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排序方式: 共有210条查询结果,搜索用时 15 毫秒
91.
Multiple efforts have been directed towards optimized processes in which enzymes, like peroxidases, are used to remove phenolic compounds from polluted wastewater. Here we describe the use of peroxidase isoenzymes from tomato hairy roots, which were able to oxidise 2,4-dichlorophenol (2,4-DCP) and phenol from aqueous solutions. This could be an interesting alternative for the removal of these compounds from contaminated sites. We used different enzyme fractions: total peroxidases (TP), ionically bound to cell wall peroxidases (IBP), basic (BP) and acidic peroxidases (AP). We analyzed the optimum conditions of removal, the effect of Polyethyleneglycol (PEG-3350) on the process and on the enzyme activities, to obtain the maximum efficiency. The optimal H2O2 concentrations for 2,4-DCP and phenol removal were 1 and 0.1mM, respectively. TP, IBP and BP showed better removal efficiencies than AP, for both contaminants. The addition of different concentrations (10-100mg l(-1)) of PEG-3350 to solutions containing 2,4-DCP showed no effect on the removal efficiencies of the isoenzymes. However, PEG (100mg l(-1)) increased the removal efficiency of phenol by BP and IBP fractions. On the other hand, peroxidase activities from BP and IBP fractions were 3 and 13 times higher, respectively, than those detected for the same fractions in phenol treated solutions without PEG. The protective effect of PEG, which depends on the contaminant as well as of the enzyme fraction used, would be important to improve the removal efficiency of phenol by some peroxidase isoenzymes. 相似文献
92.
93.
Vecchi R Bernardoni V Fermo P Lucarelli F Mazzei F Nava S Prati P Piazzalunga A Valli G 《Environmental monitoring and assessment》2009,154(1-4):283-300
Nowadays, high-time resolved aerosol studies are mandatory to better understand atmospheric processes, such as formation, removal, transport, deposition or chemical reactions. This work focuses on PM10 physical and chemical characterisation with high-time resolution: elements (from Na to Pb), ions and OC/EC fractions concentration were determined during two weeks in summer and two in winter 2006 with 4-hours resolution. Further measurements aimed at hourly elemental characterisation of fine and coarse fractions and at the determination of particles number concentration in the 0.25-32 microm size range in 31 bins. The chemical mass closure was carried out in both seasons, enhancing intra-day differences in PM10 composition. In Milan, the highest contribution came from organic matter (34% and 33% in summer and winter, respectively); other important contributors were secondary inorganic compounds (16% and 24% in summer and winter, respectively) and, in summer, crustal matter (14%). Temporal trends showed strong variations in PM10 composition during contiguous time-slots and diurnal variations in different components contribution were identified. Moreover, peculiar phenomena, which would have hardly been detected with 24-hours samplings, were evidenced. Particles removal due to precipitations, aerosol local production and long range transport were studied in detail. 相似文献
94.
Pozo-Antonio José Santiago Cardell Carolina Comite Valeria Fermo Paola 《Environmental science and pollution research international》2022,29(20):29438-29454
Environmental Science and Pollution Research - Black crusts (BCs) are one of the most critical alteration forms found on stones belonging to architectural heritage. Since they could be considered... 相似文献
95.
Pargoletti Eleonora Comite Valeria Fermo Paola Sabatini Valentina Annunziata Luisa Ortenzi Marco Aldo Farina Hermes Cappelletti Giuseppe 《Environmental science and pollution research international》2022,29(20):29455-29466
Environmental Science and Pollution Research - Atmospheric pollutants, such as NOx, SO2, and particulate matter, together with water percolation inside the stone pores, represent the main causes of... 相似文献
96.
Squadrone Stefania Pederiva Sabina Bezzo Tabata Sartor Rocco Mussat Battuello Marco Nurra Nicola Griglione Alessandra Brizio Paola Abete Maria Cesarina 《Environmental science and pollution research international》2022,29(20):29529-29534
Environmental Science and Pollution Research - Microplastics are contaminants of great concern all over the world. Microplastics constitute pollutants themselves; moreover, other contaminants such... 相似文献
97.
Hoffmann Nicolás Fincheira Paola Tortella Gonzalo Rubilar Olga 《Environmental science and pollution research international》2022,29(55):82619-82631
Environmental Science and Pollution Research - Anaerobic digestion (AD) is the most widely used technology for organic matter treatment. However, multiple types of research have reported on... 相似文献
98.
Speranza A Ferri P Battistelli M Falcieri E Crinelli R Scoccianti V 《Chemosphere》2007,66(7):1165-1174
Due to its widespread industrial use, chromium is considered a dangerous environmental pollutant. It is known to inhibit plant growth and development. The present study provides the first evidence of the toxicity of this metal on the male haploid generation of a higher plant. Both Cr(III) and Cr(VI) species, supplied as CrCl(3) and CrO(3), respectively, exerted a strong dose-dependent inhibitory effect on kiwifruit pollen tube emergence and growth. Cr(III) resulted more effective than Cr(VI) in the 16-75microM interval; moreover, complete inhibition of germination was attained at much lower doses than Cr(VI). Also tube morphology was affected. While the plasma membrane was still undamaged in the large majority of the treated pollen grains, dramatic ultrastructural alterations were induced by chromium including chromatin condensation, swelling of mitochondria, cytoplasmic vacuolization, and perturbed arrangement of endoplasmic reticulum cisternae. Thus, it seems that the impact of the two chromium species on kiwifruit pollen may result in severe compromission of both essential structures and functions of the male gametophyte. 相似文献
99.
Marco Iotti Paola Fabbri Massimo Messori Francesco Pilati Patrizia Fava 《Journal of Polymers and the Environment》2009,17(1):10-19
Organic–inorganic hybrid coatings based on poly(ε-caprolactone), poly(ethylene oxide) or poly(lactic acid) as organic phase
and silica from tetraethoxysilane as inorganic phase were prepared by the sol–gel approach. Coatings were applied onto poly(lactic
acid) films for food packaging in order to improve its barrier properties towards oxygen and water vapour. All the prepared
coatings were dense, homogeneous layers characterized by a good adhesion to the substrate. The permeance of the coating layers
resulted one order of magnitude lower than that of the uncoated poly(lactic acid) (PLA) film. The hydrophilic character of
the coating did not permit to gain a significant decrease in the water vapour permeance. The perfect visual transparency of
the coatings allows their application without worsening of the esthetical properties of the substrate PLA film. 相似文献
100.
Europe has a wealth of community forest arrangements. This paper aims to transcend the diversity of locally specific terms and forms, to highlight the value of considering them inclusively. Building on methods to make sense of diversity, we use reflexive grounded inquiry in fifteen cases in Italy, Scotland, Slovenia and Sweden. Within four dimensions (forest, community, relationships between them, and relationships with wider society), we identify 43 subdimensions to describe them collectively. Our approach shows how European arrangements contribute to wider discourses of collective natural resource management. Both tradition and innovation in Europe inform options for environmental governance. Arrangements challenge the distinction between ‘communities of place’ and ‘communities of interest’, with implications for social and environmental justice. They exemplify multilevel environmental governance through both vertical and horizontal connections. Emerging from long histories of political and environmental pressures, they have a role in enhancing society’s connection with nature and adaptive capacity.Electronic supplementary materialThe online version of this article (10.1007/s13280-020-01377-x) contains supplementary material, which is available to authorised users. 相似文献