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排序方式: 共有56条查询结果,搜索用时 31 毫秒
1.
Synthesis of poly(hydroxyalkanoate) from hydrolyzed linseed oil 总被引:3,自引:0,他引:3
Elena Casini Theo C. de Rijk Pieter de Waard Gerrit Eggink 《Journal of Polymers and the Environment》1997,5(3):153-158
Pseudomonas putida was grown on a mixture of long-chain fatty acids obtained by hydrolysis of linseed oil. A poly(3-hydroxyalkanoate) containing
51.2% of unsaturated monomers was obtained. A considerable percentage (13.6%) was constituted by C14 and C16 monomers containing three double-bonds in the side chains. The polymer showed a high tendency to crosslink when it was kept
in presence of air. In the crosslinked polymer no polyunsaturated monomers could be detected. 相似文献
2.
Four sequence batch reactors (SBRs) fed by fermented sugar cane wastewater were continuously operated under the aerobic dynamic feeding (ADF) mode with different configurations of sludge retention time (SRT), carbon and initial biomass concentrations to enrich polyhydroxyalkanoate (PHA) accumulating mixed microbial cultures (MMCs) from municipal activated sludge. The stability of SBRs was investigated besides the enrichment performance. The microbial community structures of the enriched MMCs were analyzed using terminal restriction fragment length polymorphism (T-RFLP). The optimum operating conditions for the enrichment process were: SRT of 5 days, carbon concentration of 2.52 g COD/L and initial biomass concentration of 3.65 g/L. The best enrichment performance in terms of both operating stability and PHA storage ability of enriched cultures (with the maximum PHA content and PHA storage yield (YPHA/S) of 61.26% and 0.68 mg COD/mg COD, respectively) was achieved under this condition. Effects of the SRT, carbon concentration and initial biomass concentration on the PHA accumulating MMCs selection process were discussed respectively. A new model including the segmentation of the enrichment process and the effects of SRT on each phase was proposed. 相似文献
3.
进水底物浓度对蔗糖废水产酸合成PHA影响研究 总被引:2,自引:1,他引:1
混合菌群合成生物可降解塑料(PHA)成为目前研究的热点,三段式PHA合成工艺(水解产酸、产PHA菌富集、PHA合成)被广泛应用.在三段式工艺中,产PHA菌的富集非常关键,只有稳定产生PHA菌才能保障PHA合成的产量.针对产PHA菌富集系统容易出现污泥膨胀的问题,本研究考察了进水底物浓度对产PHA菌富集效率及运行稳定性的影响.在560mg·L-1、1 120 mg·L-1、1 680 mg·L-1这3组不同进水底物浓度的对比实验中,证实了COD 1 120 mg·L-1条件下富集反应器能够在较短污泥龄下稳定富集具有较高污泥浓度的高效产PHA菌,且不会发生污泥膨胀.在94 d的富集期后其批次实验最大PHA含量、PHA转化率(COD/COD)及PHA比合成速率能分别达到50%、0.714 5及0.191 2 mg·(mg·h)-1.研究还同时证实细胞内糖原水平高低与其PHA合成能力密切相关,可采用其作为富集效果的重要检测指标之一. 相似文献
4.
聚β羟基烷酸盐(PHA)以其较好的生物相容性、可生物降解性和再生性成为最有前途的生物高分子材料.本文基于甘油作为基质在饱食-饥饿模式下富集合成PHA的混培物,以乙酸、丙酸、丁酸、乳酸和葡萄糖作为基质考察混培物合成PHA的基质广谱性,结果表明乳酸和乙酸作为基质时PHA的产率系数较高;使用不同比例乙酸/丙酸混合基质时,PHA产量随着乙酸含量的增加而增大,乙酸/丙酸为3∶1时PHA产量最高.通过活性污泥同时贮存与生长模型模拟与线性回归两种方法证实,在单一基质或乙酸/丙酸混合基质情况下,PHA合成速率与OUR存在线性关系,因此,基于在线OUR测量数据可以实时估计PHA合成量. 相似文献
5.
