主要来自当地开放性运矿产生的扬尘所致.因此加强该地区矿石运输管理是保护该地区耕地和人群健康的需要.     

Effect of variations in the redox potential of Gleysol on barium mobility and absorption in rice plants

Two assays were designed to obtain information about the influence of redox potential variations on barium mobility and bioavailability in soil. One assay was undertaken in leaching columns, and the other was conducted in pots cultivated with rice (Oryza sativa) using soil samples collected from the surface of Gleysol in both assays. Three doses of barium (100,300 mg kg⁻¹ and 3000 mg kg⁻¹-soil dry weight) and two redox potential values (oxidizing and reducing) were evaluated. During the incubation period, the redox potential (Eh) was monitored in columns and pots until values of −250 mV were reached. After the incubation period, geochemical partitioning was conducted on the barium using the European Communities Bureau of Reference (BCR) method. Rainfall of 200 mm d⁻¹ was simulated in the columns and in the planting of rice seedlings in the pots. The results of the geochemical partitioning demonstrated that the condition of reduction favors increased barium concentrations in the more labile chemical forms and decreased levels in the chemical forms related to oxides. The highest barium concentrations in leached extracts (3.36 mg L⁻¹) were observed at the highest dose and condition of reduction at approximately five times above the drinking water standard. The high concentrations of barium in the soil did not affect plant dry matter production. The highest levels and accumulation of barium in roots, leaves, and grains of rice were found at the highest dose and condition of reduction. These results demonstrate that reduction leads to solubilization of barium sulfate, thereby favoring greater mobility and bioavailability of this element.     

Risk assessment and prioritisation of contaminated sites on the catchment scale

Contaminated sites pose a significant threat to groundwater resources worldwide. Due to limited available resources a risk-based prioritisation of the remediation efforts is essential. Existing risk assessment tools are unsuitable for this purpose, because they consider each contaminated site separately and on a local scale, which makes it difficult to compare the impact from different sites. Hence a modelling tool for risk assessment of contaminated sites on the catchment scale has been developed. The CatchRisk screening tool evaluates the risk associated with each site in terms of its ability to contaminate abstracted groundwater in the catchment. The tool considers both the local scale and the catchment scale. At the local scale, a flexible, site specific leaching model that can be adjusted to the actual data availability is used to estimate the mass flux over time from identified sites. At the catchment scale, a transport model that utilises the source flux and a groundwater model covering the catchment is used to estimate the transient impact on the supply well. The CatchRisk model was tested on a groundwater catchment for a waterworks north of Copenhagen, Denmark. Even though data scarcity limited the application of the model, the sites that most likely caused the observed contamination at the waterworks were identified. The method was found to be valuable as a basis for prioritising point sources according to their impact on groundwater quality. The tool can also be used as a framework for testing hypotheses on the origin of contamination in the catchment and for identification of unknown contaminant sources.     

Health risks of heavy metals in contaminated soils and food crops irrigated with wastewater in Beijing, China

Consumption of food crops contaminated with heavy metals is a major food chain route for human exposure. We studied the health risks of heavy metals in contaminated food crops irrigated with wastewater. Results indicate that there is a substantial buildup of heavy metals in wastewater-irrigated soils, collected from Beijing, China. Heavy metal concentrations in plants grown in wastewater-irrigated soils were significantly higher (P相似文献   

Semi-analytical solution of two-dimensional sharp interface LNAPL transport models

In this paper, we present semi-analytical solutions for two-dimensional equations governing transport of Light Non-Aqueous Phase Liquids (LNAPL) in unconfined aquifers. The proposed model is based on sharp interface displacement and steady groundwater flow assumptions, where both the water–LNAPL interface and the LNAPL–air interface are represented as sharp interfaces. In the case of steady groundwater flow, these equations can be reduced to a two-dimensional nonlinear solute transport equation, with the LNAPL thickness in the free product lens being the primary unknown variable. The linearized form of this solute transport equation falls into the category of two-dimensional transport equation with time-dependent dispersion coefficients. This equation can be solved analytically for an infinite domain region. In this paper, the general form of the analytical solution for the transport equation, as well as the solutions for some specific cases are presented. To demonstrate the utility of the proposed solution, numerical results obtained for two example problems are discussed and presented comparatively with a finite-element solution and other more restrictive solutions available in the literature. Although the solutions discussed in this paper have some simplifying assumptions, such as sharp-interfaces between fluid phases, steady groundwater flow and homogeneous aquifer properties, the semi-analytical solutions presented in this study may be used effectively as bench mark solutions in evaluating LNAPL migration in the subsurface. These solutions are simple and cost effective to implement and may be used in the calibration of other more complex numerical solutions that can be found in the literature.