Determination of chemical warfare agents

Ethylarsine dichloride was used during WW I as a chemical warfare agent. Residues of this chemical warfare agent and its metabolites are still present today and continue to contaminate soil and water. A gas Chromatographic method for the detection and determination of ethylarsine dichloride is shown. Six dithiols were tested as possible derivatization reagents for ethylarsine dichloride. With selection of the dithiol, matrix interferences can be eliminated because of the different retention times of the derivatives.     

Destruction of diphenylarsine chloride (CLARK I) with activated ozone

The new technology of Plasmazon® uses the extremely strong oxidation of radicals to break up the compocunds of organic connections, e.g. chemical warfare agents like Clark I. In making a comparison of oxidation to normal ozone, the factor of the Plasmazon® -technology is available up to 10³. The investigation in an experimental test shows that it is possible to destroy the warfare agent character of Clark I. As the possibility of a large-lot application this technology is the method of choice for other chemical or biological warfare agents.     

Protected area characteristics that help waterbirds respond to climate warming

Protected area networks help species respond to climate warming. However, the contribution of a site's environmental and conservation-relevant characteristics to these responses is not well understood. We investigated how composition of nonbreeding waterbird communities (97 species) in the European Union Natura 2000 (N2K) network (3018 sites) changed in response to increases in temperature over 25 years in 26 European countries. We measured community reshuffling based on abundance time series collected under the International Waterbird Census relative to N2K sites’ conservation targets, funding, designation period, and management plan status. Waterbird community composition in sites explicitly designated to protect them and with management plans changed more quickly in response to climate warming than in other N2K sites. Temporal community changes were not affected by the designation period despite greater exposure to temperature increase inside late-designated N2K sites. Sites funded under the LIFE program had lower climate-driven community changes than sites that did not received LIFE funding. Our findings imply that efficient conservation policy that helps waterbird communities respond to climate warming is associated with sites specifically managed for waterbirds.     

Impr?gnierte Filterpapiere für die Wasserreinigung

Mit impr?gnierten Filtermaterialien ist es m?glich, die Schwermetalle Blei, Kupfer und Nickel sowie Arsen durch Sorption bzw. chemische Bindung aus Wasser zu entfernen. Bei 24stündiger Einwirkungszeit wurden Reduktionsraten von 97% bis>99,9% erreicht.     

Recent Trends in Residential Energy Use in OECD Countries and their Impact on Carbon Dioxide Emissions: A Comparative Analysis of the Period 1973–1992

In the late 1970s and for most of the 1980s, residential energy use in the OECD underwent significant changes. Many of these changes were a result of more efficient energy use in response to higher energy prices, energy efficiency programs, and the appearance of new technologies for saving energy. This study analyzes these changes and the impact of energy use on carbon emissions in the residential sector for nine OECD countries for the period from 1973 to 1992. The major findings of this analysis are:

1. CO₂ emissions per capita were lower in 1992 in almost all of the countries we studied;
2. The two primary changes were improvements in energy efficiency and a decrease in the share of fossil fuels used for electricity and district heating production;
3. The main source of growth in emissions from residential energy use was increased ownership of electric appliances, where, in spite of important improvements in energy efficiency, ownership grew so rapidly that electricity use (and subsequent emissions) increased;
4. Changes in fuel mix, including both the changes in the share of fuels used in households and the share of fuels used to generate electricity and district heating, led to a decrease in emissions in the nine countries;
5. Increasing the efficiency of electric appliances and further reductions in the intensity of space heating are probably the key elements in a strategy to improve efficiency as a means to lowering CO₂ emissions.