采用经乙酸钠驯化培养具有一定聚羟基烷酸酯(PHA)储存能力的活性污泥,考察乙酸、丙酸和丁酸3种短链脂肪酸,以及乙酸、丁酸分别与丙酸按1∶1、1∶2、2∶1比例组合成的6种混合酸作为碳源时对活性污泥中PHA的储存和转化的影响。实验结果表明,在3种短链脂肪酸中,以丁酸为碳源得到活性污泥PHA储存量最高,为40.53 mg/g;在混合酸中,乙酸与丙酸按1∶2组合时,系统PHA储存量最高,为773.4 mg/g。混合酸相对于单一的脂肪酸碳源更有利于活性污泥储存PHA。在混合酸总量一定的条件下,随着丙酸比例的增加,乙酸与丙酸混合比丁酸与丙酸混合更有利于微生物的PHA储存。 相似文献
6.
Hans Preusting Jaap Kingma Gjalt Huisman Alexander Steinbüchel Bernard Witholt 《Journal of Polymers and the Environment》1993,1(1):11-21
WhenPseudomonas oleovorans (GPo1) is grown on sodium octanoate under ammonium limiting conditions, it is able to accumulate a copolyester consisting of medium chain length 3-hydroxyalkanoic acids (PHAm). 3-Hydroxybutyrate is only incorporated in trace amounts. WhenP. oleovorans is equipped with the PHB biosynthetic genes ofAlcaligenes eutrophus (GPo1[pVK101::PP1]), it forms a polyester containing major amounts of 3-hydroxybutyrate. The resulting polymer however is a blend of PHAm and PHB, rather than a copolymer of 3-hydroxybutyrate and medium chain length 3-hydroxyalkanoic acids [11]. To establish whether PHAm and PHB molecules are stored in the same or separate granules by this recombinantP. oleovorans strain, we studied polymer forming cells by freeze-fracture electron microscopy. This approach is possible because previous freeze-fracture electron microscopy studies on PHAm and PHB accumulating strains have shown that PHAm and PHB granules can be distinguished from each other: PHAm granules from mushroom-like structures, whereas PHB granules from needle structures during freeze-fracturing. In this paper we show that stationary phase cells of GPo1[pVK101::PP1] contained both mushroom and needle-like structures, indicating that PHAm and PHB chains were stored in separate granules. To be able to determine whether the separation of PHAm and PHB is complete, the respective granules were separated on sucrose gradients. A total cell extract of GPo1[pVK101::PP1] which was subjected to sucrose gradient centrifugation revealed two white bands of different densities: the upper band with a density of 1.05 g/mL consisted exclusively of PHAm granules, while the lower band with a density of 1.19 g/mL consisted of PHB granules only. Thus, when bacteria synthesize both PHAm and PHB, the resulting polymer chains are segregated completely and stored in separate granules. 相似文献
7.
8.
马晓亮 《安全.健康和环境》2006,6(12):38-40
运用预先危险性分析法(PHA),对芳烃联合装置地下管线测漏处理过程中存在的风险进行了分析,确定了应采取的安全措施,取得了明显效果. 相似文献
9.
Zhiqiang Chen Lizhi Zhao Ye Ji Qinxue Wen Long Huang 《Frontiers of Environmental Science & Engineering》2019,13(4):54
10.
Identifying dead-legs and related corrosion issues continues to be a challenge in the process industry. Pipeline corrosion has been a factor in several recent incidents involving releases and fires. A review of incident reports and citations over the past ten years indicates that Process Hazard Analysis (PHA) revalidations have been noted for not addressing the hazards of a process including corrosion mechanisms and dead-legs. In order for the hazards to be addressed, they must first be accurately identified in a PHA and documented along with any recommended actions for preventive maintenance. This paper describes a methodology for identifying and addressing dead-legs and related corrosion issues in a PHA that can be used to update corporate PHA procedures to be more robust in preventing corrosion related incidents. 相似文献