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71.
72.
垃圾焚烧发电过程中的二次污染物控制处理技术 总被引:2,自引:0,他引:2
概述了二口恶英、重金属、酸性气体、灰渣等垃圾焚烧二次污染物的形成机理,并详细介绍了通过控制垃圾焚烧条件、尾气处理以及吸附等方法,可以有效控制二口恶英类污染物的排放;重金属的控制可以用除尘器或使用相应的吸附剂处理;采用较为成熟的烟气处理技术,可以控制处理酸性气体;灰渣可采用固化稳定化和酸或其他溶剂提出法处置。 相似文献
73.
对流化床垃圾焚烧炉的工艺改进进行了分析 ,在焚烧炉内更有利于脱除酸性气体 ,当垃圾热值达 4 5 0 0kJ/kg时 ,部分吹入氧气可使燃烧温度达 1 30 0℃以上。用空心球代替流动砂可以取消流动砂的循环环节 相似文献
74.
在转式垃圾焚烧炉和固定床加热炉中,研究了有机垃圾焚烧过程中温度、水分、无机氯及有机氯对几种重金属分布的影响。研究结果表明,焚烧垃圾过程中焚烧温度对重金属分布特性的影响特性不一,重金属锌和铅容易转移到气相中去,而重金属镍和铬大部分是以固态形式残留在底渣中;水能与重金属及其化合物发生反应,引起物质转变,影响重金属的分布;氯的存在也影响重金属的分布特性,氯的参与使重金属更易向飞灰或烟气中迁移。 相似文献
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焚烧法处理环己酮生产中的皂化液 总被引:1,自引:0,他引:1
用环已烷氧化生产环已酮的生产过程中会产生大量的皂化液 ,它含有大量的有害物质 ,是一种难处理的高污染有机废水。某石化厂在借鉴造纸行业的黑液焚烧技术的基础上 ,采用焚烧法来处理皂化液 ,并得到副产蒸气和回收了碳酸钠 ,实现了皂化液的无害化与资源化 ,具有良好的社会效益、环境效益和经济效益 ,每处理 1t皂化液可盈利 10 0~ 2 0 0元 相似文献
78.
Bures M Pekárek V Karban J Fiserová E 《Environmental science and pollution research international》2003,10(2):121-125
BACKGROUND, AIMS AND SCOPE: In the first part of this paper the main principles which control the dehalogenation of polychlorinated aromatic compounds on municipal waste incineration fly ash (MWI-FA) have been discussed and the model fly ash of similar dehalogenation activity has been proposed. Even if both systems show comparable dehalogenation properties, the main question concerning the postulated identical reaction mechanism in both cases is left unanswered. The other very important point is to what extent is this dechlorination mechanism thermodynamically controlled. The same problem is often discussed in the literature also for the de novo synthetic reactions. From the data it is clear that metallic copper plays a decisive role in the mechanism of the dehalogenation reaction. Although the results reported in the first part strongly support the idea that copper acts in this dechlorination as the reaction component, in contrast to its generally accepted catalytic behaviour, we believed that additional support for this conclusion can be obtained with the help of a thermodynamic interpretation of the mechanism of the reaction. RESULTS AND DISCUSSION: The pathways of hexachlorobenzene dechlorination on MWI-FA and model fly ash were studied in a closed system at 260-300 degrees C under nitrogen atmosphere. These pathways were the same for both systems, with the following prevailing sequences: hexachlorobenzene --> pentachlorobenzene --> 1,2,3,5-tetrachlorobenzene --> 1,3,5-trichlorobenzene --> 1,3-dichlorobenzene. Thermodynamic calculations were carried out by using the method of minimization total Gibbs energy of the whole system. In the calculations, the following reaction components were taken into account: all gaseous chlorinated benzenes, benzene, hydrogen chloride, a gaseous trimer Cu3Cl3, and also Cu2O and CuCl2 as solid components. The effect of the reaction temperature and the amount of copper and water vapour were considered as well. The effect of reaction temperature was determined from the data calculated for the 500 to 750 K temperature region. The effect of the initial composition was determined for the molar amounts of copper = 0.01-3 moles and water vapour = 0.2 to 3 moles per mole of chlorobenzene isomer CONCLUSIONS: The results of hexachlorobenzene dechlorination by MWI-FA and model fly ash under comparable reaction conditions allow us to conclude that both dechlorinations proceed via the same dechlorination pathways, which can be taken as an evidence of the identical dehalogenation mechanism for both systems. The relative percentual distribution of the dehalogenated products depends on the temperature, but not on the initial amount of water vapour or copper metal. On the other hand, the initial amount of copper substantially affects the conversion of the dehalogenation as well as the molar ratio of Cu3Cl3 to HCl in the equilibrium mixture. Comparison of the experimental with thermodynamic results supports the idea that dehalogenation reactions are thermodynamically controlled. RECOMMENDATIONS AND OUTLOOK: Thermodynamic analysis of the dehalogenation reactions may prove useful for a wide range of pollutants. The calculations concerning polychlorinated biphenyls and phenols are under study. 相似文献
79.
80.
比较了胶布热空气连续硫化废气的几种处理方法,认为焚烧法是最有效的处理方法,并对应用该法处理废气的工艺原理、主要设备、余热回收是焚烧过程中诮注意的事项作了较详尽的阐述。 相似文献